Results 31 to 40 of about 19,048 (288)

Synthesis and photophysical properties of novel benzophospholo[3,2-b]indole derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2017
The parent benzophospholo[3,2-b]indole was prepared by the reaction of dichlorophenylphosphine with a dilithium intermediate, which was prepared in two steps from 2-ethynyl-N,N-dimethylaniline.
Mio Matsumura   +7 more
doaj   +1 more source

Perspective Phosphine oxide additives for perovskite diodes and solar cells

open access: yes, 2023
Lead halide perovskites have been considered promising semicon-ducting materials for next-generation optoelectronic devices due to their solution processability and excellent optoelectronic proper-ties.
Huang, Jing,   +3 more
core   +1 more source

Catalyst-free photooxidation of triarylphosphines under aerobic conditions

open access: yesJournal of Saudi Chemical Society, 2015
A new method for the photooxidation of triarylphosphines into the corresponding oxides is developed. In this new protocol, neither a catalyst nor an additive is required. The greenest oxidant, oxygen in air atmosphere, is used.
Aishun Ding   +5 more
doaj   +1 more source

Triesters of tris-(hydroxymethyl)phosphine oxide

open access: yes, 1965
A series of tri-acylated and tri-arylated tris(hydroxymethyl)phosphine oxide derivatives was prepared either from tris-(hydroxymethyl)phosphine oxide or from tris-(iodomethyl)phosphine ...
Anteunis, Marc   +2 more
core   +1 more source

Ni-Catalyzed Enantioselective Benzylation of Secondary Phosphine Oxide

open access: yes, 2022
A nickel-catalyzed benzylic substitution of secondary phosphine oxide was described, affording the dialkylated P-stereogenic tertiary phosphine oxides with high to excellent enantioselectivities.
Qi Wei (198826)   +5 more
core   +1 more source

Phenolic 3° Phosphine Oxides as a Class of Metal-Free Catalysts for the Activation of C–O Bonds in Aliphatic Alcohols: Direct Synthesis of Catalyst Candidates, and Kinetic Studies

open access: yesInorganics, 2022
It was recently reported that a (2-hydroxybenzyl)phosphine oxide (2-HOBPO) can serve as a phosphorus-centered catalyst for the stereo-invertive coupling of aliphatic alcohols and acidic pronucleophiles (akin to a Mitsunobu reaction, but without ...
Matthew A. Martin   +5 more
doaj   +1 more source

Mild and efficient copper-catalyzed N-arylation of alkylamines and N-H heterocycles using an oxime-phosphine oxide ligand

open access: yes, 2005
A mild and efficient copper-catalyzed system for N-arylation of alkylamines and N-H heterocycles with aryl iodides using a novel, readily prepared and highly stable oxime-functionalized phosphine oxide ligand was developed.
Xu, L   +5 more
core   +1 more source

Evolutionarily divergent DUF4465 domains have a common vitamin B12‐binding function

open access: yesFEBS Open Bio, EarlyView.
We show that DUF4465 family proteins, widespread across bacteria from gut microbiomes, hydrothermal vents, and soil, share a common vitamin B12‐binding function. These augmented β‐jellyroll proteins bind vitamin B12 via extended loops. Our findings establish sequence‐diverse DUF4465 proteins as a widespread class of B12‐binding proteins, highlighting ...
Charlea Clarke   +4 more
wiley   +1 more source

Interactions of phosphate, phosphine oxide and phosphoramide ligands with Th(IV)

open access: yesResults in Chemistry
The complexation behavior of phosphate, phosphine oxide, and phosphoramide ligands with Th(IV) is investigated at the Density Functional Theory (DFT) level.
Aditya Ramesh Sachin   +2 more
doaj   +1 more source

A mild and efficient copper-catalyzed coupling of aryl iodides and thiols using an oxime-phosphine oxide ligand

open access: yes, 2006
A mild and efficient copper-catalyzed system for the coupling of aryl iodides and thiols was developed using a readily prepared and highly stable oxime-phosphine oxide ligand. Good to excellent yields were obtained. (c) 2006 Elsevier Ltd.
Wu, Fan   +4 more
core   +1 more source

Home - About - Disclaimer - Privacy