Results 71 to 80 of about 3,087 (178)

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

Chemistry – A European Journal, Volume 32, Issue 20, 27 May 2026.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina, Rodrigo González‐Prieto, Jesús Jover, Adrián Pérez‐Redondo, José Luis Priego, Carlos Yélamos   +5 more
wiley   +1 more source

Ir-Catalyzed Reduction of Carbonyl Compounds Using Biogenetic Alcohols

Inorganics, 2019
Biomass has gained great attention as an alternative to fuel-derived chemicals. This report concerns new catalytic systems consisting of [IrCp*Cl2]2 (Cp*: Pentamethylcyclopentadienyl) for the reduction of aldehyde and biogenetic alcohols as hydrogen ...
Yuta Nishina
doaj   +1 more source

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

European Journal of Organic Chemistry, Volume 29, Issue 19, 22 May 2026.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Scandium

, 2014
Use of pentamethylcyclopentadienyl ligands (C₅Me₅) in place of cyclopentadienyl (Cp) provides reactive, but thermally robust monomelic 14-electron scandocene derivatives.
Min, Endy Y.-J, Bercaw, John E., Kenward, Alyson L., Piers, Warren   +3 more
core  

Pentamethylcyclopentadienyl-rhodium and iridium complexes containing (N^N and N^O) bound chloroquine analogue ligands: synthesis, characterization and antimalarial properties [PDF]

, 2016
The synthesis and characterization of twenty new pentamethylcyclopentadienyl-rhodium and iridium complexes containing N^N and N^O-chelating chloroquine analogue ligands are described.
Kock, Carmen de, Smith, Peter J., Monari, Magda, de Kock, Carmen, Kumar, Kamlesh, Ekengard, Erik, Fogeron, Thibault, Smith, Peter J, Kumar, Kamlesh,, Haukka, Matti, Nordlander, Ebbe,, Lund University., Ekengard, Erik,, Nordlander, Ebbe   +13 more
core   +1 more source

(η5-Pentamethylcyclopentadienyl)(η6-p-toluenesulfonamide)ruthenium(II) tetraphenylborate

Acta Crystallographica Section E, 2008
The crystal structure of the title compound, [Ru(C10H15)(C7H9NO2S)]C24H20B, has been determined as part of our investigation into the structural and biological properties of organometallic RuII–arene–Cp* complex salts of the type [R-PhRuCp*]+&
Peter C. Healy, Sally-Ann Poulsen, Michael L. Williams, Bradley T. Loughrey   +3 more
doaj   +1 more source

A Comparative DFT Study for Ruthenium

Journal of the Turkish Chemical Society, Section A: Chemistry, 2020
Here, a comparative DFT study of a transition metal complex, (pentamethylcyclopentadienyl) (diisopropylmethylphosphine) (chloro) (trichlorosilyl) rutheniumhydride, is reported.
Nil ERTEKİN BİNBAY
doaj   +1 more source

An Organometallic [2]Catenane With Pt‒(di‐NHC)‒Pt Units: A Topology‐Driven Strategy for Enhanced Phosphorescence in Discrete Aggregates

Angewandte Chemie, Volume 138, Issue 19, 4 May 2026.
The mechanically interlocked Borromean rings are stabilized by π···π stacking interactions while the [2]catenane is stabilized by solvophobic effects. While the π···π interactions in the Borromean rings lead to severe luminescence quenching, the solvophobically assembled [2]catenane effectively circumvents these interactions, simultaneously restricting
Ye Lu, Xi‐Dong Wu, Zi‐Yan Min, Lu An, Shi‐Ping Yang, F. Ekkehardt Hahn   +5 more
wiley   +1 more source

Synthesis, characterization, and reactivity of pentamethylcyclopentadienyl complexes of divalent cobalt and nickel [PDF]

, 1993
The thesis is divided into the following 4 chapters: synthesis, characterization, and reactivity of trinuclear pentamethylcyclopentadienyl cobalt and nickel clusters with triply-bridging methylidyne groups; chemical and physical properties of ...
Smith, M. E., Smith, M.E.
core  

Synthesis, molecular structure, computational study and in vitro anticancer activity of dinuclear thiolato-bridged pentamethylcyclopentadienyl Rh(iii) and Ir(iii) complexes

, 2013
International audienceNeutral dinuclear dithiolato-bridged pentamethylcyclopentadienyl Rh(III) complexes of the type (C5Me5)2Rh2(μ-SR)2Cl2 (R = CH2Ph, 1; R = CH2CH2Ph, 2) and cationic dinuclear trithiolato-bridged pentamethylcyclopentadienyl Rh(III) and ...
Garci, Amine, Giannini, Federico, Murray, Benjamin, S., Dyson, Paul, J., Dyson, Paul J., Gupta, Gajendra, Trouillas, Patrick, Suess-Fink, Georg, Furrer, Julien, Therrien, Bruno, Fabre, Gabin, Murray, Benjamin S., Süss-Fink, Georg   +12 more
core   +1 more source