Results 41 to 50 of about 23,681 (206)

Photochemical Oxidative Cyclisation of Stilbenes and Stilbenoids—The Mallory-Reaction

Molecules, 2010
After Mallory described in 1964 the use of iodine as catalyst for the photochemical cyclisation of stilbenes, this reaction has proven its effectiveness in the synthesis of phenanthrenes, other PAHs and phenacenes with a surprisingly large selection of ...
Kåre B. Jørgensen
doaj   +1 more source

Ambident Reactivity in the Phenyl + NO Radical Recombination

Chemistry – A European Journal, EarlyView.
ABSTRACT The recombination reaction of nitric oxide (NO) with radicals via its oxygen atom, rather than the more common nitrogen site, offers an intriguing pathway to the formation of oxynitrenes. The photochemical isomerization of nitroso compounds into their corresponding oxynitrenes may involve such a step.
Virinder Bhagat, Adrián Portela‐González, André K. Eckhardt, J. Philipp Wagner   +3 more
wiley   +1 more source

Application of Lanthanide Shift Reagent to the ¹H-NMR Assignments of Acridone Alkaloids

Molecules, 2020
This study investigates the application of the paramagnetic shift reagent tris(dipivaloylmethanato)-europium(III) in NMR spectral studies of permethoxyacridone alkaloids (1–3) and pyranoacridone alkaloids (4–6).
Sio-Hong Lam, Hsin-Yi Hung, Ping-Chung Kuo, Daih-Huang Kuo, Fu-An Chen, Tian-Shung Wu   +5 more
doaj   +1 more source

Tuning the Twist by Molecular Design: A New Strategy for Hexabenzocoronene‐Containing Helical Twistacene

Chemistry – A European Journal, EarlyView.
An efficient Scholl–based strategy enables precise control of the C–C bond to access the first hexabenzocoronene–containing helical twistacene (NG2). The resulting nanographene shows pronounced helical distortion, high stability, enhanced solubility, and promising redox and optoelectronic properties.
Juan P. Mora‐Fuentes, Daniel Villar‐Castro, J. Francisco Barbosa‐de‐Bessa, Daniel Aranda, Frank Hampel, Dolores Pérez, M. Eugenia Pérez‐Ojeda, Diego Peña, Andreas Hirsch   +8 more
wiley   +1 more source

Remarkable effect of alkynyl substituents on the fluorescence properties of a BN-phenanthrene

Beilstein Journal of Organic Chemistry, 2019
A series of BN-phenanthrenes with substituents of a diverse nature have been synthesized by palladium-catalyzed cross-coupling reactions of a common chloro-substituted precursor, which was made from readily available materials in only four steps ...
Alberto Abengózar, David Sucunza, Patricia García-García, Juan J. Vaquero   +3 more
doaj   +1 more source

Chemical Constituents from the Aerial Parts of Cyrtopodium paniculatum

Molecules, 2016
We report the first phytochemical study of the neotropical orchid Cyrtopodium paniculatum. Eight new compounds, including one phenanthrene 1, one 9,10-dihydro-phenanthrene 2, one hydroxybenzylphenanthrene 3, two biphenanthrenes 4–5, and three 9,10 ...
Florence Auberon, Opeyemi Joshua Olatunji, Gaëtan Herbette, Diamondra Raminoson, Cyril Antheaume, Beatriz Soengas, Frédéric Bonté, Annelise Lobstein   +7 more
doaj   +1 more source

Carbon Dots for Cancer Theranostics: Synthesis Strategies, Luminescence Properties, and Advances in Bioimaging‐Guided Diagnosis and Therapy

Chemistry – A European Journal, EarlyView.
Lighting up the path to precision oncology: This review comprehensively summarizes the rational design of carbon dots (CDs), elucidating how core size, surface chemistry, and heteroatom doping dictate their luminescence mechanisms. Special emphasis is placed on engineering NIR‐II emissive CDs for deep‐tissue imaging.
Zekun Yan, Yupeng Liu, Jinyun Tan, Songnan Qu   +3 more
wiley   +1 more source

Cytotoxic effect of selected wild orchids on two different human cancer cell lines

Heliyon, 2020
Majority of the orchid species are used in the traditional medicines for the treatment of several diseases. They are the sources of polysaccharides, phenanthrenes, bibenzyl derivatives, revesteral, stilbenoids and polyphenol compounds.
Pusp Raj Joshi, Mukti Ram Paudel, Mukesh Babu Chand, Shreeti Pradhan, Krishna Kumar Pant, Giri Prasad Joshi, Manoj Bohara, Sven H. Wagner, Basant Pant, Bijaya Pant   +9 more
doaj   +1 more source

Metal‐Free Electrophilic Borylative Cyclizations of Alkynes

The Chemical Record, EarlyView.
Metal‐free borylative cyclizations based on electrophilic alkyne activation by boron Lewis acids provide efficient access to borylated hetero‐ and carbocycles. Early studies using B(C6F5)3 displayed limited scope and application, whereas recent ClBcat‐ and BCl3‐based methods enable mild CB and CC/CX bond formation for the synthesis of cycles ...
Jaime Mateos‐Gil, Marcos Humanes, Manuel A. Fernández‐Rodríguez, Patricia García‐García   +3 more
wiley   +1 more source

Phytochemistry and Biological Activities of Curcuma aeruginosa (Roxb.)

Indonesian Journal of Chemistry, 2022
Curcuma aeruginosa Roxb. is a stemless, aromatic rhizomatous plant, generally characterized by red corolla lobes, purple calyx, dark purple leaf sheath, purple-brown midrib, and greenish-blue rhizome.
Aprilia Permata Sari, Unang Supratman
doaj   +1 more source