Results 11 to 20 of about 1,846 (182)

Hydrogen Isotope Effect on the Isomerization of Peroxynitrous Acid

open access: closedCroatica Chemica Acta, 1998
The proton affinity (PA) of peroxynitrite (ONOO-) and peroxynitrous acid (ONOOH) are calculated to be 1440.5 kJ mol-1 and 749.8 kJ mol-1, respectively. Comparison with results for the nitrous, nitric and peroxynitric acid and their anions supports these estimates.
S. Padmaja   +3 more
openalex   +6 more sources

On the proton affinity of peroxynitrite and peroxynitrous acid [PDF]

open access: greenCroatica chemica acta, 2001
The proton affinity (PA) of peroxynitrite (ONOO-) and peroxynitrous acid (ONOOH) are calculated to be 1440.5 kJ mol-1 and 749.8 kJ mol-1, respectively. Comparison with results for the nitrous, nitric and peroxynitric acid and their anions supports these estimates.
Saša Kazazić   +4 more
openalex   +1 more source

Second OH overtone excitation and statistical dissociation dynamics of peroxynitrous acid

open access: closedThe Journal of Chemical Physics, 2005
The second OH overtone transition of the trans-perp conformer of peroxynitrous acid (tp-HOONO) is identified using infrared action spectroscopy. HOONO is produced by the recombination of photolytically generated OH and NO2 radicals, and then cooled in a pulsed supersonic expansion.
Ian M. Konen   +3 more
openalex   +5 more sources

H<sub>2</sub>S Is a Potential Universal Reducing Agent for Prx6-Type Peroxiredoxins. [PDF]

open access: yesAdv Sci (Weinh)
We report the identification of H2S as reducing agent for Prx6‐type peroxiredoxins. In contrast to common physiological reducing agents of other peroxiredoxins, HS− is small enough to access the active site of oxidized Prx6‐type enzymes in the fully‐folded protein conformation.
Lang L, Leiskau L, Bambach L, Deponte M.
europepmc   +2 more sources

Oxidant-modified amylin fibrils and aggregates alter the inflammatory profile of multiple myeloid cell types, but are non-toxic to islet β cells

open access: yesRedox Biology, 2023
Diabetes mellitus currently affects ∼10% of the population worldwide, with Type 2 predominating, and this incidence is increasing steadily. Both Type 1 and 2 are complex diseases, involving β-cell death and chronic inflammation, but the pathways involved
Ramona Clemen   +3 more
doaj   +1 more source

Antioxidant Properties of Food-Derived Lactic Acid Bacteria: A Review. [PDF]

open access: yesMicrob Biotechnol
The graphical abstract shows an example of the division of the mechanisms of action of lactic acid bacteria in the context of antioxidant properties. Point 1 describes the scavenging of free radicals. Point 2 describes the chelation of metal ions. Point 3 describes the accumulation of manganese and the production of antioxidant enzymes.
Łepecka A, Kołożyn-Krajewska D.
europepmc   +2 more sources

Coupled Antibacterial Effects of Plasma-Activated Water and Pulsed Electric Field

open access: yesFrontiers in Physics, 2022
In the biomedical applications of cold plasma, the dominant biological effect is most typically attributed to the reactive oxygen and nitrogen species (RONS), while the physical effect of electric fields is sometimes overlooked. Here, we investigated the
Robin Mentheour, Zdenko Machala
doaj   +1 more source

A guide to reactive oxygen species in tumour hypoxia: measurement and therapeutic implications. [PDF]

open access: yesMol Oncol
Hypoxia reshapes tumour redox landscapes by altering compartmental ROS production (mitochondria, NOX, ER, peroxisomes). Accurate interpretation requires oxygen‐contextualised measurement (live biosensors, chemical probes, EPR, LC–MS) and awareness of artefacts (reoxygenation, probe specificity).
Hacker L   +3 more
europepmc   +2 more sources

Degradation of 1,4-dioxane by reactive species generated during breakpoint chlorination: Proposed mechanisms and implications for water treatment and reuse

open access: yesJournal of Hazardous Materials Letters, 2022
Breakpoint chlorination, an important chemical process relevant to chlorine-based advanced oxidation processes for potable reuse and to traditional water treatment, was investigated for its oxidative capacity, generation of reactive species, and ...
Samuel D. Patton   +2 more
doaj   +1 more source

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