Results 181 to 190 of about 76,679 (335)

An Electrochemical Study of Key Catalytically Active Gold Complexes

open access: yesAngewandte Chemie, EarlyView.
A systematic electrochemical investigation of Au(I) complexes sheds light on how ligand environments control gold oxidizability. Through cyclic voltammetry and density functional theory (DFT) analysis, key trends are established for phosphine, N‐heterocyclic carbene (NHC), and hemilabile P^N ligands, offering valuable insights into the design of ...
Emma Baubiat   +4 more
wiley   +2 more sources

Catalytic 1,2‐Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes

open access: yesAngewandte Chemie, EarlyView.
We report a multicomponent reaction involving an aryl halide, an aldehyde, and a silane derivative, facilitated by low‐valent bismuth redox catalysis under mild conditions. The protocol represents an unprecedented example of four elementary organometallic steps at a Bi center within the catalytic cycle.
Xiangrong Liu   +4 more
wiley   +2 more sources

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