Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL
Cyclic gallaphosphene 1 undergoes a twofold E─H bond activation with ammonia and water via a beneficial interplay between the polar “GaPGa” unit and the electrophilic nature of the C center in the bridging PCO unit, yielding six‐membered heterocycles 2 and 3, in which both nucleophilic phosphorus atoms are protonated.
Mahendra K. Sharma +3 more
wiley +2 more sources
Primitive Ligands Drive 1D CsPbI3 Nanostructures with Strongly Polarized Photoluminescence
This work illustration highlights I− concentration drives the structural evolution of CsPbI3 from cubic to orthorhombic phase, accompanied by octahedral distortion. In addition, increasing I− transforms nanorods into ginkgo‐leaf‐like assemblies, including a 659–683 nm PL redshift due to bandgap narrowing and strain effects.
Juan Xie +12 more
wiley +2 more sources
Directing Cation Coordination and Phase in Nickel Sulfide Nanocrystals through the Addition of Phosphines. [PDF]
Endres EJ +3 more
europepmc +1 more source
Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation
From redox numbers to red light: Donor oxidation and core reduction potentials predict E0‐0 in cyanoarene dyes, guiding selection of an efficient red‐light catalyst, 4MeODPATPN (PC13). Under 620 nm light, PC13 facilitates Ni‐catalyzed C─heteroatom cross‐couplings (C─N, C─O, C─S) with high functional‐group tolerance and reduced hydrodehalogenation ...
Amir Gizatullin +6 more
wiley +2 more sources
Nickel Phosphine Complexes: Synthesis, Characterization, and Behavior in the Polymerization of 1,3-Butadiene. [PDF]
Guelfi M +7 more
europepmc +1 more source
Activation of Cyanate Anions by Phosphine Radical Cations Enables Formal Hydrocarbamoylation of Alkenes. [PDF]
Vojáčková P, Studer A.
europepmc +1 more source
The Phosphine- Aryldiethynyls(-CC(Ar)CC-)-gold(I)-gold(III)- Complexes: Synthesis and spectral study
Prithwiraj Byabartta
openalex +1 more source
Design of Phosphine-Heteroarenesulfonamide Ligands as Dinuclear Silver Catalysts for Enantioselective Construction of α,β-Diamino Acids. [PDF]
Iizuka Y +6 more
europepmc +1 more source
Reductive rearrangement of substituted quinolines to 2,3-disubstituted indoles enabled by water activation. [PDF]
Spreckelmeyer N +5 more
europepmc +1 more source

