Results 51 to 60 of about 3,594 (226)
Dibenzosuberene‐Winged Polycyclic Aromatic Hydrocarbons
The twisted acene 8, which features two dibenzosuberene “wings”, was prepared by the addition of a crowded aryne to a similarly “winged” cyclopentadienone. Compound 8 is chiral, and it has a high barrier to thermal racemization (ΔG‡rac = 36 kcal/mol), but it undergoes fast photochemical racemization even in ambient light.
Mingshu Xie +3 more
wiley +1 more source
At least thirteen parameters relating phenanthrene and methylated phenanthrenes to the maturity of organic matter have been defined in the literature and a mass of the data have been accumulated. However, these parameters are not always effective in many
Xiaotian Huang +4 more
doaj +1 more source
The study is paying attention to the variation of the comparative abundance of naphthalenes, phenanthrenes of aromatic fractions separated from seven different Egyptian crude oils, and were studied by GC–MS to assess the thermal maturity and recognize ...
Eman S. Abdullah +4 more
doaj +1 more source
This thesis focuses on the development of flow photochemical methods, for the synthesis of phenanthrenes, helicenes and benzochromenes. Chapter 1 reviews the literature of triplet aryl cations, which are rarely discussed intermediates in synthetic ...
Wilding-Steele, Luke
core
Pt/C‐Catalyzed Deuteration of Polycyclic Aromatic Hydrocarbons with Suppressed Arene Hydrogenation
An additive‐enabled Pt/C protocol promotes hydrogen–deuterium exchange in fused polycyclic aromatic hydrocarbons (PAHs) in D2O/2‐PrOH at 80 °C. Decalin suppresses undesired ring hydrogenation while accelerating on‐ring H–D exchange, furnishing highly deuterated PAHs (PAHs‐dn).
Naoya Sakurada +6 more
wiley +1 more source
Phenanthrenes from as Novel Phosphodiesterase-5 Inhibitors
Phosphodiesterase 5 (PDE5) inhibitors can be used for the treatment of erectile dysfunction and pulmonary hypertension. In order to search for new leads of PDE5 inhibitors, we investigated the chemical constituents of the tubers of Eulophia macrobulbon ...
Prapapan Temkitthawon +5 more
doaj +1 more source
Extensive Phytochemical Assessment of Hook (Orchidaceae)
Dendrobium fimbriatum Hook is an important medicinal and ornamental orchid that may lead to important drugs and cosmetics. In this study, 2 analytical strategies were combined to describe the detailed composition of a hydroethanolic extract of the whole ...
Quentin Favre-Godal +8 more
doaj +1 more source
Dendrobium officinale, a well-known plant used as a medicinal and food homologous product, has been reported to contain various bioactive components, such as polysaccharides, bibenzyls, phenanthrenes, and flavonoids.
Wenhua Chen +6 more
doaj +1 more source
Palladium-catalyzed cocyclotrimerization of allenes with arynes has been developed for selectively synthesizing phenanthrenes. In the presence of [(allyl)PdCl]2 and P(o-tol)3, a variety of allenes, including internal and terminal allenes, underwent the ...
Shao-Feng Pi (2297335) +4 more
core +1 more source

