Results 71 to 80 of about 14,703 (275)

Photoisomerization of a small cyclic ketone in the vapor phase

open access: yes, 2017
Photoisomerization channels in the vapor phase photochemistry of cyclohexanone (CH) are studied by performing photolysis with 311 nm UV light, and analyzing the photoproducts by means of FTIR spectroscopy.
Samanta, Monoj   +7 more
core   +1 more source

Pointlike Material Accumulation and Displacement in Azopolymer Thin Films Driven by Spatial Light Modulation

open access: yesAdvanced Optical Materials, EarlyView.
A maskless, SLM‐driven approach enables the deterministic inscription of arbitrary topographical features in azopolymer films by mapping complex vectorial light fields onto local viscoplastic stress. This platform allows for the rapid generation and dynamic erasure of high‐aspect‐ratio micro‐spikes, offering a versatile tool for reconfigurable flat ...
Jonas Strobelt   +3 more
wiley   +1 more source

Molecular Solar Thermal Fuels with High Energy Density Based on Azobenzene Derivatives

open access: yesEnergies
Molecular solar thermal fuels (MOSTs) based on azobenzene derivatives have become one of the research hotspots for solar thermal conversion and storage due to their excellent cycling stability, resistance to photodegradation, and the capability to ...
Yan Jiang   +5 more
doaj   +1 more source

Dynamic Fluorescence Modulation via Light‐Driven Competitive Protonation

open access: yesAdvanced Optical Materials, EarlyView.
A two‐component molecular system demonstrates reversible, light‐driven fluorescence write–erase cycling and thermal imaging. Illumination of a merocyanine photoacid transfers a proton to a highly efficient fluorescent pyridinium dye, switching its emission color; thermal relaxation reverses the process in the dark.
Serena X. Liu   +10 more
wiley   +1 more source

Control over molecular motion using the cis–trans photoisomerization of the azo group

open access: yesBeilstein Journal of Organic Chemistry, 2012
Control over molecular motion represents an important objective in modern chemistry. Aromatic azobenzenes are excellent candidates as molecular switches since they can exist in two forms, namely the cis (Z) and trans (E) isomers, which can interconvert ...
Estíbaliz Merino, María Ribagorda
doaj   +1 more source

Nonadiabatic ab initio molecular dynamics of photoisomerization in bridged azobenzene

open access: yes, 2012
The photoisomerization mechanisms of bridged azobenzene are investigated by means of surface hopping dynamics simulations based on the Zhu-Nakamura theory.
韩克利   +4 more
core   +1 more source

Molecular Appendix Adjusted Architectural Propagations of Red‐Light Controlled Macroscopic Photoactuating Performances

open access: yesAdvanced Robotics Research, EarlyView.
Amphiphilic chloroazobenzenes, bearing different amino acids as end groups alanine, phenylalanine, and valine, exhibit excellent photoisomerizations. Varying structures of three amino acid groups participate in supramolecular formations and therefore photoinduced morphological transformations via adjusting intermolecular interactions. These interaction
Shuangshuang Meng   +3 more
wiley   +1 more source

photoisomerization

open access: yes, 2014
Citation: 'photoisomerization' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.P04622 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Molecular Preorganization Unlocks Reversible Solid‐State Photoconversion in Dianthrylnaphthalene‐Based Molecular Solar Thermal Systems

open access: yesAngewandte Chemie, EarlyView.
Three dianthrylnaphthalenes were synthesized and investigated for molecular solar thermal (MOST) energy storage. Naphthyl‐based bridging units preorganize the two anthracene moieties face‐to‐face, leading to improved photoisomerization quantum yield (QY) and unlocked bidirectional photoswitching in the solid state compared to previously reported ortho ...
Nicolò Baggi   +10 more
wiley   +2 more sources

Waveguide Photoactuators: Materials, Fabrication, and Applications

open access: yesAdvanced Robotics Research, EarlyView.
Waveguide photoactuators convert guided light into mechanical motion. Their tethered‐flexible design enables minimally invasive surgery and confined‐space robotics. This review aims to guide materials selection, device design, and system integration, accelerating the transition of waveguide photoactuators from laboratory prototypes to versatile ...
Minjie Xi   +4 more
wiley   +1 more source

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