Research on detection technology of photolysis rate of atmospheric trace gases [PDF]
A detection system for measuring the optical velocity of trace gases was built based on a micro-spectrometer, including an optical receiver, a radiation calibration system, a spectrometer system, and a host computer software.
Liu Zhihong+3 more
doaj +1 more source
The Photolysis of Aromatic Hydrocarbons Adsorbed on the Surfaces of Cosmic Dust Grains [PDF]
The work is devoted to the adaptation of the results of laboratory studies of the laser-induced dissociation of molecules of benzene adsorbed on a quartz substrate to the conditions of the interstellar medium. Adsorption was performed under conditions of low temperature and deep vacuum.
arxiv +1 more source
Photolysis production and spectroscopic investigation of the highest vibrational states in H$_2$ (X$^1Σ_g^+$ $v=13,14$) [PDF]
Rovibrational quantum states in the $X^1\Sigma_g^+$ electronic ground state of H$_2$ are prepared in the $v=13$ vibrational level up to its highest bound rotational level $J=7$, and in the highest bound vibrational level $v=14$ (for $J=1$) by two-photon photolysis of H$_2$S.
arxiv +1 more source
Synthesis, Characterization and Reactions of (Azidoethynyl)trimethylsilane
Synthesis of azido(trimethylsilyl)acetylene (6) was performed by treating the iodonium salt 5 with highly soluble hexadecyltributylphosphonium azide (QN3) at −40 °C.
Klaus Banert+3 more
doaj +1 more source
Phototauntomerism of o-nitrobenzyl compounds: o-quinonoid aci-nitro species studied by matrix isolation and DFT calculations [PDF]
Photolyses of 2-nitrobenzyl methyl ether and 2-nitrotoluene with 254 nm light have been investigated in Ar and N2 matrices at 12 K, and have been found to give o-quinonoid aci-nitro species as the primary photoproducts, along with other products.
Dunkin, Ian R.+3 more
core +1 more source
Tetracycline (TC) is a broad-spectrum antibiotic compound. Wastewater with TC may have an adverse effect on ecosystems. Riboflavin-5′-phosphate (FMN or flavin mononucleotide) is a non-toxic product of the phosphorylation of vitamin B2 and is ...
Shiuh-Tsuen Huang+7 more
doaj +1 more source
The present study aimed to investigate an effective, sustainable and accessible way to inactivate chlorine-resistant microorganisms, such as Acanthamoeba castellanii, through the photolysis of sodium chloride (NaCl) and sodium hypochlorite (NaOCl) in the
Beni J. M. Chaúque, Marilise B. Rott
doaj +1 more source
Under conditions typically encountered in the aquatic environment, the absorption of sunlight by nitrite and nitrate leads to the transformation of trace organic contaminants.
Rachel C. Scholes, C. Prasse, D. Sedlak
semanticscholar +1 more source
Ultrafast carbon monoxide photolysis and heme spin-crossover in myoglobin via nonadiabatic quantum dynamics [PDF]
Light absorption of myoglobin triggers diatomic ligand photolysis and spin crossover transition of iron(II) that initiate protein conformational change. The photolysis and spin crossover reactions happen concurrently on a femtosecond timescale. The microscopic origin of these reactions remains controversial.
arxiv +1 more source
Kinetics of n-Butoxy and 2-Pentoxy Isomerization and Detection of Primary Products by Infrared Cavity Ringdown Spectroscopy [PDF]
The primary products of n-butoxy and 2-pentoxy isomerization in the presence and absence of O_2 have been detected using pulsed laser photolysis-cavity ringdown spectroscopy (PLP-CRDS).
Bean, Brian D.+8 more
core +1 more source