Results 191 to 200 of about 1,369,061 (328)

Cooperative Photometallobiocatalysis: Nonheme Fe Enzyme‐Catalyzed Enantioconvergent Radical Decarboxylative Azidation, Thiocyanation, and Isocyanation of Redox‐Active Esters

open access: yesAngewandte Chemie, EarlyView.
Through the directed evolution of an underexploited nonheme Fe extradiol dioxygenase, we developed a unified cooperative photobiocatalytic strategy to allow for three types of enantioconvergent radical transformations, including azidation, thiocyanation, and isocyanation.
Liu‐Peng Zhao   +8 more
wiley   +2 more sources

Architected Microalgae‐Based Matter via 3D Printing: Properties, Printing Techniques, and Applications

open access: yesAdvanced NanoBiomed Research, EarlyView.
Microalgae are emerging as sustainable and economical bioresources that can be utilized as bioinks for creating constructs with intriguing functionalities. This review discusses the properties and applications of microalgae, providing a comprehensive review of recent advancements and challenges in 3D‐printed microalgae‐based constructs for various ...
Yiwei Zou   +3 more
wiley   +1 more source

Molecular phylogenetics and evolution

open access: yes, 2014
73
Munoz-Ramirez, C. P.   +5 more
openaire   +6 more sources

Phylogenetic Resolution and Quantifying the Phylogenetic Diversity and Dispersion of Communities

open access: yesPLoS ONE, 2009
Conservation biologists and community ecologists have increasingly begun to quantify the phylogenetic diversity and phylogenetic dispersion in species assemblages. In some instances, the phylogenetic trees used for such analyses are fully bifurcating, but in many cases the phylogenies being used contain unresolved nodes (i.e. polytomies).
openaire   +5 more sources

Invariants for level-1 phylogenetic networks under the random walk 4-state Markov model [PDF]

open access: yesarXiv
Phylogenetic networks can represent evolutionary events that cannot be described by phylogenetic trees, such as hybridization, introgression, and lateral gene transfer. Studying phylogenetic networks under a statistical model of DNA sequence evolution can aid the inference of phylogenetic networks.
arxiv  

Bounding the softwired parsimony score of a phylogenetic network [PDF]

open access: yesarXiv
In comparison to phylogenetic trees, phylogenetic networks are more suitable to represent complex evolutionary histories of species whose past includes reticulation such as hybridisation or lateral gene transfer. However, the reconstruction of phylogenetic networks remains challenging and computationally expensive due to their intricate structural ...
arxiv  

Tertiary Lymphoid Organs Are Associated With Bacterial Dysbiosis in Chronic Rhinosinusitis

open access: yes
International Forum of Allergy &Rhinology, EarlyView.
Sathish Paramasivan   +9 more
wiley   +1 more source

Identification of an Activity Selector for the Nitroso‐Forming Activity in Bacterial Type‐III Copper Enzymes

open access: yesAngewandte Chemie International Edition, EarlyView.
Small but crucial difference: Type‐III copper enzymes, like tyrosinase (TYR) and o‐aminophenol oxidase (AO), catalyze the oxidation of o‐aminophenols (AP) to quinone imines. Unlike TYR, AO can further oxidize AP to nitrosophenols. This nitroso‐forming activity is controlled by a key amino acid near the Cu(A) ion.
Hoa Le Xuan, Felix Panis, Annette Rompel
wiley   +1 more source

Mixing and Matching of Hybrid Megasynthases is a Hub for the Evolution of Metabolic Diversity in Cyanobacteria

open access: yesAngewandte Chemie International Edition, EarlyView.
Natural combinatorics: Evolutionary mixing and matching of three cyanobacterial biosynthetic gene clusters resulted in the emergence of minutumamides, a novel family of peptide‐polyketide hybrids. Retro‐evolutionary analysis led to the discovery of nostopeptolide KVJ3, an evolutionary ancestor that links nostopeptolide and minutumamide biosynthesis and
Keishi Ishida   +6 more
wiley   +1 more source

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