Schizophrenic molecules and materials with multiple personalities - how materials science could revolutionise how we do chemical sensing [PDF]
, 2009 Molecular photoswitches like spiropyrans derivatives offer exciting possibilities for the development of analytical platforms incorporating photo-responsive materials for functions such as light-activated guest uptake and release and optical reporting on
Scarmagnani, Silvia +9 more
core +1 more source
Design rules for optimization of photophysical and kinetic properties of azoarene photoswitches [PDF]
, 2023 Azoarenes are an important class of molecular photoswitches that often undergo E➝Z isomerization with ultraviolet light and have short Z-isomer lifetimes.
Steven, Lopez, Daniel, Adrion
core +1 more source
Effects of π-Extension on Pyrrole Hemithioindigo Photoswitches [PDF]
, 2019 The most red-shifted hemithioindigo photoswitches have been identified through systematic introduction of aryl units to a parent pyrrole hemithioindigo photoswitch.
Junrou Huang (6489844) +3 more
core +4 more sources
Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties [PDF]
Styrylbenzazoles form a promising yet under-represented class of photoswitches that can perform a light-driven E-Z isomerization of the central alkene double bond without undergoing irreversible photocyclization, typical of the parent stilbene.
Feringa, Ben L., +7 more
core +1 more source
Comparative Analysis of Model‐Agnostic Explanation Methods in Materials Science
Advanced Intelligent Systems, EarlyView.To address the critical lack of explainable artificial intelligence (XAI) benchmarks in materials science, we present a quantitative and qualitative analysis of six XAI methods applied to molecular fingerprints. Our results reveal significant discrepancies in feature importance rankings, demonstrating that the chosen explanation approach introduces ...
Anna Przybyłowska +7 more
wiley +1 more source
Synthesis, characterization and applicability of three isotope labeled azobenzene photoswitches
, 2008 We describe a short, efficient approach for the synthesis of three novel isotope labeled azobenzene photoswitches. Synthesis is based on commercially available fully isotope labeled precursors.
Kolano, C +7 more
core +1 more source
Design, synthesis and application of arylazopyrazole photoswitches
, 2022 Photoswitches are molecules that can undergo reversible changes to their physical and chemical properties upon irradiation with light. The arylazopyrazoles are a class of azo-based photoswitch, which show excellent photochemical properties such as ...
Gibson, Rosina
core +1 more source
ChemistryOpen, 2019 Modular synthesis of structurally diverse functionalized azobiphenyls and azoterphenyls for the realization of optically switchable materials has been described.
Dr. Sylvain Grosjean +5 more
doaj +1 more source
Substituent effects in N-acetylated phenylazopyrazole photoswitches
Beilstein Journal of Organic ChemistryPhenylazopyrazole photoswitches proved to be valuable structural motifs for various applications ranging from materials science to medicine. Despite their potential, their structural diversity is still limited and a larger pool of substitution patterns ...
Radek Tovtik +4 more
doaj +1 more source
Chemical control over hemi-indigo photoswitches [PDF]
Photoswitches have found widespread application as tools to reversibly change chemical and/or physical properties at the molecular level, thereby affecting their surrounding environment.
Duindam, N.
core +1 more source