Results 41 to 50 of about 108,120 (190)

Sub-Chronic Oral Exposure to Iridium (III) Chloride Hydrate in Female Wistar Rats: Distribution and Excretion of the Metal

open access: yesDose-Response, 2012
Iridium tissue distribution and excretion in female Wistar rats following oral exposure to iridium (III) chloride hydrate in drinking water (from 1 to 1000 ng/ml) in a sub-chronic oral study were determined.
Ivo Iavicoli   +7 more
doaj   +1 more source

Formation of nanostructured iridium and polycluster diamond films [PDF]

open access: yesTekhnologiya i Konstruirovanie v Elektronnoi Apparature, 2007
Iridium films and layered structures "iridium — diamond" were formed on Al2O3, MgO and SrTiO3 substrates. Iridium films were obtained by magnetron sputtering, and polycluster diamond films — by microwave discharge method. Structure of iridium and diamond
Pashchenko P. V.   +7 more
doaj   +2 more sources

Study of Iridium electrodeposition on Ti and A304

open access: yesInternational Journal of Electrochemical Science, 2015
Iridium is considered a valuable material due to its physical, chemical and electrocatalytic properties [1-3]. Iridium recovery from post-consumed industrial materials and effluents [4, 5] is necessary, since the natural resources for its production are ...
S.S. Serrano Lopez   +4 more
doaj   +1 more source

A Panchromatic Cyclometalated Iridium Dye Based on 2-Thienyl-Perimidine

open access: yesMolecules, 2022
Though 2-arylperimidines have never been used in iridium(III) chemistry, the present study on structural, electronic and optical properties of N-unsubstituted and N-methylated 2-(2-thienyl)perimidines, supported by DFT/TDDFT calculations, has shown that ...
Paulina Kalle   +7 more
doaj   +1 more source

Multiband $d-p$ model and self-doping in the electronic structure of Ba$_2$IrO$_4$

open access: yes, 2016
We introduce and investigate the multiband $d-p$ model describing a IrO$_4$ layer (such as realized in Ba$_2$IrO$_4$) where all $34$ orbitals per unit cell are partly occupied, i.e., $t_{2g}$ and $e_g$ orbitals at iridium and $2p$ orbitals at oxygen ions.
Oleś, Andrzej M.   +1 more
core   +1 more source

Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium : biological relevance and synthetic strategies [PDF]

open access: yes, 2012
This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination
Barry, Nicolas P. E., Sadler, P. J.
core   +1 more source

Electronic Structure of Hyperkagome Na4Ir3O8

open access: yes, 2010
We investigate the electronic structure of the frustrated magnet Na4Ir3O8 using density functional theory. Due to strong spin-orbit coupling, the hyperkagome lattice is characterized by a half-filled complex of states, making it a cubic iridium analogue ...
M. R. Norman, T. Micklitz, W. H. Press
core   +1 more source

Probing the C-H Activation of Linear and Cyclic Ethers at (PNP)Ir [PDF]

open access: yes, 2009
Interaction of the amido/bis(phosphine)-supported (PNP)Ir fragment with a series of linear and cyclic ethers is shown to afford, depending on substrate, products of α,α-dehydrogenation (carbenes), α,β-dehydrogenation (vinyl ethers), or decarbonylation ...
Chen, Chun-Hsing   +6 more
core   +1 more source

Sub-monolayers of iridium electrodeposited on Ti2AlC substrate as catalysts for hydrogen evolution reaction in sulfuric acid solution

open access: yesZaštita Materijala, 2020
The hydrogen evolution reaction (HER) was investigated at sub-monolayers of iridium electrodeposited on Ti2AlC substrate. The lowest amount of electrodeposited iridium was 3 close-packed (111) monolayers (3 ML), while the highest one was 22 ML (3, 5, 10,
Vladimir D. Jović   +1 more
doaj   +1 more source

Nano-metal diborides-supported anode catalyst with strongly coupled TaOx/IrO2 catalytic layer for low-iridium-loading proton exchange membrane electrolyzer

open access: yesNature Communications, 2023
The sluggish kinetics of oxygen evolution reaction (OER) and high iridium loading in catalyst coated membrane (CCM) are the key challenges for practical proton exchange membrane water electrolyzer (PEMWE).
Yuannan Wang   +8 more
doaj   +1 more source

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