Results 1 to 10 of about 266 (146)

Crystallization Kinetics and Polymorphic Transformations in Polybutene-1. [PDF]

open access: yesJ Res Natl Bur Stand A Phys Chem, 1965
When subcooled from the melt to any temperature between about 90 to 110 °C, polybutene-1 transforms at a readily measurable rate to a crystalline phase denoted "form 2," which is typically spherulitic. The kinetics of this process have been measured by optical and dilatometric techniques. The results are consistent with the concepts that the initiation
Powers J   +3 more
europepmc   +3 more sources

Synthesis of Isotactic Polybutene-1 with Ziegler-Natta Catalyst [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2022
Hypothesis: Butene-1 is in excess in the polyolefin plants of Iran. Considering the properties of isotactic polybutene-1, including high creep and environmental stress cracking resistances, excellent elastic reversibility and good chemical abrasion ...
shokoufeh Hakim   +2 more
doaj   +1 more source

LDPE and poly(1-butene) blends: Morphology, crystallinity and rheological properties [PDF]

open access: yesPolyolefins Journal, 2021
In this work, the compatibility and crystallinity of low density polyethylene (LDPE) and polybutene-1 (PB-1) blends were studied. Various blends of LDPE/PB-1 containing 5, 10 and 20 wt.% PB-1 were prepared in a corotating twin-screw extruder and ...
Reza Poorghasemi, Yousef Jahani
doaj   +1 more source

Mpemba effect in crystallization of polybutene-1

open access: yesSoft Matter, 2023
The Mpemba effect and its inverse can be understood as a result of nonequilibrium thermodynamics.
Jinghua Liu   +4 more
openaire   +3 more sources

An improved method for the high isotacticity measurement of polybutene-1

open access: yesPolymer Testing, 2021
High isotactic polybutene-1 (HiPB) plays important roles in presenting outstanding resistance to creep and crack at high temperature. Therefore, rapid and accurate measurement of the HiPB is extremely important for both synthesis and application of ...
Weiping Zheng   +4 more
doaj   +1 more source

The influence of branching efficiency on the rheology and morphology of melt state long chain branched polypropylene/polybutene-1 blends [PDF]

open access: yesPolyolefins Journal, 2019
In this study, the compatibility of the blends of polypropylene (PP) and polybutene-1(PB-1) homopolymer before and after long chain branching process were studied.
Ali Foroozan   +2 more
doaj   +1 more source

Accelerated crystallization and crystal-crystal transition of PB induced by PP with optimized content

open access: yesPolymer Testing, 2023
Isotactic polybutene-1 (PB)/isotactic polypropylene (PP) blends, typical crystalline/crystalline polymer blends with low-melting-temperature (Tm) PB and high-Tm PP, exhibit complicated interactions between their components in both molten and solid states.
Xiangjie Yan   +5 more
doaj   +1 more source

High-temperature creep behaviors of polybutene-1 with different chain microstructure and molecular weight

open access: yesPolymer Testing, 2023
The creep resistance of polymer determines the dimensional stability of product under stress. The isotactic polybutene-1 (iPB) with outstanding high-temperature creep resistance and stress-crack resistance is applied widely in the field of hot-water ...
Yuanjin Zhao   +3 more
doaj   +1 more source

Crystallinity and Stereoregularity of Polybutene-1

open access: yesKobunshi Kagaku, 1962
X線回折による結晶化度と密度とを主としてZieglem触媒により合成したポリブテン-1について測定した。結晶化度と比容積との間に直線関係が成立することから, 結晶質と非晶質の密度の値0.950および0, 868が得られた。アイソタクチックポリブテン-1には結晶化バンドとみなしうる吸収が多数見出された。一方, 1221cm-1バンドは固態状態ではその吸光度比の値が比容積と直線関係を示すが溶融状態や溶液で消失しない。したがって固態状態で一定の熱処理をした試料について比較するときには結晶化度の尺度として使用しうると考えられる。吸光度比 (A1221/A1151) と密度 (d) との間には次の実験式が成立する。
Atsuo Nishioka, Kazuo Yanagisawa
  +6 more sources

Home - About - Disclaimer - Privacy