Results 41 to 50 of about 925 (184)

(η6-Benzophenone)(η5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate

open access: yesActa Crystallographica Section E, 2009
The structure of the title compound, [Ru(C10H15)(C13H10O)](C24H20B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetraphenylborate anions (Cp* = pentamethylcyclopentadienyl). Tethering the Cp*Ru group to one aryl ring of benzophenone results
Bradley T. Loughrey   +3 more
doaj   +1 more source

Noncovalent Immobilization of Pentamethylcyclopentadienyl Iridium Complexes on Ordered Mesoporous Carbon for Electrocatalytic Water Oxidation

open access: yesSmall Science, 2021
The attachment of molecular catalysts to conductive supports for the preparation of solid‐state anodes is important for the development of devices for electrocatalytic water oxidation.
Ana M. Geer   +10 more
doaj   +1 more source

Rational Optimization of Self‐Reporting Alcohol‐Oxidizing RhIII$^{\mathrm{III}}$ Complexes

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 17, 17 June 2026.
A series of four different [(NN)Rh(Cp*)X]n+$^{\mathrm{n+}}$ complexes (NN = chelating α$\alpha$‐diimine ligand, Cp* = pentamethylcyclopentadienyl, X = Cl, solvent) are reported which all do possess a colorimetric self‐reporting property upon alcohol oxidation formation of the Rh(I) state. Analysis of alcohol oxidation rates
Luca Hefty   +5 more
wiley   +1 more source

Polimerização de estireno utilizando compostos organolantanídeos ativados por MAO

open access: yesQuímica Nova, 2006
In an attempt to improve the performance of organolanthanide catalysts we investigated the use of the industrially important cocatalyst methylaluminoxane (MAO) to activate organolanthanide compounds in olefin polymerization. The catalytic systems LnBrCp2(
Alessandra de Souza Maia   +3 more
doaj   +1 more source

DNA‐Binding Properties of Iridium(III) Complexes Encompassing Design, Function and Biophysical Assessments

open access: yesChemPhysChem, Volume 27, Issue 11, 15 June 2026.
This review describes the biophysical techniques used to investigate DNA‐binding phenomena and the progress made so far in the application of iridium(III) complexes for this purpose. Ir(III) complexes offer myriad opportunities in the design and study of DNA‐binding agents and discussed examples are contextualised with complementary studies in ...
Ibrahim S. Alkhaibari   +2 more
wiley   +1 more source

Bis(η5-pentamethylcyclopentadienyl)cobalt(II)

open access: yesActa Crystallographica Section E, 2009
The crystal structure of the title compound, decamethylcobaltocene, [Co(C10H15)2], has been determined. High-quality single crystals were grown from a cold saturated hexamethyldisiloxane solution.
Meghan M. Clark   +2 more
doaj   +1 more source

Unraveling the Effect of Chemical Environment on Half‐Sandwich Cp*ReO3 Complex Stability in Deoxydehydration Reaction

open access: yesChemCatChem, Volume 18, Issue 11, 15 June 2026.
For the first time, Cp*ReO3 complex was rigorously investigated for deoxydehydration (DODH) reaction, enabling the transformation of biomass‐derived polyols into valuable chemicals. This work reveals how the chemical environment governs catalyst stability and provides key mechanistic insights into active rhenium species.
Han Wang   +4 more
wiley   +1 more source

[1,2-Bis(diphenylphosphino)ethane]chlorido(η5-pentamethylcyclopentadienyl)iron(II) dichloromethane solvate

open access: yesActa Crystallographica Section E, 2010
In the title compound, [Fe(C10H15)Cl(C26H24P2)]·CH2Cl2, the FeII atom is coordinated by two P atoms from a 1,2-bis(diphenylphosphino)ethane ligand [Fe—P = 2.2130 (7) and 2.2231 (7) Å], a chloride ...
Ya-ping Ou, Dan Feng, Jing-jing Yuan
doaj   +1 more source

Bis[bis(pentamethylcyclopentadienyl)ytterbium(III)] ditelluride [PDF]

open access: yesActa Crystallographica Section C Crystal Structure Communications, 1988
[Yb(C 10 H 15 ) 2 ] 2 Te 2 cristallise dans P2 1 /n avec affinement jusqu'a 0,036. L'ion Te 2+ est situe sur un centre de symetrie, perpendiculairement et entre les deux atomes Yb.
Zalkin, A., Berg, D.J.
openaire   +2 more sources

Utilizing a Bulky Ligand to Regulate Orbach, Raman, and QTM Relaxation Processes in a Series of Oh‐Type Dy(III)‐Based Single‐Molecule Magnets

open access: yesSmartMat, Volume 7, Issue 3, June 2026.
Synthesizes three similar octahedral (Oh) Dy(III)‐based single‐molecule magnets via a bulky alcohol ligand, which enhances the effective energy barrier up to 1649 K. This study provides structural design strategies for regulating Orbach, Raman and QTM processes and demonstrates the significant potential of large steric hindrance ligands in creating a ...
Ya‐Wei Geng   +5 more
wiley   +1 more source

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