Results 81 to 90 of about 14,703 (275)

Light‐Driven Control of Polar Order in Ferroelectric Nematic Liquid Crystals

open access: yesAngewandte Chemie, EarlyView.
Light‐responsive ferroelectric nematics are achieved by molecularly matching azobenzene photo‐switches to the polar packing motif of DIO. This design yields intrinsically photo‐responsive ferroelectric nematic mesogens and optically addressable DIO blends, in which light reversibly modulates spontaneous polarization and switches between high‐ and low ...
Anjali Devi Das   +5 more
wiley   +2 more sources

Unveiling the role of dark states in dynamic control of azopyrrole photoisomerization by light-matter interaction

open access: yesCommunications Chemistry
Strong light-matter interactions demonstrated considerable potential to control photochemical reactions. Here, we coupled a single cavity mode to the electronic S0-S1 transition of azopyrrole E and Z-isomers.
Pallavi Garg   +5 more
doaj   +1 more source

Anethole Isomerization and Dimerization Induced by Acid Sites or UV Irradiation

open access: yesMolecules, 2010
The formation of cis-anethole and various dimers as a result of the exposure of trans-anethole to microporous solid acids (dealuminated HY zeolites), or UV-Vis irradiation was established by means of high resolution gas chromatography coupled to mass ...
Elena Stashenko   +2 more
doaj   +1 more source

Multi-state Photoswitching in Thienoquinoid-Based Fluorescent Trithiophenes. [PDF]

open access: yesChemistry
A methine‐bridged trithiophene with a thienoquinoid core undergoes photoisomerization of both C═C bonds, affording three geometrical isomers in a ratio controlled by the irradiation wavelength. Despite full π‐conjugation, the system retains fluorescence, enabling wavelength‐addressable multi‐state switching with luminescent readout.
Nishimura R   +3 more
europepmc   +2 more sources

Photoisomerization Kinetics and Mechanical Stress in Azobenzene-Containing Materials

open access: yes, 2017
Kinetics of photoisomerization and time evolution of ordering in azobenzene-containing materials are studied theoretically and by using computer simulations.
Jaroslav Ilnytskyi (3772906)   +2 more
core   +1 more source

Fundamental limitations on photoisomerization from thermodynamic resource theories [PDF]

open access: yes, 2020
Small, out-of-equilibrium, and quantum systems defy simple thermodynamic expressions. Such systems are exemplified by molecular switches, which exchange heat with a bath. These molecules can photoisomerize, or change conformation, or switch, on absorbing
Limmer, DT, Yunger Halpern, N
core   +1 more source

Intelligent Micro/Nanorobots for Targeted Interventional Therapy: From Bench to Clinic

open access: yesAdvanced Robotics Research, EarlyView.
Zirui Zhang et al. reviewed the application and challenges of mobile nanomachines in interventional therapy. By converting exogenous energy, including chemical, magnetic, optical, and ultrasonic sources, into mechanical forces, micro/nanorobots (MNRs) enable precise actuation at unprecedented scales. Evolving far beyond traditional drug delivery, these
Zirui Zhang   +5 more
wiley   +1 more source

Time‐Resolved Multidimensional NMR Spectroscopy Reveals the Bifurcated Folding Pathway of a Thrombin‐Binding DNA G4–Azobenzene Derivative Complex

open access: yesAngewandte Chemie, EarlyView.
A photoswitchable ligand was used to trigger conformational changes within the thrombin binding aptamer DNA G‐Quadruplex. These reversible ligand driven rearrangements were examined by time‐resolved NMR experiments to gain insight of the dynamic folding landscape of the G‐quadruplex.
Jason Martins   +2 more
wiley   +2 more sources

Density functional theory study of azobenzene derivatives as potential materials for wettability switching

open access: yesҚарағанды университетінің хабаршысы. Физика сериясы
In this study, density functional theory (DFT) is employed to analyze the properties of 16 azobenzene derivatives, assessing their potential as wettability switching materials. Inspired by K.
G. Adyrbekova   +6 more
doaj   +1 more source

Effect of a =X-NH-Fragment, (X = C, N), on Z/E Isomerization and ON/OFF Functionality of Isatin Arylhydrazones, ((Arylamino)Methylene)Indolin-2-Ones and Their Anions

open access: yesMolecules, 2020
The subject of this work was the study of thermally and photochemically stimulated Z ↔ E isomerization and hydrazo ↔ azo tautomerism of Z- and E-isomers of isatin arylhydrazones and ((arylamino)methylene)indolin-2-ones and their anions. Using NMR, UV-Vis
Pavol Tisovský   +5 more
doaj   +1 more source

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