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Dissociation of phenols and phenolate salts and homocomplexation in the corresponding phenol–phenolate systems in benzonitrile

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1985
The acidities of 12 substituted phenols (pKBNa relative to the pKBNa of HClO4) and the formation constants of the corresponding homocomplexes, KAHA, in benzonitrile have been determined from e.m.f. measurements. Comparison with previous results reveals that the stability of homocomplexes increases in aprotic solvents in the order acetonitrile ...
Józef Magoński   +2 more
openaire   +2 more sources

Phenol and substituted phenols AOPs remediation

Journal of Hazardous Materials, 2005
The oxidation of phenol and two substituted species (4-nitrophenol and 4-chlorophenol) has been carried out by means of the O3, UV-vis, O3+UV-vis, TiO2+UV-vis, O(3)+UV-vis+TiO2 and O3+TiO2 systems. From UV-vis experiments, the quantum yield of these organics has been calculated (0.018, 0.005 and 0.017 mol per Einstein for phenol, 4-nitrophenol and 4 ...
Fernando J. Beltrán   +3 more
openaire   +3 more sources

Asymmetric dearomatization of phenols.

Organic and biomolecular chemistry, 2016
This review summarizes the recent advances in the field of asymmetric dearomatization of phenols and their applications in the total synthesis of some complex natural products.
Wangsheng Sun   +3 more
semanticscholar   +1 more source

Phenol Peeling and the History of Phenol Peeling

Clinics in Plastic Surgery, 1998
Historically, phenol peeling has been embraced by plastic surgeons as the method of choice for improving the appearance of coarse facial rhytides. The principal advantage of phenol peeling is its predictability: it requires no pretreatment regime. This article details the technical aspects of phenol peeling, its uses and limitations, as well as methods
openaire   +5 more sources

(C6 F5 )3 B Catalyzed Chemoselective and ortho-Selective Substitution of Phenols with α-Aryl α-Diazoesters.

Angewandte Chemie, 2016
The development of an efficient method for the site-selective substitution of unprotected phenols has long been considered as an attractive but challenging task.
Zhu Yu   +5 more
semanticscholar   +1 more source

Chemoselective Asymmetric Intramolecular Dearomatization of Phenols with α-Diazoacetamides Catalyzed by Silver Phosphate.

Journal of the American Chemical Society, 2017
We report asymmetric dearomatization of phenols using Ag carbenoids from α-diazoacetamides. The Ag catalyst promoted intramolecular dearomatization of phenols, whereas a Rh or Cu catalyst caused C-H insertion and a Büchner reaction.
Hiroki Nakayama   +3 more
semanticscholar   +1 more source

Silver‐Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers

Angewandte Chemie - International Edition, 2015
Aryl trifluoromethyl ethers (ArOCF3 ) are prevalent in pharmaceuticals, agrochemicals, and materials. However, methods for the general and efficient synthesis of these compounds are extremely underdeveloped and limited.
Chao Chen, Lingling Chu, Xiu-hua Xu
exaly   +2 more sources

Carboxylation of Phenols with CO2 at Atmospheric Pressure.

Chemistry, 2016
A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2 ...
Junfei Luo   +3 more
semanticscholar   +1 more source

Atheroprotective effects of (poly)phenols: a focus on cell cholesterol metabolism.

Food & Function, 2015
Collated observations from several epidemiological studies have demonstrated that dietary intake of (poly)phenols from nuts, coffee, cocoa, grapes, and berries may protect against the development of atherosclerosis.
I. Zanotti   +6 more
semanticscholar   +1 more source

Microbial Degradation of Phenol and Phenolic Compounds

2021
Phenol and phenolic compounds play an essential role in various modern-day industries. However, due to the toxic and recalcitrant nature of phenolic compounds, these compounds have a detrimental effect on the environment and aquatic life. In the recent past, different physicochemical methods have been employed by various researchers for phenol ...
Milan Malhotra   +3 more
openaire   +2 more sources

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