Results 41 to 50 of about 3,794 (208)

Ruthenium‐Catalyzed CH Alkenylation of Trypanocidal Naphthoquinones: A Mechanistic Benchmarking Study

open access: yesChemistryOpen, Volume 15, Issue 2, February 2026.
Computational roadmap to click‐ready quinones. Quantum chemical analysis reveals how substituents modulate the reactivity of trypanocidal naphthoquinones in Ru‐catalyzed CH alkenylation, guiding the design of sulfonyl‐fluoride scaffolds for next‐generation antiparasitic agents.
Esther R. S. Paz   +8 more
wiley   +1 more source

Dicarbonyl(hexamethylene-1,3,5,7-tetramine-κN1)(η5-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate

open access: yesActa Crystallographica Section E, 2012
In the title compound, [Fe(C10H15)(C6H12N4)(CO)2]BF4, the arrangement around the FeII atom corresponds to a three-legged piano stool. The pentamethylcyclopentadienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of ...
Cyprian M. M'thiruaine   +3 more
doaj   +1 more source

Influence of Polymer and Support Interactions on the Electrocatalytic Properties of Heterogenized Molecular Complexes

open access: yesChemCatChem, Volume 18, Issue 1, 15 January 2026.
ABSTRACT Heterogenized molecular catalysts have been the subject of increasing interest in the context of electrochemical small molecule activation due to the possibility of active site homogeneity and tunability, which can surpass many nanostructured materials.
Elizabeth K. Johnson, Charles W. Machan
wiley   +1 more source

Acetonitriledicarbonyl(η5-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate

open access: yesActa Crystallographica Section E, 2011
In the structure of the title compound, [Fe{η5-C5(CH3)5}(NCCH3)(CO)2]BF4, the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stool fashion in which the pentamethylcyclopentadienyl (Cp*) ligand occupies ...
Cyprian M. M'thiruaine   +3 more
doaj   +1 more source

Latest News: Reactions of Group 4 Bis(trimethylsilyl)acetylene Metallocene Complexes and Applications of the Obtained Products

open access: yesChemistryOpen, 2021
Recently published reactions of group 4 metallocene bis(trimethylsilyl)acetylene (btmsa) complexes from the last two years are reviewed. Complexes like Cp’2Ti(η2‐Me3SiC2SiMe3) and Cp2Zr(py)(η2‐Me3SiC2SiMe3) with Cp’ as Cp (cyclopentadienyl) and Cp ...
Prof. Uwe Rosenthal
doaj   +1 more source

(η6-Benzophenone)(η5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate

open access: yesActa Crystallographica Section E, 2009
The structure of the title compound, [Ru(C10H15)(C13H10O)](C24H20B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetraphenylborate anions (Cp* = pentamethylcyclopentadienyl). Tethering the Cp*Ru group to one aryl ring of benzophenone results
Bradley T. Loughrey   +3 more
doaj   +1 more source

Noncovalent Immobilization of Pentamethylcyclopentadienyl Iridium Complexes on Ordered Mesoporous Carbon for Electrocatalytic Water Oxidation

open access: yesSmall Science, 2021
The attachment of molecular catalysts to conductive supports for the preparation of solid‐state anodes is important for the development of devices for electrocatalytic water oxidation.
Ana M. Geer   +10 more
doaj   +1 more source

Polimerização de estireno utilizando compostos organolantanídeos ativados por MAO

open access: yesQuímica Nova, 2006
In an attempt to improve the performance of organolanthanide catalysts we investigated the use of the industrially important cocatalyst methylaluminoxane (MAO) to activate organolanthanide compounds in olefin polymerization. The catalytic systems LnBrCp2(
Alessandra de Souza Maia   +3 more
doaj   +1 more source

Bis(η5-pentamethylcyclopentadienyl)cobalt(II)

open access: yesActa Crystallographica Section E, 2009
The crystal structure of the title compound, decamethylcobaltocene, [Co(C10H15)2], has been determined. High-quality single crystals were grown from a cold saturated hexamethyldisiloxane solution.
Meghan M. Clark   +2 more
doaj   +1 more source

Functionalization of Complexed N2O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium

open access: yesOrganometallics, 2014
Methyl triflate reacts with the metastable azoxymetallacyclopentene complex Cp*2Zr(N(O)NCPhCPh), generated in situ from nitrous oxide insertion into the Zr–C bond of Cp*2Zr(η2-PhCCPh) at −78 °C, to afford the salt [Cp*2Zr(N(O)N(Me)CPhCPh)][O3SCF3] (1) in
D. Mindiola   +3 more
semanticscholar   +1 more source

Home - About - Disclaimer - Privacy