Results 161 to 170 of about 12,297 (288)

N-H/P-H bond activation of ammonia, amines and phosphines at a transient borylene. [PDF]

Chem Sci
Weber M, Kar S, Joos P, Dewhurst RD, Braunschweig H.   +4 more
europepmc   +1 more source

Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges

Angewandte Chemie International Edition, EarlyView.
Controlling biological systems with small‐molecule chromophores has evolved into a powerful strategy and is applied from chemical biology to medicine. However, the complexity of in vivo systems cannot be matched by a single wavelength of light. Developing methods to combine and individually control multiple chromophores is crucial.
Nadja A. Simeth
wiley   +1 more source

Enantioselective Iridium-Catalyzed C-H Bond Alkylation for the Synthesis of N-N Atropisomeric Phosphines. [PDF]

J Am Chem Soc
Fu SH, Pang RJ, Yue Y, Xi LL, Feng J, Liu RR.   +5 more
europepmc   +1 more source

Electron Donor-Acceptor Chromophore Assembly as an Enabling Process for the Overall Light-Driven Reduction of Phosphine Oxides. [PDF]

Org Lett
Tran TT, Arkhypchuk AI, Orthaber A, Ott S.   +3 more
europepmc   +1 more source

Directing Cation Coordination and Phase in Nickel Sulfide Nanocrystals through the Addition of Phosphines. [PDF]

Chem Mater
Endres EJ, Chen Y, Jiang DE, Macdonald JE.   +3 more
europepmc   +1 more source

Secondary Phosphines Bearing N-Heterocyclic Imine Groups: Polarity Umpolung of Highly Electron-Rich P-H Bonds. [PDF]

Inorg Chem
Röthel MB, Eder T, Brylak F, Seidl M, Löwe P, Dielmann F.   +5 more
europepmc   +1 more source

Selectivity for Exhaustive Cross-Coupling of Dihaloarenes is Affected by the Interplay Between Halide Byproduct, Solvent, and Ligand. [PDF]

Organometallics
Larson NG, Sandin MP, Neufeldt SR.
europepmc   +1 more source

Unlocking Catalyst Activation as a Critical Bottleneck in Cross‐Coupling Reactions: Room‐Temperature Couplings of Weak Nucleophiles Enabled by [Pd(1‐MeNAP)TFA]2 Precatalysts

Angewandte Chemie International Edition, EarlyView.
In many Pd‐catalyzed cross‐couplings, catalyst performance has been found to be limited by catalyst activation. Methylnaphthyl (MeNAP) palladium trifluoroacetate dimers are presented as easy‐to‐store and easy‐to‐handle precursors, which rapidly activate under reaction conditions, even when only weakly coordinating, non‐reducing nucleophiles are present.
Sourav Manna, Henric F. Janning, Nikolaos V. Tzouras, Jane Anto Simplica Sagayaraj, Fadil Faizal Mannighayil, Angelino Doppiu, Lukas J. Gooßen   +6 more
wiley   +1 more source

The organophosphorus synthesis triangle: introducing methods for the missing quaternization and de-quaternization routes. [PDF]

Chem Sci
Vetter AC, Ortin Y, Nikitin K, Gilheany DG.   +3 more
europepmc   +1 more source

Insertion of CO₂, Isocyanates, and Acetonitrile into the P-Si Bond of a Silyl-Substituted <i>N</i>‑Heterocyclic Carbene Phosphinidene. [PDF]

Organometallics
Hochholzer A, Doleschal ME, Chakraborty P, Inoue S.   +3 more
europepmc   +1 more source