Results 31 to 40 of about 3,943 (245)

Light-Driven Charge Transport and Optical Sensing in Molecular Junctions

open access: yesNanomaterials, 2022
Probing charge and energy transport in molecular junctions (MJs) has not only enabled a fundamental understanding of quantum transport at the atomic and molecular scale, but it also holds significant promise for the development of molecular-scale ...
Chaolong Tang   +4 more
doaj   +1 more source

Enhancing tetraphenylethene cyclization as photoswitch

open access: yesSmart Molecules, 2023
Tetraphenylethene (TPE), a star building block with promising aggregation‐induced emission, has received much interest. Given that its intramolecular Woodward‐Hoffmann cyclic intermediate instantaneously converts back to the original state within several
Yue Wu   +9 more
doaj   +1 more source

Optocontrol of glutamate receptor activity by single side-chain photoisomerization

open access: yeseLife, 2017
Engineering light-sensitivity into proteins has wide ranging applications in molecular studies and neuroscience. Commonly used tethered photoswitchable ligands, however, require solvent-accessible protein labeling, face structural constrains, and are ...
Viktoria Klippenstein   +4 more
doaj   +1 more source

Two-Photon Excitation of Azobenzene Photoswitches for Synthetic Optogenetics

open access: yesApplied Sciences, 2020
Synthetic optogenetics is an emerging optical technique that enables users to photocontrol molecules, proteins, and cells in vitro and in vivo. This is achieved by use of synthetic chromophores—denoted photoswitches—that undergo light ...
Shai Kellner, Shai Berlin
doaj   +1 more source

Photoswitchable Probes of Oxytocin and Vasopressin

open access: yesJournal of Medicinal Chemistry, 2023
Oxytocin (OT) and vasopressin (VP) are related neuropeptides that regulate many biological processes. In humans, OT and VP act via four G protein-coupled receptors, OTR, V1aR, V1bR, and V2R (VPRs), which are associated with several disorders. To investigate the therapeutic potential of these receptors, particularly in the receptor-dense areas of the ...
Wirth, Ulrike   +5 more
openaire   +5 more sources

Sterically Hindered Stiff-Stilbene Photoswitch Offers Large Motions, 90% Two-Way Photoisomerization, and High Thermal Stability

open access: yes, 2022
Molecular photoswitches have been widely used as molecular machines in various fields due to the small structures and simple motions generated in reversible isomerization.
Kazuki Ohira (14122582)   +7 more
core   +1 more source

Modulating photoswitch performance with halogen, coordinative and hydrogen bonding : a comparison of relative bond strengths

open access: yes, 2021
The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of
Sethio, Daniel   +10 more
core   +1 more source

On/Off Photoswitching of the Electropolymerizability of Terthiophenes [PDF]

open access: yesJournal of the American Chemical Society, 2008
In this contribution the polymerization of terthiophene, to form an alkene bridged alpha,alpha-coupled sexithiophene polymer, is controlled by light; i.e. the electropolymerizability of the monomer 1F is switched off and on with UV and visible light, respectively. The system comprises of both bis-terthiophene and photochromic dithienylethene units. The
Areephong, Jetsuda   +7 more
openaire   +3 more sources

Dynamic Force Spectroscopy of Photoswitch-Modified DNA

open access: yes, 2016
We apply a combination of photoswitch-modified DNA and AFM-based pulling measurements to study the force-induced melting of double-stranded DNA in the unzipping geometry.
Keiko Munechika (1830142)   +4 more
core   +1 more source

A Chiroptical Photoswitchable DNA Complex [PDF]

open access: yesThe Journal of Physical Chemistry B, 2011
The interesting structural, electronic, and optical properties of DNA provide fascinating opportunities for developing nanoscale smart materials by integrating DNA with opto-electronic components. In this article we demonstrate the electrostatic binding of an amine-terminated dithienylethene (DET) molecular switch to double-stranded synthetic ...
- Mammana   +4 more
openaire   +3 more sources

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