Results 11 to 20 of about 48,743 (243)

XAFS spectrum of Iridium

open access: yes
This dataset consists of X-ray absorption fine structure (XAFS) spectra at Ir L3-edge of Iridium measured at Photon Factory BL-12C, and is a part of XAFS database (MDR XAFS DB, https://doi.org/10.48505/nims.1447) as a collection of ...
Photon Factory
core   +3 more sources

A Hexanuclear Iridium Chain

open access: yesAngewandte Chemie International Edition, 2003
Electrons in chains: A novel metallic chain made up of six iridium atoms (see picture) with an average oxidation state of +1.33 has been found in the complex HH,HT,HH-[Ir6(μ-OPy)6(I)2(CO)12] (Opy=2-pyridonate, H=head, T=tail). This complex provides a new link in the electronic sequence connecting dinuclear IrI and IrII complexes.
Tejel, Cristina   +5 more
openaire   +3 more sources

Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligands

open access: yes, 2016
EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and
Henwood, Adam Francis   +11 more
core   +1 more source

Organometallic half-sandwich iridium anticancer complexes [PDF]

open access: yes, 2011
The low-spin 5d6 IrIII organometallic half-sandwich complexes [(η5-Cpx)Ir(XY)Cl]0/+, Cpx = Cp*, tetramethyl(phenyl)cyclopentadienyl (Cpxph), or tetramethyl(biphenyl)cyclopentadienyl (Cpxbiph), XY = 1,10-phenanthroline (4−6), 2,2′-bipyridine (7−9 ...
Liu, Zhe   +34 more
core   +1 more source

Processing of Iridium and Iridium Alloys

open access: yesPlatinum Metals Review, 2008
Iridium and its alloys have been considered to be difficult to fabricate due to their high melting temperatures, limited ductility, sensitivity to impurity content and particular chemical properties. The variety of processing methods used for iridium and its alloys are reviewed, including purification, melting, forming, joining and powder metallurgy ...
openaire   +1 more source

Tuning the emission of cationic iridium (III) complexes towards the red through methoxy substitution of the cyclometalating ligand

open access: yes, 2015
EZ-C acknowledges CFI (Canadian Foundation for Innovation), NSERC (the Natural Sciences and Engineering Research Council of Canada), FQRNT (Le Fonds québécois de la recherche sur la nature et les technologies) and the University of St Andrews for ...
Samuel, Ifor David William   +5 more
core   +1 more source

Cell‐cycle‐specific lesion evolution rather than inhibition of double‐strand‐break repair underpins cisplatin radiosensitization

open access: yesMolecular Oncology, EarlyView.
We analyze cisplatin–DNA adducts (CDAs) and double‐strand breaks (DSBs) in a cell‐cycle‐dependent manner. We find that CDAs form similarly across all cell cycle phases. DSBs arise only in S‐phase. CDAs might not directly impair DSB repair, but S‐phase DSB lesions evolve in the presence of CDAs and disrupt repair in G2, also causing radiosensitization ...
Ye Qiu   +10 more
wiley   +1 more source

Iridium-Catalyzed 1,3-Rearrangement of Allylic Ethers

open access: yes, 2023
The 1,3-rearrangement of allylic derivatives has rarely been reported, except for allylic alcohols. Herein, we describe an iridium-catalyzed 1,3-rearrangement of readily available allylic ethers to access the difficultly prepared allylic ethers with a ...
Yifan Song (2537101)   +5 more
core   +1 more source

Longitudinal circulating tumor DNA profiling in patients with advanced endometrial cancer using an off‐the‐shelf targeted NGS panel

open access: yesMolecular Oncology, EarlyView.
Intratumour heterogeneity complicates precision management of advanced endometrial cancer. Circulating tumor DNA (ctDNA) offers a minimally invasive strategy to capture tumor evolution and therapeutic resistance. Here, we compare tumor‐agnostic NGS with tumor‐informed ddPCR, outlining their relative sensitivity, concordance, and clinical implications ...
Carlos Casas‐Arozamena   +15 more
wiley   +1 more source

Loss of IGF‐1R impairs DNA‐PKcs recruitment to chromatin leading to defective end‐joining

open access: yesMolecular Oncology, EarlyView.
IGF‐1R promotes radioresistance by facilitating DNA‐PKcs recruitment to chromatin, enabling non‐homologous end‐joining (NHEJ) repair of double‐strand breaks. Inhibition or loss of IGF‐1R disrupts this recruitment to damage sites, driving compensatory reliance on microhomology‐mediated end‐joining (MMEJ) repair.
Matthew O. Ellis   +3 more
wiley   +1 more source

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