Water-Catalytic Deconstructive and Proton Transfer Cyclopropanation of Sulfoxonium Ylide with Olefin. [PDF]
Water‐catalytic deconstructive and proton transfer cyclopropanation of sulfoxonium ylide with olefin is developed through a sequential water‐mediated ring‐closing/opening reaction. This atom‐economical, environmentally friendly methodology offers easy access to a range of cyclopropyl ketones with moderate to good yields.
Yu X, Huang L, Yang H, Song L, Jin Y.
europepmc +2 more sources
Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes [PDF]
Transfer hydrogenolysis of 5-allyloxy- 1-phenyltetrazoles using either a heterogeneous or a homogeneous palladium catalyst and a hydrogen donor leads to cleavage of the allyloxy C-O bond to yield an alkane or an alkene and 1-phenyltetrazolone, depending ...
Cristiano, Maria Lurdes Santos +2 more
core +1 more source
Phenyl radical + propene: a prototypical reaction surface for aromatic-catalyzed 1,2-hydrogen-migration and subsequent resonance-stabilized radical formation [PDF]
The C[subscript 9]H[subscript 11] potential energy surface (PES) was experimentally and theoretically explored because it is a relatively simple, prototypical alkylaromatic radical system.
Buras, Zachary +5 more
core +1 more source
Trace evidence of trans-phenylpropene as a marker of smoked methamphetamine. [PDF]
This case study investigates trans-phenylpropene as a potential marker for smoked methamphetamine. The decedent, a 31-year-old male, was found with paraphernalia that indicated that he may have been smoking abused drugs prior to death. Methamphetamine and cocaine were detected in the residue remaining in the paraphernalia.
Diaá M. Shakleya +4 more
semanticscholar +3 more sources
Liver cancer is one of the most frequent tumor entities worldwide, which is causally linked to viral infection, fatty liver disease, life-style factors and food-borne carcinogens, particularly aflatoxins.
Max J. Carlsson +14 more
doaj +1 more source
Chemical composition and product quality control of turmeric (Curcuma longa L.) [PDF]
Chemical constituents of various tissues of turmeric (Curcuma longa L.) have been extensively investigated. To date, at least 235 compounds, primarily phenolic compounds and terpenoids have been identified from the species, including 22 diarylheptanoids ...
Aggarwal, Bharat +5 more
core +2 more sources
Antimicrobial and antibiofilm activity and machine learning classification analysis of essential oils from different mediterranean plants against pseudomonas aeruginosa [PDF]
Pseudomonas aeruginosa is a ubiquitous organism and opportunistic pathogen that can cause persistent infections due to its peculiar antibiotic resistance mechanisms and to its ability to adhere and form biofilm.
Artini, Marco +10 more
core +2 more sources
Isoeugenol has a non-Disruptive Detergent-like Mechanism of Action
Isoeugenol is an essential oil constituent of nutmeg, clove, and cinnamon. Despite isoeugenol’s promising antimicrobial activity, no studies have yet investigated its mode of antibacterial action at the molecular level.
Morten eHyldgaard +6 more
doaj +1 more source
Organic reactions mediated by electrochemically generated ArS+. [PDF]
Low-temperature electrochemical oxidation of ArSSAr was carried out to generate a pool of "ArS(+)". Spectroscopic studies ((1)H NMR and CSI-MS) of the resulting solution revealed the accumulation of ArS(ArSSAr)(+).
Matsumoto, Kouichi +2 more
core +1 more source
Essential oils obtained via the hydrodistillation of two Asian herbs (Houttuynia cordata and Persicaria odorata) were analyzed by gas chromatography coupled to mass spectrometry (GC–MS) and gas chromatography with flame ionization detector (GC–FID ...
Kristýna Řebíčková +5 more
doaj +1 more source

