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Journal of the American Chemical Society, 2008 This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 A for 1 and 0.0325 A for 2), the UV-vis spectra display a split Soret band with a shoulder ...
Palmer, Joshua H. +5 more
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Processing of Iridium and Iridium Alloys
Platinum Metals Review, 2008 Iridium and its alloys have been considered to be difficult to fabricate due to their high melting temperatures, limited ductility, sensitivity to impurity content and particular chemical properties. The variety of processing methods used for iridium and its alloys are reviewed, including purification, melting, forming, joining and powder metallurgy ...
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Iridium‐Catalyzed Arylative Cyclization of Alkynones by 1,4‐Iridium Migration [PDF]
Angewandte Chemie International Edition, 2014 Abstract1,4‐Metal migrations enable the remote functionalization of CH bonds, and have been utilized in a wide variety of valuable synthetic methods. The vast majority of existing examples involve the 1,4‐migration of palladium or rhodium. Herein, the stereoselective synthesis of complex polycycles by the iridium‐catalyzed arylative cyclization of ...
Benjamin M. Partridge +2 more
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DNA-Binding Properties of Iridium(III) Complexes Encompassing Design, Function and Biophysical Assessments. [PDF]
ChemphyschemAlkhaibari IS, Buurma NJ, Pope SJA.
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Multidentate Surfactant-Dependent Synthesis of Giant Iridium Superstructures. [PDF]
LangmuirBalasubramanian R, Hill ME.
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Iridium(III) Complexes Bearing Pyrene- and Anthracene-Functionalized Ligands-Photophysics and Application Potential in Photocatalysis, Triplet-Triplet Annihilation Upconversion, Photodynamic Therapy, and Photoactivated Chemotherapy. [PDF]
MoleculesKryczka A +3 more
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