Results 31 to 40 of about 57,845 (293)

The Photochemistry of Benzotriazole Derivatives. Part 2: Photolysis of 1-Substituted Benzotriazole Arylhydrazones: New Route to Phenanthridin-6-yl-2-phenyldiazines

open access: yesMolecules, 2011
Irradiation of 1-substituted benzotriazole arylhydrazones 3a–c, 4a,b and 5a,b with a 16 W low pressure mercury arc-lamp (254 nm) for 24 h gave phenanthridin-6-yl-2-phenyldiazines 9a–c, phenanthridin-6(5H)-ones 10a–c, 1-anilinobenzimidazoles 11a–c, 2-aryl-
Nouria A. Al-Awadi   +3 more
doaj   +1 more source

Antibiotics in Aquaculture Wastewater: Is It Feasible to Use a Photodegradation-Based Treatment for Their Removal?

open access: yesToxics, 2021
Aquacultures are a sector facing a huge development: farmers usually applying antibiotics to treat and/or prevent diseases. Consequently, effluents from aquaculture represent a source of antibiotics for receiving waters, where they pose a potential ...
Carla Patrícia Silva   +4 more
doaj   +1 more source

A new photoremovable protecting group : synthesis and reaction mechanism [PDF]

open access: yes, 2006
A new photoremovable protecting group, allowing for irradiation up to 400 nm, is introduced. A simple synthetic route to three derivatives was described and their photochemistry in aqueous solutions and acetonitrile was investigated.
Kamdzhilov, Yavor
core   +1 more source

Speed Control of Single Molecules on a Surface

open access: yesAngewandte Chemie, EarlyView.
The speed of a single molecule moving across a silver crystal surface is determined with the tip of a scanning tunneling microscope (STM). Travelling distances Δx and travelling times Δt, which are determined simultaneously with high precision, allow to directly measure time–distance relationships.
Donato Civita   +5 more
wiley   +2 more sources

Synthesis, Characterization and Reactions of (Azidoethynyl)trimethylsilane

open access: yesMolecules, 2015
Synthesis of azido(trimethylsilyl)acetylene (6) was performed by treating the iodonium salt 5 with highly soluble hexadecyltributylphosphonium azide (QN3) at −40 °C.
Klaus Banert   +3 more
doaj   +1 more source

Strategy for Engineering High Photolysis Efficiency of Photocleavable Protecting Groups through Cation Stabilization [PDF]

open access: yes, 2022
[Image: see text] Photolabile protecting groups (PPGs) enable the precise activation of molecular function with light in many research areas, such as photopharmacology, where remote spatiotemporal control over the release of a molecule is needed.
Alachouzos, Georgios   +13 more
core   +4 more sources

Harnessing Phase Separation for the Development of High‐Performance Hydrogels

open access: yesAdvanced Science, EarlyView.
ABSTRACT Hydrogels are indispensable for the development of next‐generation bioelectronics, soft robotics, and biomedical devices, where their mechanical properties determine performance and reliability. Among strategies to enhance hydrogel mechanics, phase separation enables controlled heterogeneity resulting in gel networks that are reinforced by ...
Yue Shao   +3 more
wiley   +1 more source

Photochemical and Structural Studies on Cyclic Peptide Models

open access: yesMolecules, 2018
Ultra-violet (UV) irradiation has a significant impact on the structure and function of proteins that is supposed to be in relationship with the tryptophan-mediated photolysis of disulfide bonds. To investigate the correlation between the photoexcitation
Tamás Milán Nagy   +8 more
doaj   +1 more source

Heat‐Suppressing Projection Two‐Photon Lithography Enables High‐Throughput Sub‐Micrometer Manufacturing of Biopolymer Hydrogels for Tissue Engineering

open access: yesAdvanced Science, EarlyView.
The iLEAP technique integrates high‐throughput two‐photon lithography with extrusion printing, bridging sub‐micrometer precision and macroscopic scaffold fabrication. By employing a low‐exothermic photoinitiator, it mitigates thermal damage to biopolymers and preserves bioactivity.
Qifeng Guan   +11 more
wiley   +1 more source

Beyond Radical Emitters: Hot‐Exciton Electroluminescence From Singlet Diradicaloids

open access: yesAngewandte Chemie, EarlyView.
The first hot‐exciton mechanism in a singlet diradicaloid is demonstrated in a polychlorinated Thiele hydrocarbon‐based organic light‐emitting transistor. Reverse intersystem crossing involving the T2 and bright singly excited states enables electroluminescence beyond the 25% spin‐statistical limit, leading to remarkable external quantum efficiency ...
Mario Prosa   +12 more
wiley   +2 more sources

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