Results 41 to 50 of about 308,670 (298)

Spectrophotometric determination of trace quaternary phosphonium salts in water with m-nitrophenol

open access: yes浙江大学学报. 农业与生命科学版, 2010
A novel method was established for spectrophotometric chromogenic reaction of m-nitrophenol with cationic surfactants to determine the trace quaternary phosphonium salts in water.
JIANG Chen-jing   +4 more
doaj   +1 more source

Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation [PDF]

open access: yes, 2016
We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction invovles the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox ...
A. F. Fearnley   +66 more
core   +2 more sources

Triphenylarsonium-functionalised gold nanoparticles: potential nanocarriers for intracellular therapeutics. [PDF]

open access: yes, 2015
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Two new triphenylarsonium alkylthiolate precursors, a thiosulfate zwitterion and a thioacetate salt, have been structurally characterised and their cytotoxicity evaluated ...
Ahn   +39 more
core   +2 more sources

Total Synthesis of (+)‐Melonine and (+)‐N4‐Oxy Melonine Enabled by an Intramolecular Alkene Diamination Reaction

open access: yesAngewandte Chemie, EarlyView.
A complexity‐generating intramolecular alkene diamination constitutes the pivotal step in the enantioselective synthesis of the title natural products featuring a strained, cage‐like pentacyclic architecture. Abstract Among more than four thousand monoterpene indole alkaloids (MIAs) isolated to date, only a few feature a 2,2,3‐trisubstituted indoline ...
Vincent Goëlo, Qian Wang, Jieping Zhu
wiley   +2 more sources

Methoxy-phenyl groups reduce the cytotoxicity and increase the aqueous solubility of phosphonium zwitterions and salts [PDF]

open access: yes, 2019
The ability of phosphonium cations to act as intracellular transport vectors is well-established. Previous research has demonstrated that phosphonioalkylthiosulfate zwitterions, and -thioacetylalkylphosphonium salts are useful precursors for the ...
Allen, David   +5 more
core   +1 more source

Candida albicans biofilm formation on peptide functionalized polydimethylsiloxane [PDF]

open access: yes, 2010
In order to prevent biofilm formation by Candida albicans, several cationic peptides were covalently bound to polydimethylsiloxane (PDMS). The salivary peptide histatin 5 and two synthetic variants (Dhvar 4 and Dhvar 5) were used to prepare peptide ...
Coenye, Tom   +7 more
core   +1 more source

2H-Pyrrole und Pyrrole aus 3-Phenyl-2H-azirinen

open access: yesCHIMIA, 1976
Vinyl-phosphonium salts [2] and phenyl-vinyl-sulfone or divinylsulfone react with benzonitril-methylides a (which are photochemically generated from 3-phenyl-2H-azirines 1 and 2) to give, via the nonisolated intermediates of type b, 2H-pyrrole 4 and the
Ulrich Widmer   +4 more
doaj   +1 more source

Electrochemistry of ferrocenylphosphines FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN), and some phosphine oxide, phosphine sulfide, phosphonium and metal complex derivatives [PDF]

open access: yes, 2003
Electrochemical studies of the free ferrocenylphosphine ligands FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN) and some phosphine oxide, phosphine sulfide, phosphonium and metal derivatives are described.
Downard, Alison J.   +2 more
core   +2 more sources

Chiral phosphonium ion-pairing catalysis: From structural innovation to asymmetric synthesis

open access: yesChemical Engineering Journal Advances
Chiral phosphonium salt catalysis has emerged as a crucial component of asymmetric ion-pairing catalysis, demonstrating growing significance in the field of asymmetric catalytic synthesis.
Wenchao Chen   +3 more
doaj   +1 more source

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