This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim +5 more
wiley +1 more source
Covalently bound substrate at the regulatory site triggers allosteric enzyme activation [PDF]
The mechanism by which the enzyme pyruvate decarboxylase from yeast is activated allosterically has been elucidated. A total of seven three-dimensional structures of the enzyme, of enzyme variants or of enzyme complexes form two yeast species (three of ...
Georg Wille +5 more
core +1 more source
First Supramolecular Sensors for Phosphonate Anions [PDF]
Fluorescent tripodal anion sensors with a 1,3,5-triethylbenzene core display a turn-on fluorescence response to phosphonate and phosphate anions and may be used as optical sensors.
Anzenbacher, Pavel +6 more
core +1 more source
Incorporating divinylbenzene into PTAA‐based copolymers induces backbone planarization and promotes polaron delocalization, leading to enhanced doping resilience and stabilized electronic structure. The resulting hole‐transport material, PDVB14, maintains robust performance under high dopant concentrations and prolonged device operation, offering a ...
Chanhyeok Kim +10 more
wiley +1 more source
Proton conductivity of multifunctional metal phosphonate frameworks [PDF]
Metal phosphonates exhibit attractive characteristics for proton conductivity, such as tunable functionality, chemical and thermal stability and the existence of H-bond networks with acidic protons within their structure.1 In the present work, we ...
Bazaga-García, Montse +9 more
core
‘User-friendly’ primary phosphines and an arsine: synthesis and characterization of new air-stable ligands incorporating the ferrocenyl group [PDF]
Reaction of FcCH₂CH₂P(O)(OH)₂ or FcCH₂P(O)(OH)(OEt) [Fc=Fe(η⁵-C₅H₄)(η⁵-C₅H₅)] with excess CH₂N₂ followed by reduction with Me₃SiCl–LiAlH₄ gives the air-stable primary phosphines FcCH₂CH₂PH₂ and the previously reported analogue FcCH₂PH₂ in high yields ...
Alley, Steven R., Henderson, William
core +2 more sources
Redox responsive mesoporous silica nanoparticles (MSNs) were engineered to deliver gemcitabine (Gem) and cisplatin (cisPt) at defined ratios to overcome chemoresistance in pancreatic ductal adenocarcinoma (PDAC). Optimized Gem MSNs and Gem cisPt MSNs enhanced cytotoxicity in murine and human Gem resistant models, with select formulations inducing ...
Tamanna Binte Huq +5 more
wiley +1 more source
Phosphonate Modified Silica for Adsorption of Co(II), Ni(II), Cu(II), and Zn(II)
A new phosphonate modified silica (PMS) has been investigated for adsorption of Co(II), Ni(II), Cu(II), and Zn(II) in aqueous solution. The adsorbent was modified of silica by immobilizing aminoethyl dihydrogen phosphate (AEPH2) on 1,4-dibromobutane ...
Dian Maruto Widjonarko +3 more
doaj +1 more source
The \u3cem\u3edapE\u3c/em\u3e-encoded \u3cem\u3eN\u3c/em\u3e-Succinyl-l,l-Diaminopimelic Acid Desuccinylase from \u3cem\u3eHaemophilus influenzae\u3c/em\u3e Is a Dinuclear Metallohydrolase [PDF]
The Zn K-edge extended X-ray absorption fine structure (EXAFS) spectra, of the dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase (DapE) from Haemophilus influenzae have been recorded in the presence of one or two equivalents of Zn(II) (i.e ...
Bienvenue, David L. +6 more
core +1 more source
Electrochemical treatment of aluminium alloy 7075 in aqueous solutions of imidazolium phosphonate and phosphate ionic liquids and scratch resistance of the resultant materials [PDF]
The abilitiy of 1-ethyl-3-methylimidazolium ethylphosphonate ([ImPhosphonate]) and 1-ethyl-3-methylimidazolium diethylphosphate ([ImPhosphate]) ionic liquids (ILs) to interact with anodized Al7075 T6 aluminium alloy has been studied via electrochemical ...
Arias Pardilla, Joaquín +4 more
core +2 more sources

