Results 171 to 180 of about 157,779 (296)

Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL

open access: yesAngewandte Chemie, EarlyView.
Cyclic gallaphosphene 1 undergoes a twofold E─H bond activation with ammonia and water via a beneficial interplay between the polar “GaPGa” unit and the electrophilic nature of the C center in the bridging PCO unit, yielding six‐membered heterocycles 2 and 3, in which both nucleophilic phosphorus atoms are protonated.
Mahendra K. Sharma   +3 more
wiley   +2 more sources

Primitive Ligands Drive 1D CsPbI3 Nanostructures with Strongly Polarized Photoluminescence

open access: yesAngewandte Chemie, EarlyView.
This work illustration highlights I− concentration drives the structural evolution of CsPbI3 from cubic to orthorhombic phase, accompanied by octahedral distortion. In addition, increasing I− transforms nanorods into ginkgo‐leaf‐like assemblies, including a 659–683 nm PL redshift due to bandgap narrowing and strain effects.
Juan Xie   +12 more
wiley   +2 more sources

Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation

open access: yesAngewandte Chemie, EarlyView.
From redox numbers to red light: Donor oxidation and core reduction potentials predict E0‐0 in cyanoarene dyes, guiding selection of an efficient red‐light catalyst, 4MeODPATPN (PC13). Under 620 nm light, PC13 facilitates Ni‐catalyzed C─heteroatom cross‐couplings (C─N, C─O, C─S) with high functional‐group tolerance and reduced hydrodehalogenation ...
Amir Gizatullin   +6 more
wiley   +2 more sources

Nickel Phosphine Complexes: Synthesis, Characterization, and Behavior in the Polymerization of 1,3-Butadiene. [PDF]

open access: yesMolecules
Guelfi M   +7 more
europepmc   +1 more source

Intracellular disulfide reduction by phosphine-borane complexes: Mechanism of action for neuroprotection

open access: green, 2016
Nicholas J. Niemuth   +4 more
openalex   +1 more source

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