Results 51 to 60 of about 122,502 (355)

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

Angewandte Chemie, EarlyView.
This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte, Anthony J. Fernandes, Dmitry Katayev   +2 more
wiley   +2 more sources

Photocatalytic removal of the herbicide clopyralid from water [PDF]

Journal of the Serbian Chemical Society, 2007
The stability of the herbicide clopyralid (3,6-dichloro-2-pyridinecarboxylic acid) was studied under different experimental conditions of pH, illumination and initial substrate concentration.
BILJANA F. ABRAMOVIC, VESNA B. ANDERLUH, DANIELA V. ŠOJIĆ, FERENC F. GAÁL   +3 more
doaj  

Direct and indirect photolysis of triclocarban in the presence of dissolved organic matter

Elementa: Science of the Anthropocene, 2015
Photolysis is an important attenuation pathway for the removal of wastewater effluent organic micropollutants from surface waters. In this work, direct and indirect processes leading to the degradation of the disinfectant, triclocarban were studied ...
Tamara D. Trouts, Yu-Ping Chin
doaj   +1 more source

Green approach for tracking the photofate of ciprofloxacin and levofloxacin in different matrices adopting synchronous fluorescence spectroscopy: a kinetic study

Royal Society Open Science, 2023
First derivative synchronous fluorescence spectroscopy (FDSFS) was applied to detect and quantify either ciprofloxacin (CIP) or levofloxacin (LEV) simultaneously with their photodegradation products, where the photolytic pathway for each analyte was ...
Mohammed E. Draz, Dalia El Wasseef, Nahed El Enany, Mary E. K. Wahba   +3 more
doaj   +1 more source

Erasable FAP Targeted Spray‐On Probe for Fluorescence‐Guided Surgery

Advanced Science, EarlyView.
We present the first erasable spray‐on probe for fluorescence‐guided surgery. Following topical delivery, FAP‐FLASH550 targets fibroblast activation protein–expressing stromal cells, delineating tumor margins with high tumor‐to‐background ratios. A 365 nm UV light pulse rapidly erases fluorescent signals through triazene photodegradation and subsequent
Zachary Rabinowitz, Riley J. Deutsch‐Williams, Ralph Weissleder   +2 more
wiley   +1 more source

Photolyzable Polymer Brushes: Subtractive 3D Structuring of Surfaces Using Water and Light

Angewandte Chemie, EarlyView.
Facile structuring of polymer brushes is achieved by flipping the process from controlled growth to controlled brush photolysis. Using surface‐initiated radical ring‐opening polymerization of cyclic monomers with photocleavable cyclobutane rings, photodegradable targets are embedded into the polymer chains. The enabled continuous subtractive patterning
Henrik Kalmer, Federica Sbordone, Phuong T. Do, Kai Mundsinger, Hazal Kayas, Robert T. Jones, Jayanti Mendhi, Tim R. Dargaville, Damien G. Harkin, Lukas Michalek, Andrew Nelson, Hendrik Frisch   +11 more
wiley   +2 more sources

STUDY OF THE STABILITY OF THE SUBSTANCE 3-[2-(4-PHENYL-1-PIPERAZINO)-2-OXOETHYL]QUINAZOLINE-4(3Н)-ONE UNDER STRESSFUL CONDITIONS

Фармация и фармакология (Пятигорск), 2021
The aim of the research was to study the stability of a new pharmaceutical substance 3-[2-(4-phenyl-1-piperazino)-2-oxoethyl]quinazoline-4(3Н)-one under stress conditions.Materials and methods.
T. A. Gendugov, A. A. Glushko, A. A. Ozerov, L. I. Shcherbakova   +3 more
doaj   +1 more source

Harnessing Phase Separation for the Development of High‐Performance Hydrogels

Advanced Science, EarlyView.
ABSTRACT Hydrogels are indispensable for the development of next‐generation bioelectronics, soft robotics, and biomedical devices, where their mechanical properties determine performance and reliability. Among strategies to enhance hydrogel mechanics, phase separation enables controlled heterogeneity resulting in gel networks that are reinforced by ...
Yue Shao, Yiming Ma, Baihao Shao, Molly M. Stevens   +3 more
wiley   +1 more source

From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts

Angewandte Chemie, EarlyView.
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk, Lars J. C. van der Zee, Simon Mathew, Bas de Bruin, J. Chris Slootweg   +4 more
wiley   +2 more sources

UV Laser-Induced Photodecomposition of Matrix-Isolated Salicylhydroxamic Acid: Identification of New Isocyanate Complexes

Molecules
Photochemical reactions of salicylhydroxamic acid were induced using tunable UV laser radiation followed by FTIR spectroscopy. Four pairs of co-products were experimentally found to appear in the photolysis: C6H4(OH)NCO⋯H2O (1), C6H4(OH)C(O)N⋯H2O (2 ...
Magdalena Sałdyka, Zofia Mielke
doaj   +1 more source