Results 31 to 40 of about 3,082 (195)

Perylene Bisimide Cyclophanes: Structure–Property Relationships upon Variation of the Cavity Size

open access: yesOrganic Materials, 2020
Five cyclophanes composed of two perylene bisimide (PBI) dyes and various CH2–arylene–CH2 linker units were synthesized. PM6-D3H4 geometry-optimized structures and a single crystal for one of these cyclophanes reveal well-defined distances between the ...
Jessica Rühe   +4 more
doaj   +1 more source

Transient Optical Characterisation of Donor-Acceptor Block Copolymers for Use in Solar Cells [PDF]

open access: yes, 2010
This thesis presents a study of photo-active, semiconducting block copolymers for use in molecular solar cells. Current state-of-the-art organic devices utilise blends of two (or more) materials that are co-deposited from a common solution; the resulting
King, Simon P., King, Simon P.
core   +1 more source

Reversible Photoreduction as a Trigger for Photoresponsive Gels [PDF]

open access: yes, 2016
We present here a new type of photoresponsive, reversible low molecular weight gel. All previous examples rely on a photoisomerisation, ring-closing or dimerization. We show that photoreduction of a perylene bisimide gelator results in the formation of a
Dave J. Adams   +7 more
core   +4 more sources

Fused‐ring induced end‐on orientation in conjugated molecular dyads toward efficient single‐component organic solar cells

open access: yesAggregate, 2023
The molecular orientations of conjugated materials on the substrate mainly include edge‐on, face‐on, and end‐on. Edge‐on and face‐on orientations have been widely observed, while end‐on orientation has been rarely reported.
Dongdong Xia   +8 more
doaj   +1 more source

Controlled aggregation of peptide-substituted perylene-bisimides [PDF]

open access: yesChemical Communications, 2012
Controlled aggregation of perylene bisimides in multiple modes has been achieved via symmetric substitution with peptides. Using optical probes of aggregation, the balance of hydrophobic and electrostatic forces are found to play a key role in directing self assembly and are exploited via solvent, pH, and specific extrinsic ion effects.
Joseph K, Gallaher   +3 more
openaire   +2 more sources

A supramolecular helix that disregards chirality [PDF]

open access: yes, 2016
The functions of complex crystalline systems derived from supramolecular biological and non-biological assemblies typically emerge from homochiral programmed primary structures via first principles involving secondary, tertiary and quaternary structures.
A González-Campo   +63 more
core   +1 more source

Iridium-Catalyzed Direct Tetraborylation of Perylene Bisimides [PDF]

open access: yesOrganic Letters, 2011
Treatment of perylene bisimides (PBIs) with bis(pinacolato)diboron in the presence of an iridium catalyst provides tetraborylated PBIs at 2,5,8,11-positions in good yields with perfect regioselectivity. The planar structure of the perylene core has been confirmed by X-ray diffraction analysis.
Takuro, Teraoka   +2 more
openaire   +3 more sources

Discrete Dimers of Redox-Active and Fluorescent Perylene Diimide-Based Rigid Isosceles Triangles in the Solid State [PDF]

open access: yes, 2019
The development of rigid covalent chiroptical organic materials, with multiple, readily available redox states, which exhibit high photoluminescence, is of particular importance in relation to both organic electronics and photonics. The chemically stable,
Chen, Tianyang   +10 more
core   +8 more sources

Self‐Assembly of Bowl‐Shaped Naphthalimide‐Annulated Corannulene

open access: yesChemistryOpen, 2020
The self‐assembly of a bowl‐shaped naphthalimide‐annulated corannulene of high solubility has been studied in a variety of solvents by NMR and UV/Vis spectroscopy.
Rebecca Renner   +2 more
doaj   +1 more source

Pi‐Stacking Enhances Stability, Scalability of Formation, Control over Flexibility, and Circulation Time of Polymeric Filamentous Nanocarriers

open access: yesAdvanced NanoBiomed Research, 2021
Self‐assembling filomicelles (FMs) are of great interest to nanomedicine due to their structural flexibility, extensive systemic circulation time, and amenability to unique “cylinder‐to‐sphere” morphological transitions.
Sophia Li   +5 more
doaj   +1 more source

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