Transition metal catalyzed coupling reaction strategy has been utilized in the synthesis of two novel BN-perylenes starting from halogenated BN-naphthalene derivatives.
Xiangdong Fang
doaj +3 more sources
Stringing the Perylene Diimide Bow
AbstractThis study explores a new mode of contortion in perylene diimides where the molecule is bent, like a bow, along its long axis. These bowed PDIs were synthesized through a facile fourfold Suzuki macrocyclization with aromatic linkers and a tetraborylated perylene diimide that introduces strain and results in a bowed structure.
Taifeng Liu +2 more
exaly +5 more sources
Chirally locked and dynamic bis-perylene diimide macrocycles with multiple sources of chirality [PDF]
Chiral organic materials show great promise in optoelectronics, sensing and catalysis. Among those, macrocycles are of great interest due to their preorganisation and potential amplification of chiroptical properties.
Denis Hartmann +3 more
doaj +2 more sources
Construction of Donor–Acceptor Heterojunctions via Microphase Separation of Discotic Liquid Crystals with Ambipolar Transport [PDF]
A series of novel discotic liquid crystalline donor–acceptor hybrid heterojunctions were prepared by blending the triphenylene derivative (T5E36) as donor and perylene tetracarboxylic esters as acceptor.
Heng Liu +9 more
doaj +2 more sources
Facile Synthesis of Dicyclohepta[cd,fg]‐as‐indacene and Confirmation of its Anti‐Kasha S3 Emission
Interest in non‐benzenoid polycyclic aromatic hydrocarbons (PAHs) has rapidly increased due to their unique electronic configurations and physical properties, which differ significantly from those of their benzenoid counterparts.
Ryoji Hatakenaka +6 more
doaj +2 more sources
Perylene-Based Covalent Organic Frameworks for Acid Vapor Sensing
Traditionally, the properties and functions of covalent organic frameworks (COFs) are defined by their constituting building blocks, while the chemical bonds that connect the individual subunits have not attracted much attention as functional components ...
Thomas Bein (668128) +7 more
core +6 more sources
INSIGHT INTO THE EFFECTS OF BAY-SUBSTITUENTS ON STABLE PERYLENE DIIMIDE RADICAL ANION SALTS [PDF]
In previous work, the facile method to prepare perylene diimide radical anion salt by alkali treatment was reported. However, the effects of structure on synthetic process of perylene diimide radical anion salt, and the difference of response to Cu 2 ...
Yuzhen Zhao +5 more
doaj +1 more source
Vitrification of octonary perylene mixtures with ultralow fragility [PDF]
Strong glass formers with a low fragility are highly sought-after because of the technological importance of vitrification. In the case of organic molecules and polymers, the lowest fragility values have been reported for single-component materials. Here,
Börjesson, Karl, +16 more
core +1 more source
Energetics and electronic structures of perylene confined in carbon nanotubes [PDF]
The energetics and geometries of perylene encapsulated in carbon nanotubes (CNTs) have been investigated employing density functional theory using the generalized gradient approximation combined with the van der Waals correction.
Yuya Nagasawa +2 more
doaj +1 more source
Color-tunable encapsulated perylene-labeled silica fluorescent hybrid nanoparticles
Novel fluorescent nanoparticles were prepared via the encapsulation of perylene diimide into silica nanoparticles. The fluorescent nanoparticles were characterized by various analytical techniques, including transmission electron microscopy (TEM ...
Amina L. Mohamed +2 more
doaj +1 more source

