Results 51 to 60 of about 37,045 (232)
Chemistry – A European Journal, EarlyView.Here we report a synthesis of the dinucleotide 4 for a projected future total synthesis of the m7G cap 1. Highlights of the route include: 1) a 3ʹ‐H‐phosphonate/5ʹ‐selenocyanate Michaelis‐Arbuzov coupling to forge the 3ʹ,5ʹ‐phosphoroselenolate; 2) an Amosova reductive selenomethylation to install the 2ʹ‐SeMe; 3) a solid CPR II 5ʹ‐O‐phosphitylation; and
K. Lawrence E. Hale +2 more
wiley +1 more source
Asymmetrically Substituted s‐Triazine Phosphonates by One‐Step Synthesis
ChemistryOpen, 2023 Asymmetrically substituted s‐triazine phosphonates with up to three different phosphonate groups C3N3RR'R” with R, R’, R”=PO(OR”’) and R”’=for example, methyl, ethyl, isopropyl or n‐butyl are interesting as polymer additives like flame retardants ...
Claudia Vogt +5 more
doaj +1 more source
Peptide mixed phosphonates for covalent complex formation with thioesterases in nonribosomal peptide synthetases [PDF]
, 2023 Sho Konno +6 more
openalex +1 more source
Chemistry – A European Journal, EarlyView.Successfully applying self‐assembled monolayers with hole‐selectivity for lead‐free tin perovskite solar cells requires judicious investigation with appropriately powerful characterization methods, in addition to efforts in the development of new materials and processing.
Donghoon Song +3 more
wiley +1 more source
Next Generation Hosts for Protein Recognition, Assembly and More
Chemistry – A European Journal, EarlyView.The original design of synthetic receptors for proteins was based on macrocycles with a hydrophobic core and a polar/charged periphery. This design, geared towards protein recognition, facilitates receptor self‐assembly. Macrocycle oligomerization, in turn, contributes to protein assembly as evidenced in many cocrystal structures.
Peter B. Crowley
wiley +1 more source
Chemistry – A European Journal, EarlyView.Herein, we report the first example of the formation of a close‐packed, regular 2D monolayer of a fivefold symmetric cyanostar macrocycle on an Au(111) surface under ultra‐high vacuum and the structural modification of such self‐assembled architecture upon cobalt atom deposition.
Lenka Černá +11 more
wiley +1 more source
Synthesis and Antiviral Bioactivity of Chiral Thioureas Containing Leucine and Phosphonate Moieties
Molecules, 2010 A series of novel chiral thioureas 3a-n bearing leucine and phosphonate moieties were synthesized in excellent yields. The structures of the compounds were completely characterized by elemental analysis, IR, 1H-, 13C-, 31P- and 19F-NMR spectral data.
Jian Wu +7 more
doaj +1 more source
Chemistry – A European Journal, EarlyView.One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim +4 more
wiley +1 more source
Advanced SciencePhosphate and phosphonate drugs are vital in building organisms, regulating physiological processes, and exhibiting diverse biological activities, including antiviral, antibacterial, antineoplastic, and enzyme‐inhibitory effects.
Wanrui Shi +7 more
doaj +1 more source
ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.Flame‐retardant bio‐based thermo‐flexible phase‐change composites for advanced battery thermal management. Batteries face critical challenges in thermal management, including overheating risks, poor interfacial contact, and mechanical vibration–induced performance attenuation.
Shichao Feng +7 more
wiley +1 more source