Results 41 to 50 of about 57,845 (293)

Limited Long‐Term Photolysis of Stratospheric Organic Aerosols With Implications for CESM Modeling

open access: yesJournal of Advances in Modeling Earth Systems
Organic aerosol (OA) is an important constituent of the Earth's atmosphere, yet the extent of its destruction by photolysis remains an active research question.
Jian Guan   +8 more
doaj   +1 more source

Synthesis of New Spiro-Cyclopropanes Prepared by Non-Stabilized Diazoalkane Exhibiting an Extremely High Insecticidal Activity

open access: yesMolecules, 2022
The synthesis of new insecticidal gem-dimethyspiro-cyclopropanes derived from pyrrolidine-2,3-dione have been described, and their biological effect against different insect species has been evaluated.
Naoufel Ben Hamadi, Ahlem Guesmi
doaj   +1 more source

Sunscreen‐Inspired Nano‐Pesticide for UV‐Shielding and Laccase‐Responsive Delivery of Mancozeb With Enhanced Fungicidal Efficacy and Ecological Safety

open access: yesAdvanced Science, EarlyView.
The sunscreen‐inspired nano‐pesticide, MCB@URFSL, provides UV‐shielding, enhanced rainfastness, and laccase‐responsive delivery for improved fungicidal efficacy and high ecological safety. ABSTRACT Fungicides are a crucial tool for protecting crops and ensuring consistent food supply.
Jin Yan   +10 more
wiley   +1 more source

Radical, Not Ionic: The Mechanochemical Zincke Nitration of Phenols

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry recasts the classical Zincke nitration as an open‐shell process. Liquid‐assisted vibrational milling of phenols with in situ HNO2 delivers direct and ipso nitration across 50 substrates, while atmosphere, NOx‐transfer, EPR and DFT evidence expose a phenoxyl‐radical/NO2 manifold underlying this historically ionic transformation ...
Roberto Scipione   +7 more
wiley   +2 more sources

Photocatalytic Properties of Graphene/Gold and Graphene Oxide/Gold Nanocomposites Synthesized by Pulsed Laser Induced Photolysis

open access: yesNanomaterials, 2020
Graphene (Gr)/gold (Au) and graphene-oxide (GO)/Au nanocomposites (NCPs) were synthesized by performing pulsed-laser-induced photolysis (PLIP) on hydrogen peroxide and chloroauric acid (HAuCl4) that coexisted with Gr or GO in an aqueous solution.
Li-Hsiou Chen   +8 more
doaj   +1 more source

Occurrence and Treatment of Antibiotic-Resistant Bacteria Present in Surface Water

open access: yesMembranes, 2023
According to the World Health Organization, antibiotic resistance is one of the main threats to global health. The excessive use of several antibiotics has led to the widespread distribution of antibiotic-resistant bacteria and antibiotic resistance ...
João Sério   +4 more
doaj   +1 more source

Photolysis of hexachlorocyclopentadiene in water

open access: yesEcotoxicology and Environmental Safety, 1982
Abstract 14 C-Hexachlorocyclopentadiene (hex) (C 5 Cl 6 ) was photolyzed rapidly when dissolved in water and irradiated with a mercury-vapor light source. The photolytic half-life of hex was less than 1.03 min. Pentachlorocyclopentenone was tentatively identified as the primary photolysis product of hex.
R G, Butz, C C, Yu, Y H, Atallah
openaire   +2 more sources

Smartphone‐Guided Visible Light Modulation of RSNOs for Antimicrobial Activity via Controlled Nitric Oxide Release

open access: yesAdvanced Science, EarlyView.
A light‐activated catheter insert combines antimicrobial blue light with nitric oxide release to generate complementary oxidative and nitrosative stress, producing potent broad‐spectrum antimicrobial activity. The approach achieves greater than 4‐log reductions in bacterial and fungal viability and significantly reduces Staphylococcus aureus ...
Alexander Bruckmann   +7 more
wiley   +1 more source

OH produced from o-nitrophenol photolysis: A combined experimental and theoretical investigation

open access: yes, 2009
Photodissociation dynamics of o-nitrophenol in the gas phase at different photolysis wavelengths (361-390 nm) is investigated, and the nascent OH radical is observed by the single-photon laser-induced fluorescence technique.
尹鸿鸣   +10 more
core   +2 more sources

Direct Observation of Radical‐Mediated Oxide‐to‐Alloy Transformation in Solution Under Pulsed Laser Irradiation

open access: yesAngewandte Chemie, EarlyView.
Time‐resolved in situ x‐ray absorption spectroscopy and DFTB‐based molecular dynamics simulations identify direct hydrogen atom transfer from ethanol to lattice oxygen as the elementary step of laser‐driven reduction in NiCo2O4. While this transfer is facile, the subsequent release of lattice oxygen is entropy‐driven and becomes accessible only at ...
Woo Hyeok Kim   +12 more
wiley   +2 more sources

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