Results 101 to 110 of about 4,438 (202)
Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger +3 more
wiley +1 more source
Cu‐based catalysts as a cornerstone in advancing sustainable energy technologies are fully reviewed in this manuscript, highlighting their potential in photo‐ and electrocatalysis. It includes metallic copper, copper oxides, copper sulfides, copper halide perovskites, copper‐based metal–organic frameworks (MOFs), and covalent organic frameworks (COFs),
Jéssica C. de Almeida +16 more
wiley +1 more source
Photoredox-catalyzed intramolecular nucleophilic amidation of alkenes with β-lactams
The direct nucleophilic addition of amides to unfunctionalized alkenes via photoredox catalysis represents a facile approach towards functionalized alkylamides.
Valentina Giraldi +4 more
doaj +1 more source
The holographic recording performance of the photopolymerizable hybrid sol–gel is enhanced by optimizing photoinitiating systems based on boron dipyrromethene dyes. Two‐ and three‐component type‐II photoinitiating systems are employed, and their photopolymerization efficiency is evaluated through holographic patterning at 532 nm.
Tatsiana Mikulchyk +4 more
wiley +1 more source
Photocatalytic Micro/Nanomotors Functioning in the Near‐Infrared Window for Biomedical Applications
This review focuses on near‐infrared responsive photocatalytic micro/nanomotors based on inorganic materials, with particular emphasis on minimally invasive biomedical applications. It discusses material strategies for achieving near‐infrared responsiveness, including heterostructure construction, upconversion nanoparticle integration, defect ...
Yufen Chen +2 more
wiley +1 more source
Photocatalytic CO‐Free Hydroformylation: Unlocking New Horizons for a Classic Reaction
ABSTRACT Hydroformylation, the conversion of alkenes into aldehydes, is a cornerstone industrial process, as aldehydes serve as versatile intermediates for numerous chemical transformations. Conventionally, this process operates under pressure of CO and H2 (syngas) and relies on homogeneous catalysis.
Carla S. Cunha +2 more
wiley +1 more source
This work demonstrates catalytic reductive allylation of ketones, aldehydes, and imines using a platinum/photoredox system. The method exhibits broad substrate scope and affords homoallylic alcohols and amines difficult to access with conventional methods.
Junpei Shimosato +5 more
wiley +1 more source
Photocatalytic CO2 reduction represents a sustainable strategy to convert greenhouse gases into fuels and value‐added chemicals driven by solar energy, showing great potential for carbon recycling. However, the inherent inertness of CO2 poses a significant challenge to achieving efficient photocatalytic CO2 reduction. Among various catalysts, dinuclear
Zongyang Liu +5 more
wiley +1 more source
Making Blank Faces Expressive: Chemical Approaches to the Modification of Chemically Inert Peptides
As an alternative to the conventional approach, which combines amino acid monomers in a one‐by‐one fashion to peptide derivatives, the chemical modification of existing peptides has attracted significant attention in recent years. However, such approaches generally target the reactive functional groups in cysteine and lysine residues, particularly in ...
Yoshitaka Moriyama +2 more
wiley +1 more source
This work reveals direct on‐surface photosynthesis of Poly‐bis(pyridyl)butadiyne (PBPyB) from simple BPyB precursors. Long straight 1D‐conjugated polymer wires with trans positioning of the pyridine moieties are revealed for the first time by scanning tunneling microscopy (STM).
Yan Wu +8 more
wiley +1 more source

