Results 61 to 70 of about 19,091 (291)

Efficient Room-Temperature Phosphorescence of Covalent Organic Frameworks through Covalent Halogen Doping

open access: yes, 2022
Organic room-temperature phosphorescence, a spin-forbidden radiative process, has emerged as an interesting but rare phenomenon with multiple potential applications in optoelectronic devices, biosensing, and anticounterfeiting.
Cory, Ruchlin   +5 more
core   +1 more source

Clustomesogen Showing Sub‐Zero Liquid Crystal Properties: Supramolecular Assembly Between Cs2[Mo6Ii8(OCOC2F5)6] and Hexaethylenoxide Containing Mesogenic Dimers

open access: yesAdvanced Materials, EarlyView.
Associating a red‐NIR phosphorescent octahedral hexanuclear molybdenum cluster compound with hexaethyleneoxide chains bearing mesogenic units on both ends leads to an emissive hybrid liquid crystal showing mesomorphism on a very unusual temperature range down to −25°C.
Killiann Heinz   +11 more
wiley   +1 more source

Single Crystals of Perylene Diimide‐Based Two‐Dimensional Covalent Organic Frameworks

open access: yesAdvanced Materials, EarlyView.
Synthesizing extended crystals of two‐dimensional covalent organic frameworks (2D COFs) has remained a major challenge. Here, we report a high‐temperature double‐modulator strategy that provides access to new perylene diimide (PDI)‐based COFs with crystal sizes of up to 50 µm.
Ling Zhang   +12 more
wiley   +1 more source

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

open access: yesAdvanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang   +4 more
wiley   +1 more source

Thermochromic aggregation-induced dual phosphorescence via temperature-dependent sp 3-linked donor-acceptor electronic coupling

open access: yesNature Communications, 2021
Aggregation-induced emission (AIE) has proven to be a viable strategy to achieve highly efficient room temperature phosphorescence (RTP) in bulk by restricting molecular motions.
Tao Wang   +6 more
doaj   +1 more source

Fluorescence and solvent-dependent phosphorescence studies of o-nitrobenzaldehyde: A combined experimental and theoretical investigation

open access: yes, 2010
The fluorescence and phosphorescence emission studies have been performed to understand the photochemistry of o-nitrobenzaldehyde in solution upon photoexcitation to the first excited singlet state (S-1).
尹鸿鳴   +10 more
core   +1 more source

Enhancing NIR-II Phosphorescence through Phosphorescence Resonance Energy Transfer for Tumor-Hypoxia Imaging

open access: yes, 2022
Phosphorescence probes have emerged as a promising hypoxia detector for their excellent characters of long luminescence lifetime, large Stokes shift, and oxygen sensitivity.
Shangyu Chen (8312229)   +8 more
core   +1 more source

Large‐Scale Determination of Frontier Orbital Energies of Disordered Small‐Molecule Organic Semiconductors Using Exciplex Emission Spectra

open access: yesAdvanced Materials, EarlyView.
ABSTRACT Accurately knowing the frontier orbital energies of the structurally disordered small‐molecule organic semiconductors that are used in optoelectronic devices such as organic light‐emitting diodes is required to rationally improve their performance. Here, we show that these energies can be deduced with a large accuracy from the peak energies of
Christian B. McDonald   +7 more
wiley   +1 more source

Engender Persistent Organic Room-Temperature Phosphorescence by Trace Ingredient Incorporation

open access: yes, 2020
The trace impurities in pure organic phosphors were always ignored because the ultra-low content impurities were considered to hardly affect the luminescent properties.
Xiang, Ma   +4 more
core   +1 more source

Tunable‐Threshold UV Dosimetry With Programmable Luminescent Tags via Oxygen‐Mediated Room‐Temperature Phosphorescence

open access: yesAdvanced Materials Technologies, EarlyView.
A fully organic UV threshold dosimeter is developed by exploiting the oxygen‐sensitive room‐temperature phosphorescence of a purely organic emitter in a polymer matrix. Upon reaching a specific cumulative UV dose, photochemical oxygen depletion triggers a sharp, high‐contrast emission.
Tim Achenbach   +3 more
wiley   +1 more source

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