A Strategy to Aminate Pyridines, Diazines, and Pharmaceuticals via Heterocyclic Phosphonium Salts. [PDF]
Patel C +3 more
europepmc +2 more sources
Spectrophotometric determination of trace quaternary phosphonium salts in water with m-nitrophenol
A novel method was established for spectrophotometric chromogenic reaction of m-nitrophenol with cationic surfactants to determine the trace quaternary phosphonium salts in water.
JIANG Chen-jing +4 more
doaj +1 more source
Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation [PDF]
We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction invovles the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox ...
A. F. Fearnley +66 more
core +2 more sources
Triphenylarsonium-functionalised gold nanoparticles: potential nanocarriers for intracellular therapeutics. [PDF]
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Two new triphenylarsonium alkylthiolate precursors, a thiosulfate zwitterion and a thioacetate salt, have been structurally characterised and their cytotoxicity evaluated ...
Ahn +39 more
core +2 more sources
A complexity‐generating intramolecular alkene diamination constitutes the pivotal step in the enantioselective synthesis of the title natural products featuring a strained, cage‐like pentacyclic architecture. Abstract Among more than four thousand monoterpene indole alkaloids (MIAs) isolated to date, only a few feature a 2,2,3‐trisubstituted indoline ...
Vincent Goëlo, Qian Wang, Jieping Zhu
wiley +2 more sources
Methoxy-phenyl groups reduce the cytotoxicity and increase the aqueous solubility of phosphonium zwitterions and salts [PDF]
The ability of phosphonium cations to act as intracellular transport vectors is well-established. Previous research has demonstrated that phosphonioalkylthiosulfate zwitterions, and -thioacetylalkylphosphonium salts are useful precursors for the ...
Allen, David +5 more
core +1 more source
Candida albicans biofilm formation on peptide functionalized polydimethylsiloxane [PDF]
In order to prevent biofilm formation by Candida albicans, several cationic peptides were covalently bound to polydimethylsiloxane (PDMS). The salivary peptide histatin 5 and two synthetic variants (Dhvar 4 and Dhvar 5) were used to prepare peptide ...
Coenye, Tom +7 more
core +1 more source
2H-Pyrrole und Pyrrole aus 3-Phenyl-2H-azirinen
Vinyl-phosphonium salts [2] and phenyl-vinyl-sulfone or divinylsulfone react with benzonitril-methylides a (which are photochemically generated from 3-phenyl-2H-azirines 1 and 2) to give, via the nonisolated intermediates of type b, 2H-pyrrole 4 and the
Ulrich Widmer +4 more
doaj +1 more source
Electrochemistry of ferrocenylphosphines FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN), and some phosphine oxide, phosphine sulfide, phosphonium and metal complex derivatives [PDF]
Electrochemical studies of the free ferrocenylphosphine ligands FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN) and some phosphine oxide, phosphine sulfide, phosphonium and metal derivatives are described.
Downard, Alison J. +2 more
core +2 more sources
Chiral phosphonium ion-pairing catalysis: From structural innovation to asymmetric synthesis
Chiral phosphonium salt catalysis has emerged as a crucial component of asymmetric ion-pairing catalysis, demonstrating growing significance in the field of asymmetric catalytic synthesis.
Wenchao Chen +3 more
doaj +1 more source

