Results 211 to 220 of about 21,611 (258)
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Photoisomerization of polybutadiene
Journal of Polymer Science Part C: Polymer Symposia, 1967AbstractPolybutadiene, in the solid state, and in the absence of added sensitizer, undergoes photochemical cis‐trans isomerization and loss of unsaturation when irradiated in vacua with krypton 1236 A. or mercury 2537 A. radiation. The estimated quantum yields for these two reactions are 0.25 and 1.53, respectively, for the krypton irradiations, and 0 ...
M. A. Golub, C. L. Stephens
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Dynamics of Photoisomerization
1982There has recently been a good deal of theoretical [1–3] and experimental [4–7] interest in activated barrier crossing processes in liquids. The best known model is that of Kramers [8] who derived expressions for the escape of particles over a barrier in various limiting cases. Combining Kramers ideas with recent kinetic theory calculations [1–3] leads
G. R. Fleming +2 more
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Photoisomerization of phenylisothiazoles
Journal of the Chemical Society D: Chemical Communications, 1970The photoisomerization of phenylisothiazoles into phenylthiazoles probably proceeds via tricyclic sulphonium cation intermediates.
Mamoru Ohashi +2 more
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Photoisomerization of Azobenzenes
ChemInform, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
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Photoisomerization and Thermal Isomerization of Arylazoimidazoles
The Journal of Physical Chemistry A, 2007Photoisomerization and thermal isomerization behaviors of an extensive series of arylazoimidazoles are investigated. Absorption spectra are characterized by a structured pipi* absorption band around 330-400 nm with a tail on the lower energy side extending to 500 nm corresponding to an npi* transition.
Joe, Otsuki +3 more
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Ergosterol Photoisomerization Reaction Scheme
Journal of Pharmaceutical Sciences, 1973The kinetics of the various isomers formed at low temperature by UV irradiation of ergosterol were studied experimentally at the wavelength λ = 253.7 nm. The characteristics of the photostationary state were used to determine the isomer precursor of the toxisterols as well as the quantum transformation yields of one isomer into another.
R, Mermet-Bouvier, E, Abillon
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Photoisomerization in Proteorhodopsin mutant D97N
Photochemistry and Photobiology, 2006The first steps of the photocycle of the D97N mutant of proteorhodopsin (PR) have been investigated by means of ultrafast transient absorption spectroscopy. A comparison with the primary dynamics of native PR and D85N mutant of bacteriorhodopsin is given.
Martin O, Lenz +3 more
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Photoorientation by Photoisomerization
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
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Photoisomerizing molecules in biological membranes
Nature Reviews ChemistryBiological membranes, consisting mostly of self-assembled amphiphilic molecules, serve as fundamental barriers that compartmentalize and organize cellular environments, essential for sustaining life functions. Reconstituting their rich dynamics and transformations is critical in addressing fundamental questions and mimicking lifelike functions.
Ainoa Guinart +3 more
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