Results 51 to 60 of about 9,982 (237)

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

open access: yesAdvanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang   +4 more
wiley   +1 more source

Large‐Scale Determination of Frontier Orbital Energies of Disordered Small‐Molecule Organic Semiconductors Using Exciplex Emission Spectra

open access: yesAdvanced Materials, EarlyView.
ABSTRACT Accurately knowing the frontier orbital energies of the structurally disordered small‐molecule organic semiconductors that are used in optoelectronic devices such as organic light‐emitting diodes is required to rationally improve their performance. Here, we show that these energies can be deduced with a large accuracy from the peak energies of
Christian B. McDonald   +7 more
wiley   +1 more source

Radical-enhanced photo-activated ultralong organic phosphorescence

open access: yesNature Communications
Stimuli-responsive ultralong room temperature phosphorescence materials have attracted great attention due to their great potential in a wide variety of advanced applications.
Yuefei Wang   +9 more
doaj   +1 more source

Specific Position of Halogen in Crystalline TADF Scintillators Enables Efficient Triplet Harvesting Through Vibrational Modulation of Spin–Orbit Coupling

open access: yesAdvanced Materials, EarlyView.
Specific ortho‐halogenation transforms crystalline TADF emitters into efficient organic scintillators. Fluorine reduces the effective singlet–triplet separation, while chlorine combines near‐degenerate excited states with vibrational modulation of spin–orbit coupling.
Illia E. Serdiuk   +8 more
wiley   +1 more source

Thermochromic aggregation-induced dual phosphorescence via temperature-dependent sp 3-linked donor-acceptor electronic coupling

open access: yesNature Communications, 2021
Aggregation-induced emission (AIE) has proven to be a viable strategy to achieve highly efficient room temperature phosphorescence (RTP) in bulk by restricting molecular motions.
Tao Wang   +6 more
doaj   +1 more source

Immediate Organic Room‐Temperature Phosphorescence in Programmable Luminescent Tags Enabled by Oxygen‐Free Fabrication

open access: yesAdvanced Materials Technologies, EarlyView.
Programmable luminescent tags based on organic room‐temperature phosphorescence are shown to be governed by oxygen incorporation during fabrication. Oxygen‐free processing enables immediate phosphorescence activation, controlled thermal preconditioning, and tunable activation doses.
Lucy Winkler   +2 more
wiley   +1 more source

Nylons with Highly-Bright and Ultralong Organic Room-Temperature Phosphorescence

open access: yesNature Communications
Endowing the widely-used synthetic polymer nylon with high-performance organic room-temperature phosphorescence would produce advanced materials with a great potential for applications in daily life and industry. One key to achieving this goal is to find
Dian-Xue Ma   +5 more
doaj   +1 more source

Photoluminescence Reshaping via Structural Confinement and Local Density of Optical States Control in Ir(III)‐Doped Biodegradable Metasurfaces

open access: yesAdvanced Materials Technologies, EarlyView.
Phosphorescent biodegradable metasurface showing vibronic selection and spectral photoluminescence narrowing. Anti‐correlation between experimental LDOS and measured lifetimes. ABSTRACT Metasurfaces incorporating phosphorescent emitters offer a route to engineer radiative and vibronic processes beyond chemical design.
Vincenzo Caligiuri   +11 more
wiley   +1 more source

Mechanical Stretch α‐Cyclodextrin Pseudopolyrotaxane Elastomer with Reversible Phosphorescence Behavior

open access: yesAdvanced Science
Polyethylene glycol chains in two terminals of the naphthalene functional group are threaded into α‐cyclodextrin cavities to form the pseudopolyrotaxane (NPR), which not only effectively induces the phosphorescence of the naphthalene functional group by ...
Yi Zhang   +4 more
doaj   +1 more source

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