Results 71 to 80 of about 9,982 (237)

Recent progress in triplet energy transfer systems toward organic afterglow materials

open access: yesCommunications Chemistry
Organic room-temperature phosphorescence (RTP) has shown potential applications in the fields of biomedical imaging, chemical sensing, anti-counterfeiting, and encryption.
Kaiwen Wu   +8 more
doaj   +1 more source

Isomeric Ag14 Nanoclusters With Distinct Photophysical and Nanomechanical Properties

open access: yesAdvanced Science, EarlyView.
Ligand‐shell isomerism in atomically precise Ag14 nanoclusters is demonstrated to regulate core distortion, photoluminescence, and mechanical properties. Subtle changes in phosphine ligand arrangement drive a pronounced emission shift from green to red and alter crystal rigidity, revealing a direct structure‐property correlation that offers new design ...
Vivek Yadav   +14 more
wiley   +1 more source

Activating Triplet Excitons in COFs via Layer‐Bridging Co Single Atoms for Photocatalytic H2O2 Production and Tandem C─N Coupling

open access: yesAngewandte Chemie, EarlyView.
This work demonstrates a layer‐bridging coordination strategy of Co single atoms in COFs that promotes the formation and utilization of triplet excited states. The introduction of Co single atoms induces pronounced energy‐level splitting and enhanced spin–orbit coupling, facilitating the generation of 1O2 and O2•– for efficient photocatalytic H2O2 ...
Guoen Tang   +6 more
wiley   +2 more sources

Reversible color switching of bright phosphorescence in purely organic materials for advanced data encryption

open access: yesNature Communications
Purely organic phosphors have emerged as promising materials for various optical applications. Herein, we report a single-component organic phosphorescent crystal, 1,1′-(2,5-dibromoterephthaloyl)bis(glutarimide) (BrGlu), which exhibits fully reversible ...
Jung-Moo Heo   +8 more
doaj   +1 more source

Origin of Enhanced Efficiency and Reduced Roll‐Off in Organic Light‐Emitting Diodes Based on Pt(II) Complexes

open access: yesAdvanced Science, EarlyView.
Controlled Pt–Pt fine structure in square‐planar Pt(II) complexes governs metal–metal‐to‐ligand charge‐transfer (MMLCT) state formation, exciton dynamics, and organic light‐emitting diode performance. Short Pt–Pt contacts in Pt(fppz)2 enable coherent metal–metal coupling, sub‐microsecond emission and an external quantum efficiency of 29%, whereas ...
Atul Shukla   +15 more
wiley   +1 more source

Diversity‐Oriented Two‐Step Annulative π‐Extension Enables Access to Structurally Complex Nanographenes

open access: yesAngewandte Chemie, EarlyView.
Pd‐catalyzed C–H arylation of polycyclic aromatic hydrocarbons (PAHs) with various aryltrimethylsilanes enables the preparation of structurally complicated arylated PAHs, which can be further transformed to nanographenes in a manner of two‐step annulative π‐extension (APEX) reaction.
Honami Katsuragawa   +5 more
wiley   +2 more sources

Tuning Steric Hindrance and Intermolecular Interactions in Tetrahydroindolocarbazoles for Dual Thermally Activated Delayed Fluorescence and Room‐Temperature Phosphorescence

open access: yesChemistryEurope
Synthesizing organic luminescent materials exhibiting long‐lived afterglow at room temperature, through room‐temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF), properties in pure organic derivatives remains a challenge,
Nagham Ibrahim   +3 more
doaj   +1 more source

Ligand engineering to achieve enhanced ratiometric oxygen sensing in a silver cluster-based metal-organic framework

open access: yesNature Communications, 2020
Incorporating dual fluorescence and phosphorescence into a single matrix is attractive for oxygen sensing, but material design is challenging. Here the authors achieve dual fluorescence-phosphorescence from a single linker chromophore in a silver ...
Xi-Yan Dong   +8 more
doaj   +1 more source

Selenophene π‐Core Fusion for Simultaneous Fast Reverse Intersystem Crossing and Narrowband Long‐Wavelength TADF

open access: yesAngewandte Chemie, EarlyView.
Dibenzo[b,d]selenophene (DBSe) π‐core fusion enables rapid triplet–singlet interconversion while preserving the narrowband emission features of multi‐resonance thermally activated delayed fluorescence (MR‐TADF) luminogens. Combined with peripheral donor engineering, this strategy enables systematic emission tuning from green to red, leading to highly ...
Jingpeng Zhang   +4 more
wiley   +2 more sources

A de‐novo Approach Towards Divergent [3+2π/σ] Photocycloadditions of Nitrones via Assembly‐Controlled Kinetic Electron Transfer Gating

open access: yesAngewandte Chemie, EarlyView.
A metal‐free photocatalytic platform converts nitrones into 4‐isoxazolines and oxa–aza–bicycloheptanes through divergent [3+2π/σ] cycloadditions. Assembly‐controlled kinetic electron transfer gating dictates substrate activation, enabling selective reactivity beyond thermodynamic expectations.
Nayan Saha   +6 more
wiley   +2 more sources

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