Results 111 to 120 of about 196,788 (338)

Arene oxidation with malonoyl peroxides [PDF]

open access: yes, 2015
Malonoyl peroxide 7, prepared in a single step from the commercially available diacid, is an effective reagent for the oxidation of aromatics. Reaction of an arene with peroxide 7 at room temperature leads to the corresponding protected phenol which ...
Andrei Dragan   +34 more
core   +2 more sources

Photothermal Hydrogel with Mn3O4 Nanoparticles Alleviates Intervertebral Disc Degeneration by Scavenging ROS and Regulating Extracellular Matrix Metabolism

open access: yesAdvanced Functional Materials, EarlyView.
The MPTT‐nanozyme‐hydrogel system (Mn3O4@ChS‐HA) provides a multifunctional therapeutic strategy for intervertebral disc degeneration (IVDD), effectively targeting oxidative stress and enhancing AF repair by restoring extracellular matrix (ECM) and redox homeostasis.
Yangyang Chen   +13 more
wiley   +1 more source

Synthesis and biological investigation of (+)-3-hydroxymethylartemisinin

open access: yesBeilstein Journal of Organic Chemistry, 2019
Herein, we describe a biomimetic entry to (+)-3-hydroxymethylartemisinin (2) as well as to the artemisinin derivatives (+)-3-hydroxymethyl-9-desmethylartemisinin (16) and (+)-3-hydroxymethyl-9-epi-artemisinin (18), starting from the known and readily ...
Toni Smeilus   +5 more
doaj   +1 more source

Systemic Inflammatory Reaction in Females with Severe Gestosis During Surgical Delivery

open access: yesОбщая реаниматология, 2007
Objective: to study the impact the impact of surgical delivery on the time course of changes in the concentration of tumor necrosis factor-а (TNF-а), interleukin (IL)-1/8, y-interferon, IL-4, IL-6, IL-10, and neopterin in the venous blood of women with ...
I. V. Mikhno, V. M. Zhenilo
doaj   +1 more source

Understanding the aqueous phase ozonolysis of isoprene: distinct product distribution and mechanism from the gas phase reaction [PDF]

open access: yes, 2012
The aqueous phase reaction of volatile organic compounds (VOCs) has not been considered in most analyses of atmospheric chemical processes. However, some experimental evidence has shown that, compared to the corresponding gas phase reaction, the aqueous ...
Chen, Z. M.   +4 more
core   +1 more source

Strain Partitioning at the Oxide Interface for the Isothermal Phase Transition in Freestanding Tri‐Layers

open access: yesAdvanced Functional Materials, EarlyView.
The metal–insulator transition temperature (TMI) is continuously tuned by the systematic change of relative thickness in VO2 and TiO2 films (tVO2/tTiO2${t_{{\mathrm{V}}{{\mathrm{O}}_2}}}/{t_{{\mathrm{Ti}}{{\mathrm{O}}_2}}}$) in freestanding TiO2/VO2/TiO2 tri‐layers.
Sungwon Lee   +5 more
wiley   +1 more source

Modeling of secondary organic aerosol yields from laboratory chamber data [PDF]

open access: yes, 2009
Laboratory chamber data serve as the basis for constraining models of secondary organic aerosol (SOA) formation. Current models fall into three categories: empirical two-product (Odum), product-specific, and volatility basis set. The product-specific and
Chan, A. W. H.   +4 more
core  

Ionic Metal Poly(heptazine Imides) and Single‐Atoms Interplay: Engineered Stability and Performance for Photocatalysis, Photoelectrocatalysis and Organic Synthesis

open access: yesAdvanced Functional Materials, EarlyView.
Poly(heptazine) imides (PHIs), a crystalline carbon nitride subclass, intercalate metals to deliver high stability, tunable electronics, and efficient charge separation. These features enable solar‐driven applications such as hydrogen evolution, CO₂ reduction, and organic synthesis.
Gabriel A. A. Diab   +6 more
wiley   +1 more source

Transient Stiffness Patterning in Hydrogels Driven by Dissipative Mechanochemical Coupling

open access: yesAdvanced Functional Materials, EarlyView.
Force‐induced disulfide bond rupture in a polymer‐based hydrogel, coupled with chemical or electrochemical reoxidation, leads to the transient modulation of the hydrogel's stiffness properties. High spatiotemporal control is achieved by this dissipative process, enabling the development of out‐of‐equilibrium stiffness patterns and transient, dose ...
Roberto Baretta   +2 more
wiley   +1 more source

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