Results 21 to 30 of about 1,033 (184)

Selective enclathration of picolines [PDF]

open access: yesActa Crystallographica Section A Foundations of Crystallography, 2004
The host 1,1,2,2-tetraphenyl-1,2-ethane diol has been employed to separate the isomers 2-picoline (2-pic), 3-picoline (3-pic), and 4-picoline (4-pic) by selective enclathration. The crystal structures are all stabilized by (host)-O−H···N(guest) hydrogen bonds. The competition experiments show that enclathration preferentially takes place in the order 4-
Susan A. Bourne   +3 more
openaire   +1 more source

Dual‐Functional Sulfonated Nanocellulose for Proton Exchange Membranes With High Proton Conductivity at Low Humidity

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A scalable dual‐functional strategy yields simultaneously sulfonated and nanosized cellulose for proton exchange membranes with continuous hydrogen‐bond networks. These sustainable membranes exhibit low‐humidity proton conductivity twofold higher than Nafion 212, providing a robust solution for next‐generation fuel cells.
Nan Li   +6 more
wiley   +1 more source

Trace level detection of analytes using artificial olfactometry [PDF]

open access: yes, 2001
The present invention provides a device for detecting the presence of an analyte, wherein said analyte is a microorganism marker gas. The device comprises a sample chamber having a fluid inlet port for the influx of the microorganism marker gas; a fluid ...
Lewis, Nathan S.   +2 more
core   +2 more sources

Chan–Lam Cross‐Coupling With Alkylboron Reagents: From Transmetallation to Radical Pathways

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Alkylative Chan–Lam coupling overcomes intrinsic transmetallation limitations of alkylboron reagents by engaging radical pathways. Recent advances reveal how radical and radical–polar crossover mechanisms enable mild C(sp3)—heteroatom bond formation. This minireview highlights key mechanistic insights and emerging strategies that transform alkylboron ...
Nicolas G.‐Simonian   +3 more
wiley   +1 more source

Chemo‐Enzymatic Route for Covalent Cellulose Fiber Dyeing

open access: yesChemistry – A European Journal, Volume 32, Issue 14, 15 April 2026.
This work presents a proof of concept for a chemo‐enzymatic approach to the covalent dyeing of cotton fibers. Laccase/TEMPO oxidation introduces aldehyde groups, enabling subsequent reductive amination with amino dyes. Excellent color homogeneity and wash fastness were demonstrated using acid red 33, highlighting the robustness of the approach and its ...
Awilda Maccow   +6 more
wiley   +1 more source

Simplified Assembly Process for Efficient Light‐Driven MOF‐Based Water Oxidation Catalysts in Acidic pH

open access: yesChemPhotoChem, Volume 10, Issue 4, April 2026.
MOF based photoanodes for light driven water oxidation can be created by combination of Fe3O nodes in MOFs such as MIL101 and highly active Ru‐based single site water oxidation catalyst. Even with linker mismatch the MOF assembles and shows stable performance in photoelectrochemical water oxidation.
Jully Patel   +3 more
wiley   +1 more source

Benzo[g]quinoline heterocyclic derivative as a typical precursor in the synthesis of new class of cyanine-like dyes [PDF]

open access: yes, 2012
New unsymmetrical cyanine-like dyes have been synthesized including monomethine, dimethine, and tetramethine, containing heterocyclic quinone of benzo[g]quinoline derivative.
El-Deen, Naglaa Salah   +2 more
core   +1 more source

Synthesis and Biological Profile of Substituted Pyrrolidinyl Carboxamides for Acyl‐ACP Thioesterase Inhibition

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 12, 23 March 2026.
The work outlined herein covers a series of novel herbicidal lead structures that possess a pyrrolidinyl pyrazole carboxamide scaffold as a key structural feature, carrying further substituted benzyl side chains. Based on scaffold hopping approaches from known fungicidal and herbicidal compounds and utilizing an optimized synthetic approach, a broader ...
Elisabeth Asmus   +24 more
wiley   +1 more source

Direct‐to‐Biology: Streamlining the Path From Chemistry to Biology in Drug Discovery

open access: yesChemMedChem, Volume 21, Issue 4, 25 February 2026.
Crude yet clever: Direct‐to‐biology workflows exploit nanoscale synthesis and plate‐based assays to accelerate hit discovery, save precious intermediates, and rethink early drug discovery. Direct‐to‐biology (D2B) has emerged as a transformative concept in early drug discovery, defined by the direct on‐target screening of crude reaction mixtures without
Ariane F. Hübner, Fabian Barthels
wiley   +1 more source

Incorporating Heavy Atom Effect onto Molecular Rotors for Realizing Exceptionally Photocatalytic Oxidation Reaction under Low‐Temperature Conditions

open access: yesAdvanced Materials Interfaces, Volume 13, Issue 3, 3 February 2026.
Here, we reported a series of molecular‐rotor‐based photoactivated oxidase mimics, DAPy‐Xm, in which heavy atom incorporation enhances both ROS generation and cold‐adapted property. Among them, DAPy‐Im enables efficient photo‐oxidation of ergosterol and photocatalytic H2O2 production at low temperature.
Barbara Zenabu Anibea   +3 more
wiley   +1 more source

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