Results 31 to 40 of about 3,082 (195)
Perylene Bisimide Cyclophanes: Structure–Property Relationships upon Variation of the Cavity Size
Five cyclophanes composed of two perylene bisimide (PBI) dyes and various CH2–arylene–CH2 linker units were synthesized. PM6-D3H4 geometry-optimized structures and a single crystal for one of these cyclophanes reveal well-defined distances between the ...
Jessica Rühe +4 more
doaj +1 more source
Transient Optical Characterisation of Donor-Acceptor Block Copolymers for Use in Solar Cells [PDF]
This thesis presents a study of photo-active, semiconducting block copolymers for use in molecular solar cells. Current state-of-the-art organic devices utilise blends of two (or more) materials that are co-deposited from a common solution; the resulting
King, Simon P., King, Simon P.
core +1 more source
Reversible Photoreduction as a Trigger for Photoresponsive Gels [PDF]
We present here a new type of photoresponsive, reversible low molecular weight gel. All previous examples rely on a photoisomerisation, ring-closing or dimerization. We show that photoreduction of a perylene bisimide gelator results in the formation of a
Dave J. Adams +7 more
core +4 more sources
The molecular orientations of conjugated materials on the substrate mainly include edge‐on, face‐on, and end‐on. Edge‐on and face‐on orientations have been widely observed, while end‐on orientation has been rarely reported.
Dongdong Xia +8 more
doaj +1 more source
Controlled aggregation of peptide-substituted perylene-bisimides [PDF]
Controlled aggregation of perylene bisimides in multiple modes has been achieved via symmetric substitution with peptides. Using optical probes of aggregation, the balance of hydrophobic and electrostatic forces are found to play a key role in directing self assembly and are exploited via solvent, pH, and specific extrinsic ion effects.
Joseph K, Gallaher +3 more
openaire +2 more sources
A supramolecular helix that disregards chirality [PDF]
The functions of complex crystalline systems derived from supramolecular biological and non-biological assemblies typically emerge from homochiral programmed primary structures via first principles involving secondary, tertiary and quaternary structures.
A González-Campo +63 more
core +1 more source
Iridium-Catalyzed Direct Tetraborylation of Perylene Bisimides [PDF]
Treatment of perylene bisimides (PBIs) with bis(pinacolato)diboron in the presence of an iridium catalyst provides tetraborylated PBIs at 2,5,8,11-positions in good yields with perfect regioselectivity. The planar structure of the perylene core has been confirmed by X-ray diffraction analysis.
Takuro, Teraoka +2 more
openaire +3 more sources
Discrete Dimers of Redox-Active and Fluorescent Perylene Diimide-Based Rigid Isosceles Triangles in the Solid State [PDF]
The development of rigid covalent chiroptical organic materials, with multiple, readily available redox states, which exhibit high photoluminescence, is of particular importance in relation to both organic electronics and photonics. The chemically stable,
Chen, Tianyang +10 more
core +8 more sources
Self‐Assembly of Bowl‐Shaped Naphthalimide‐Annulated Corannulene
The self‐assembly of a bowl‐shaped naphthalimide‐annulated corannulene of high solubility has been studied in a variety of solvents by NMR and UV/Vis spectroscopy.
Rebecca Renner +2 more
doaj +1 more source
Self‐assembling filomicelles (FMs) are of great interest to nanomedicine due to their structural flexibility, extensive systemic circulation time, and amenability to unique “cylinder‐to‐sphere” morphological transitions.
Sophia Li +5 more
doaj +1 more source

