Results 121 to 130 of about 65,477 (305)

Hydrophobic MFI‐Type Zeolites via Alkali‐Cation‐Induced Defect Healing: Implications for Adsorbent and Catalyst Design

open access: yesAdvanced Materials, EarlyView.
Sub‐stoichiometric amounts of Na+ or K+ enhance defect healing during Silicalite‐1 (MFI) and TS‐1 calcination by promoting Si–O–Si annealing and healing framework vacancies. The resulting defect‐free zeolites are more hydrophobic and show improved butanol/water separation and improved activity and selectivity in the epoxidation of 1‐hexene, offering a ...
Christos Kanteler   +14 more
wiley   +1 more source

Introdução de ligações cruzadas no LLDPE através de processo de extrusão reativa de graftização do vinil-trimetóxi-silano (VTMS) na cadeia polimérica: Efeito das condições de processamento e do sistema reacional Silane grafting and mositure crosslinking of LLDPE by a reactive extrusion process: effect of processing conditions and reaction system

open access: yesPolímeros, 2011
Embora a reticulação do polietileno efetuada através de processo de extrusão reativa, envolvendo a graftização de silanos vinílicos na cadeia polimérica, seja um processo bastante utilizado industrialmente, poucos estudos têm sido publicados sobre a ...
Alexandre B. Pessanha   +2 more
doaj  

Peroxides as Sources of Electrophilic Oxygen: Their Reactivity and Synthesis

open access: yes, 2020
Peroxides can be used as a source of electrophilic oxygen per the 1925 discovery by Gilman and Adams that Grignard reagents could be reacted with various peroxides to form carbon-oxygen bonds.
Locklear, Moriah
core  

Polyphenol‐Inspired Materials for Agricultural Applications

open access: yesAdvanced Materials, EarlyView.
This review outlines the use of polyphenol‐inspired materials for sustainable agriculture, highlighting their molecular design, interfacial assembly, structure–property relationships, and prospects toward precision agriculture, climate resilience, ecosystem protection, and circular bioeconomy strategies.
Haofu Liu   +8 more
wiley   +1 more source

Defect‐Engineered Microwave‐Responsive Ni@C Composites From Waste PET for Catalytic Plastic Upcycling

open access: yesAdvanced Materials, EarlyView.
A circular upcycling strategy transforms waste poly(ethylene terephthalate) bottles into microwave‐responsive Ni@C catalyst featuring lattice‐distorted nickel cores and defective carbon shells. These strain‐rich heterointerfaces enhance dielectric loss and promote localized microwave hotspots, accelerating peroxymonosulfate activation and polymer‐chain
Xiao Lu   +7 more
wiley   +1 more source

S‐Nitrosothiols as Thiol‐Protecting Groups for Controlled Thiol‐Maleimide Crosslinking of Homogeneous Soft Hydrogels

open access: yesAdvanced Materials, EarlyView.
Rapid thiol‐maleimide addition frequently outpaces mixing, resulting in heterogeneous hydrogels. S‐nitrosothiols act as thiol‐protecting groups, allowing uniform mixing with maleimide‐functionalized polymers before gelation. Sodium thiosulfate or sodium ascorbate then regenerates thiols on demand, triggering controlled thiol‐maleimide crosslinking ...
Julian A. Serna   +7 more
wiley   +1 more source

Fracture resistance of endodontically-treated teeth submitted to bleaching treatment with hydrogen peroxide and titanium dioxide nanoparticles photoactivated by LED-laser

open access: yesRevista de Odontologia da UNESP
Objective: The aim of this study was evaluate the fracture resistance of endodontically-treated teeth after bleaching treatment using 15% hydrogen peroxide plus titanium dioxide nanoparticles (15HPTiO2) photoactivated by LED-laser, in comparison with ...
Keren Cristina JORDÃO-BASSO   +7 more
doaj   +1 more source

Protective mechanisms against peptide and protein peroxides generated by singlet oxygen

open access: yes, 2004
Reaction of certain amino acids, peptides, and proteins with singlet oxygen yields substrate-derived peroxides. Recent studies have shown that these species are formed within intact cells and can inactivate key cellular enzymes.
Davies, Michael J.   +2 more
core   +1 more source

Decoding Synergistic Pathways in Bimetallic MOFs for Advanced Oxidation Processes

open access: yesAdvanced Materials, EarlyView.
This review presents a unified framework linking metal pairing and framework design with electronic structure, redox cycling, oxidant activation, reactive‐species generation, and catalytic performance across photocatalytic and oxidant‐based BMOF‐AOPs. The resulting design principles guide the development of hydrolytically stable and efficient BMOFs for
Karim El‐Naggar   +2 more
wiley   +1 more source

peroxides

open access: yes, 2014
Citation: 'peroxides' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.P04510 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

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