Results 31 to 40 of about 174,345 (147)

Molecular cloning and expression of the phenoxazinone synthase gene from Streptomyces antibioticus.

open access: yesJournal of Biological Chemistry, 1984
DNA fragments from the Streptomyces antibioticus genome have been cloned in Streptomyces lividans using the SphI site of the vector, pIJ702. Using a sib selection procedure, transformants were screened for their ability to produce levels of the enzyme, phenoxazinone synthase, which were detectable by enzyme assay.
G H, Jones, D A, Hopwood
openaire   +2 more sources

Functional study of Phaeodactylum tricornutum Seipin highlights specificities of lipid droplets biogenesis in diatoms

open access: yesNew Phytologist, Volume 247, Issue 5, Page 2245-2269, September 2025.
Summary Diatoms are a major phylum of microalgae, playing crucial ecological roles. They derive from secondary endosymbiosis, leading to a complex intracellular architecture. Their ability to store oil in lipid droplets (LDs) upon unfavourable conditions has raised interest for applications, in particular biofuels, yet Lipid Droplet (LD) biogenesis ...
Damien Le Moigne   +20 more
wiley   +1 more source

Beyond Phenolics: Alternative Substrates for Type III Copper Enzymes

open access: yesChemBioChem, Volume 26, Issue 7, April 1, 2025.
The copper‐containing metalloenzyme tyrosinase is well known for synthesis of melanin pigments and enzymatic browning of fruits and vegetables. These reactions proceed from phenolics, but tyrosinases can also convert aromatic amines. This perspective brings together the scarce data on the enzymatic conversion of non‐phenolic substrates by these ...
Matthias Pretzler, Annette Rompel
wiley   +1 more source

Synthesis and characterization of a new 4-styrylpyridine based square planar copper(II) complex: exploration of phenoxazinone synthase-mimicking activity and DFT study

open access: yes, 2019
A new 4-styrylpyridine (4-spy)-based square planar copper(II) complex, [Cu(4-spy)2(NCS)2] {4-spy = 4-styrylpyridine} (1), has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction study. The complex crystallizes in
Mohammad Hedayetullah Mir (2422363)   +5 more
core   +1 more source

Importance of C–H⋯π interactions in stabilizing the syn/anti arrangement of pendant alkoxy side arms in two manganese(iv) Schiff base complexes: exploration of catechol oxidase and phenoxazinone synthase like activities

open access: yes, 2017
Two manganese(iv) complexes have been prepared and characterized. Both complexes exhibit catechol oxidase and phenoxazinone synthase like activities.
Antonio Frontera   +3 more
core   +1 more source

Redox‐Induced Aromatic Substitution: A Study on Guanidino‐Functionalized Aromatics

open access: yesChemistry – A European Journal, Volume 30, Issue 72, December 23, 2024.
Oxidation of a redox‐active aromatic molecule leads to an umpolung from a nucleophile to an electrophile, enabling addition of a nucleophile as part of an aromatic substitution. Thereby a variety of new, non‐symmetrically substituted redox‐active compounds could be synthesized.
Ute Wild   +4 more
wiley   +1 more source

Influence of the first and second coordination spheres on the diverse phenoxazinone synthase activity of cobalt complexes derived from a tetradentate Schiff base ligand

open access: yes, 2017
Cobalt complexes as functional models for phenoxazinone synthase showing the influence of both first and second order coordination spheres on the catalytic activity and important intermediates in the ESI mass spectrum providing better information on the ...
Narayan Ch. Jana   +2 more
core   +1 more source

Synthesis, spectroscopic depiction and phenoxazinone synthase activity by a cobalt(II) complex

open access: yes, 2019
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723 104, West Bengal, India Department of Chemistry, University of North Bengal, Darjeeling-734 013, West Bengal, India E-mail: mr.bbiswas@rediffmail.com, icbbiswas@gmail.com Department of Chemistry, University of Kalyani, Kalyani-741 235, West Bengal, India Manuscript received online 29 ...
Ajit Das   +5 more
openaire   +1 more source

C-S bond cleavage influenced by metal coordination in Zn(II) bound Schiff base complex: synthesis, structural characterization, catecholase and phenoxazinone synthase activities [PDF]

open access: yes, 2018
1351-1357A new zinc(II) Schiff base complex (1) has been synthesized and X-ray crystallographically characterized. It crystalizes in P2/c space group with monoclinic crystal system.
Purohit, Chandra Shekhar   +4 more
core  

An iron(III)-Schiff base complex as a functional model of phenoxazinone synthase enzyme

open access: yes, 2017
Department of Chemistry, Raghunathpur College, Purulia-723 133, West Bengal, India E-mail : mr.bbiswas@rediffmail.com Department of Chemistry, Vivekananda Mahavidyalaya, Burdwan-713 104, West Bengal, India Manuscript received online 26 December 2015, accepted 02 November 2016 A new iron(III) complex, [Fe(L)Cl2 (H2O)] (1) containing a (N,O,Cl)-donor ...
Bhaskar Biswas, Partha Sarathi Sengupta
openaire   +1 more source

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