Results 31 to 40 of about 121,504 (326)

A mechanistic study on the phototoxicity of atorvastatin: singlet oxygen generation by a phenanthrene-like photoproduct [PDF]

open access: yes, 2009
Atorvastatin calcium (ATV) is one of the most frequently prescribed drugs worldwide. Among the adverse effects observed for this lipid-lowering agent, clinical cases of cutaneous adverse reactions have been reported and associated with photosensitivity ...
IESCE, MARIA ROSARIA   +4 more
core   +1 more source

Study on the Direct and Indirect Photolysis of Antibacterial Florfenicol in Water Using DFT/TDDFT Method and Comparison of Its Reactivity with Hydroxyl Radical under the Effect of Metal Ions

open access: yesToxics
Florfenicol (FLO) is a widely used antibacterial drug, which is often detected in the environment. In this paper, the photolysis mechanism of FLO in water was investigated using density functional theory (DFT) and time-dependent density functional theory
Yue Kang, Ying Lu, Se Wang
doaj   +1 more source

Photolysis of in-situ electrogenerated hydrogen peroxide for the degradation of emerging pollutants [PDF]

open access: yes, 2017
This study investigates the degradation of paracetamol, an emerging contaminant widely used as pain and fever reliever, by means of hydrogen peroxide either alone or in combination with UV-C photolysis.
Bavasso, Irene   +3 more
core   +1 more source

Photochemical Electrocyclic Ring Closure and Leaving Group Expulsion from N-(9-oxothioxanthenyl)Benzothiophene Carboxamides [PDF]

open access: yes, 2013
N-(9-Oxothioxanthenyl)benzothiophene carboxamides bearing leaving groups (LG− = Cl−, PhS−, HS−, PhCH2S−) at the C-3 position of the benzothiophene ring system photochemically cyclize with nearly quantitative release of the leaving group, LG−.
Sarker, Majher I.   +3 more
core   +3 more sources

Photochemical transformation of perfluoroalkyl acid precursors in water using engineered nanomaterials [PDF]

open access: yes, 2020
The production of perfluoroalkyl acids (PFAAs) has been phased out over recent decades; however, no significant decline in their environmental concentrations has been observed.
Dai, Yunrong   +4 more
core  

Generation of superoxide and singlet oxygen from α-tocopherolquinone and analogues. [PDF]

open access: yes, 2007
Three potential routes to generation of reactive oxygen species from a tocopherolquinone have been identified. The quinone of the water-soluble vitamin E analogue Trolox C (Trol-Q) is reduced by hydrated electron and isopropanol a hydroxyalkyl radical ...
Bisby, RH   +4 more
core   +1 more source

Investigation on UV Degradation and Mechanism of 6:2 Fluorotelomer Sulfonamide Alkyl Betaine, Based on Model Compound Perfluorooctanoic Acid

open access: yesChemEngineering
The UV treatment of 6:2 FTAB involves the mitigation of this persistent chemical by the impact of ultraviolet radiation, which is known for its resistance to environmental breakdown.
Naveed Ahmed   +5 more
doaj   +1 more source

Positionally dependent ^(15)N fraction factors in the UV photolysis of N_2O determined by high resolution FTIR spectroscopy [PDF]

open access: yes, 2000
Positionally dependent fractionation factors for the photolysis of isotopomers of N_2O in natural abundance have been determined by high resolution FTIR spectroscopy at three photolysis wavelengths.
Blake, G. A.   +6 more
core  

Photochemical Studies in Flash Photolysis. II. Photolysis of Acetone with Filtered Light [PDF]

open access: yes, 1961
Flash photolysis was studied in the absence of wavelengths below 200 mμ. Effects of acetone pressure, light intensity, added biacetyl, temperature, and wavelength were investigated.
Marcus, R. A., Slagg, N.
core   +1 more source

Continuous‐Flow Photocatalytic Degradation of Glyphosate and Aminomethylphosphonic Acid Under Simulated Sunlight with TiO2‐Coated Poly(vinylidene fluoride) Membrane

open access: yesAdvanced Functional Materials, EarlyView.
Glyphosate (GLY) and its primary metabolite, aminomethylphosphonic acid (AMPA), are photodegraded using a poly(vinylidene fluoride) membrane with immobilized titanium dioxide (PVDF‐TiO2) in a continuous flow‐through operation under solar light. At optimized conditions, the PVDF‐TiO2 membrane achieved 95% GLY and 80% AMPA removal with •O2− as the ...
Phuong B. Trinh   +4 more
wiley   +1 more source

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