Results 131 to 140 of about 14,313 (278)

Stretchable Energy Storage with Eutectic Gallium Indium Alloy

open access: yesAdvanced Energy Materials, Volume 15, Issue 11, March 18, 2025.
A highly stretchable liquid metal‐based electrode is developed via a one‐step process, retaining conductivity and capacitance after mechanical deformation up to 900% strain. The stretchable all‐solid‐state device provides a areal energy density of 43 µWh cm⁻2 after 150% strain.
Adit Gupta   +6 more
wiley   +1 more source

An Iridium Distannylidyne – Expanding the Scope of Tetrylidyne Transition Metal Coordination Chemistry

open access: yesAngewandte Chemie, EarlyView.
This work presents the synthesis, characterization, and reactivity of an iridium distannylidyne as the first heavy transition metal ditetrylidyne. Characterized by its short Ir─Sn bonds and linear bonding angles at the tin atoms, this compound displays versatile reactivity toward carbon dioxide and trimethylsilyl azide.
Lennart G. Holzapfel   +6 more
wiley   +2 more sources

Amorphous π‐Conjugated Passivator Facilitates Widening Process Window for Reliable Perovskite Solar Modules

open access: yesAdvanced Energy Materials, EarlyView.
A wide process window is essential for the commercialization of perovskite photovoltaics. Here, we demonstrate an amorphous π‐conjugated passivator having an asymmetric mono‐iodine substituent on a carbazole moiety imparts a high dipole moment, desirable molecular energy levels, and high thickness tolerance, thereby enabling a wide process window in ...
Hyun Seo Kim   +17 more
wiley   +1 more source

Mechanistic Control of Cathode–Electrolyte Interphase Formation in Gel Polymer Electrolyte for Lithium‐Ion Batteries

open access: yesAngewandte Chemie, EarlyView.
To regulate a distinct degradation pathway introduced by residual monomers in in‐situ gel polymer electrolytes (GPEs), tris(4‐fluorophenyl)phosphine (TFPP) is coupled with a voltage hold (VH) protocol. TFPP first covers the high‐Ni cathode surface and then preferentially decomposes during the hold step, forming a cathode–electrolyte interphase (CEI ...
Sang Goo Kang   +4 more
wiley   +2 more sources

Automated Alignment Powered by Computer Vision Streamlines the Two‐Photon Polymerization‐Based Micro 3D Printing of Multiscale and Multimaterial Structures

open access: yesAdvanced Intelligent Discovery, EarlyView.
Two‐photon polymerization enables high‐resolution microfabrication, but performing alignment when printing multiple structures is difficult. Here, we present a fast, robust, and open‐source protocol for automated alignment on Nanoscribe systems. Achieving ≈0.4 μm accuracy in under 5 s, our protocol reduces time and error in multimaterial printing. This
Daniel Maher   +4 more
wiley   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

open access: yesAngewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang   +1 more
wiley   +2 more sources

Catalyst‐Specialized Chemical Language Model Based on Transformer Variational Autoencoder for Catalyst Design and Discovery

open access: yesAdvanced Intelligent Discovery, EarlyView.
We present CatTransVAE, a catalyst‐specialized chemical language model (CLM) built on a transformer variational autoencoder (VAE), developed through pretraining on general compounds followed by fine‐tuning on diverse catalyst databases. A template‐guided generation framework is introduced to enable controlled catalyst design under structural ...
Apakorn Kengkanna, Masahito Ohue
wiley   +1 more source

P‐Directed and Lewis Acid‐Assisted Pd‐Catalyzed Si─Me Bond Activation Enabling Alkyl Exchange at Silicon

open access: yesAngewandte Chemie, EarlyView.
A new type of Si─Me bond activation enabling catalytic alkyl exchange at Si was developed. It involves a P‐directing group and Pd─Lewis acid cooperation. It enables the conversion of Me3SiCl into silanols with three different organic substituents. ABSTRACT A novel mode of Si─Me bond activation has been unveiled through the cooperative action of a P ...
Hajime Kameo   +5 more
wiley   +2 more sources

Functional Polymer‐Engineered Magnetic Nanoparticles as Dual‐Modal Theragnostic Probes for Early Alzheimer's Disease Detection and Therapy

open access: yesAdvanced NanoBiomed Research, EarlyView.
The nanoparticle consists of a 3 nm iron oxide core functionalized with an amphiphilic polymer coating containing Aβ‐targeting DSA moieties and biocompatible PEG chains. This design supports measurable transport in a BBB‐related model and specific interaction with Aβ species, while providing MRI contrast enhancement for diagnosis and therapeutic ...
Ao Shen   +8 more
wiley   +1 more source

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