Results 31 to 40 of about 1,180 (161)
Tuning the Catalytic Properties of UiO-66 Metal-Organic Frameworks: From Lewis to Defect-Induced Bronsted Acidity [PDF]
[EN] The Lewis/Bronsted acidity and catalytic properties of UiO-66-type metal-organic frameworks are studied in the context of tunable acid catalysts based on the presence of linker defects that create coordinatively unsaturated Zr4+ centers.
Cirujano, F. G. +1 more
core +2 more sources
ABSTRACT Hyperammonemia is a medical emergency, and the cause must be identified quickly in order to treat appropriately. Malnutrition is a known risk factor for hyperammonemia; however, there are limited reliable lab indicators used to identify malnutrition.
M. M. Crenshaw +12 more
wiley +1 more source
The molecule of the title compound, C35H52O2, adopts an extended conformation, with the phenylacetate group twisted by 69.3 (1)° from the least-squares plane of the tetracyclic ring system. In the crystal structure, the molecules are aligned in an antiparallel fashion to form alternate layers.
openaire +1 more source
Amino acetate functionalized Schiff base organotin(IV) complexes as anticancer drugs: synthesis, structural characterization, and in vitro cytotoxicity studies [PDF]
Summary: Potassium 2-{[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)]amino}-4-methyl-pentanoate (L1HK) and potassium 2-{[(E)-1-(2-hydroxyphenyl)alkylidene]amino}-4-methyl-pentanoates (L2HK-L3HK) underwent reactions with PhnSnCl4-n (n = 2 and 3) to give the ...
Basu Baul, Tushar +3 more
core
ABSTRACT Ornithine transcarbamylase (OTC) deficiency can present during the neonatal period, infancy, or adulthood. Late‐onset phenotypes are influenced by residual enzyme activity and OTC gene expression. The objective of this study was to assess the pathogenicity of a rare promoter region variant, c.‐106C>A.
Samuel Quinn Tholl +9 more
wiley +1 more source
Conversion of Lignin to Heat and Power, Chemicals or Fuels into the Transition Energy Strategy [PDF]
Energy transition toward low carbon, high sustainable and efficient generation and distribution systems will change the supply matrix of the world and create new opportunities but challenges still remain.
Aburto, Jorge +1 more
core +1 more source
In this study, fermentation was performed with Kuding tea and glutinous rice as raw materials and different yeast strains (L254 (Saccharomyces cerevisiae), FBKL2.0235 (Trichomonascus ciferrii), and Angel yeast). The fermentation characteristics and the volatile and nonvolatile components of Kudingcha rice wine were analyzed by examining physical and ...
Xiaoye Luo +9 more
wiley +1 more source
Drug Discovery Applications of Nitroso (Hetero)Arene Derivatives
Nitroso (hetero)aromatic compounds are bioactive molecules with antiviral, anticancer, neuroprotective, and antimicrobial properties. This review highlights their mechanisms of action—oxidative stress, DNA damage, and enzyme inhibition—alongside synthesis, structure–activity relationships, and toxicity challenges, offering insight into their ...
Silvia Roscales, Aurelio G. Csáky
wiley +1 more source
Formation of quaternary carbons through cobalt-catalyzed C(sp3)–C(sp3) Negishi cross-coupling [PDF]
Formation of all-carbon-substituted quaternary carbons is a key challenge in organic and medicinal chemistry. We report a cobalt-catalyzed C(sp3)–C(sp3) cross-coupling that allows for the introduction of benzyl, heteroarylmethylzinc and allyl groups to ...
Alcazar, Jesus +5 more
core +2 more sources
C‐Acylation of Guaiacol with Acetic Acid Over Solid Acid Catalysts Under Mild Reaction Conditions
Direct acylation of guaiacol (G) with acetic acid (AA) over Aquivion® PW87 under mild conditions affords 4‐hydroxy‐3‐methoxyacetophenone (p‐HMAP) with a remarkable para/ortho molar ratio of 26:1. Combined DFT and experimental studies reveal an acid‐catalyzed intermolecular acyl transfer via 2‐methoxyphenyl acetate (MPA), enabling a highly selective and
Nicola Schiaroli +3 more
wiley +1 more source

