Results 101 to 110 of about 54,764 (213)

Self‐assembly and Lateral Cobalt Coordination of a Fivefold Symmetric Cyanostar Macrocycle on an Au(111) Surface

open access: yesChemistry – A European Journal, EarlyView.
Herein, we report the first example of the formation of a close‐packed, regular 2D monolayer of a fivefold symmetric cyanostar macrocycle on an Au(111) surface under ultra‐high vacuum and the structural modification of such self‐assembled architecture upon cobalt atom deposition.
Lenka Černá   +11 more
wiley   +1 more source

Synthesis of diversely functionalised 2,2-disubstituted oxetanes: fragment motifs in new chemical space [PDF]

open access: yes, 2015
Novel oxetane motifs incorporating diverse functional groups on the ring are readily accessed by an O–H insertion/cyclisation strategy.
Bull, JA, Croft, RA, Davis, OA
core   +1 more source

Self‐Immolative Gels: Programmable Degradation Using Self‐Immolative Linkers and Polymers

open access: yesChemistry – A European Journal, EarlyView.
Self‐immolative linkers and polymers undergo bond‐cleaving reaction cascades in response to specific stimuli. Their incorporation into gels can be harnessed to release cargo, induce property changes, or trigger degradation in a highly controlled manner. These functions can be employed in applications such as sensing and drug delivery.
Chuanfeng Li, Elizabeth R. Gillies
wiley   +1 more source

One-step nonhydrolytic sol–gel synthesis of mesoporous TiO2 phosphonate hybrid materials

open access: yesBeilstein Journal of Nanotechnology, 2019
Mesoporous TiO2–octylphosphonate hybrid materials were prepared in one step by a nonhydrolytic sol–gel method involving the reaction of Ti(OiPr)4, acetophenone (2 equiv) and diethyl octylphosphonate (from 0 to 0.2 equiv) at 200 °C for 12 hours, in ...
Yanhui Wang   +2 more
doaj   +1 more source

Flame‐Retardant Bio‐Based Thermo‐Flexible Phase‐Change Composites with Antivibration and Low‐Contact Resistance for Advanced Battery Thermal Management

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Flame‐retardant bio‐based thermo‐flexible phase‐change composites for advanced battery thermal management. Batteries face critical challenges in thermal management, including overheating risks, poor interfacial contact, and mechanical vibration–induced performance attenuation.
Shichao Feng   +7 more
wiley   +1 more source

A Highly Stable Zinc‐Mimosinate Metal–Organic Framework for Controlled Agrochemical Delivery

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The graphical abstract illustrates the design of metal–organic frameworks (MOFs) as agrochemicals constructed from active building blocks. The highly robust GR‐MOF‐25 is assembled from the natural herbicide L‐mimosine and Zn2+ ions, combining herbicidal, micronutrient, and antibacterial properties.
MCarmen Contreras   +4 more
wiley   +1 more source

Memory of Chirality in Radical Addition–Translocation–Cyclization Cascades

open access: yesHelvetica Chimica Acta, EarlyView.
Radical addition–translocation–cyclization cascades of chiral alkynes show striking memory of chirality (MoC), with strong retention of configuration when fast, polarity favored cyclization are involved. The most effective system employs a highly electron‐poor pentafluorobenzenesulfonyl group.
Christian Simon Gloor   +3 more
wiley   +1 more source

Arsonic Acid Functional Polymers Enable Stabilization of Iron Oxide Nanoparticles in Aqueous Solution

open access: yesMacromolecular Rapid Communications, EarlyView.
Arsonic acid containing diblock copolymers are developed to incorporate arsonic acid moieties for surface anchoring to IONPs, along with water soluble PEG blocks to impart colloidal stability in aqueous environments. The resulting polymer‐coated IONPs are evaluated for stability in physiological media and cytocompatibility.
Nhu Thao Huynh   +10 more
wiley   +1 more source

Genome‐wide screen reveals a universal role of ATP in ciprofloxacin tolerance among genetically distinct Escherichia coli persisters

open access: yesmLife, EarlyView.
Abstract Bacterial persisters show tolerance to bactericidal antibiotics and play essential roles in chronic infections; however, the general mechanisms underlying persister formation and antibiotic tolerance remain insufficiently characterized. In this study, the Escherichia coli Keio library was used to identify genes involved in ciprofloxacin ...
Zhenfang Mei   +9 more
wiley   +1 more source

Dental composites: a comprehensive review on formulation, properties and recent developments

open access: yesPolymer International, EarlyView.
Dental composites are essential in modern restorative dentistry; this review covers their development, composition, key properties and recent advances, highlighting new technologies for optimizing materials and improving clinical outcomes. Abstract Dental composites have evolved considerably since their introduction, becoming the cornerstone of modern ...
Rayenne Latoui   +2 more
wiley   +1 more source

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