Results 51 to 60 of about 925 (184)
The title compound, [Fe4(C10H15)2(C8H10O4S2)2S4], contains a twisted Fe4S4 cubane-like core. A twofold rotation axis passes through the Fe4S4 core, completing the coordination of the four Fe atoms with two pentamethylcyclopentadienyl ligands and two ...
Shohei Ito +3 more
doaj +1 more source
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina +5 more
wiley +1 more source
(2,2-Bipyridyl)bis(η5-pentamethylcyclopentadienyl)strontium(II)
In the title compound, [Sr(C10H15)2(C10H8N2)], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr...Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the ...
Sergio Rozenel +4 more
doaj +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
(η5-Pentamethylcyclopentadienyl)(η6-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate
The title compound, [Ru(C10H15)(C10H12O)][B(C6H5)4], crystallizes as discrete (η5-pentamethylcyclopentadienyl)Ru(η6-4-phenylbutan-2-one)]+ cations and [BPh4]− anions. In the cation, the non-H atoms of the butan-2-one group are
Bradley T. Loughrey +2 more
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Ir-Catalyzed Reduction of Carbonyl Compounds Using Biogenetic Alcohols
Biomass has gained great attention as an alternative to fuel-derived chemicals. This report concerns new catalytic systems consisting of [IrCp*Cl2]2 (Cp*: Pentamethylcyclopentadienyl) for the reduction of aldehyde and biogenetic alcohols as hydrogen ...
Yuta Nishina
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(η5-Pentamethylcyclopentadienyl)(η6-p-toluenesulfonamide)ruthenium(II) tetraphenylborate
The crystal structure of the title compound, [Ru(C10H15)(C7H9NO2S)]C24H20B, has been determined as part of our investigation into the structural and biological properties of organometallic RuII–arene–Cp* complex salts of the type [R-PhRuCp*]+&
Peter C. Healy +3 more
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A Comparative DFT Study for Ruthenium
Here, a comparative DFT study of a transition metal complex, (pentamethylcyclopentadienyl) (diisopropylmethylphosphine) (chloro) (trichlorosilyl) rutheniumhydride, is reported.
Nil ERTEKİN BİNBAY
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Rutile Without Substrate Limitations: Top‐Interface‐Driven Crystallization of TiO2
A RuO2 upper layer acts as a removable crystallization template that triggers rutile TiO2 formation from the top interface, independent of the underlying substrate. This top‐interface‐driven crystallization mechanism enables rutile growth even on amorphous ZrO2/TiN, offering a substrate‐agnostic route to high‐k dielectrics compatible with DRAM process ...
Jihoon Jeon +3 more
wiley +1 more source
In the title compound, [LiTa(C10H15)(C10H13N)2Cl(C4H10O)], the TaV atom is coordinated by a η5-pentamethylcyclopentadienyl (Cp*) ligand, a chloride ion and two N-bonded 2-tert-butylphenylimide dianions.
Jacqueline M. Cole +3 more
doaj +1 more source

