Mpemba effect in crystallization of polybutene-1 [PDF]
The Mpemba effect and its inverse can be understood as a result of nonequilibrium thermodynamics.
Jinghua Liu+4 more
core +7 more sources
Crystallization Kinetics and Polymorphic Transformations in Polybutene-1. [PDF]
When subcooled from the melt to any temperature between about 90 to 110 °C, polybutene-1 transforms at a readily measurable rate to a crystalline phase denoted "form 2," which is typically spherulitic. The kinetics of this process have been measured by optical and dilatometric techniques. The results are consistent with the concepts that the initiation
Powers J+3 more
europepmc +5 more sources
Applicazione della meccanica della frattura viscoelastica alla previsione della vita di tubi in polibutene [PDF]
Isotactic polybutene-1 (i-PB1) is a polymer used for the manufacturing of pressurized pipes. In this work two grades of i-PB1 with a different degree of isotacticity have been investigated; they have been supplied by Basell Polyolefins. Fracture tests
Luca Andena+2 more
doaj +6 more sources
Lamellar thickness and stretching temperature dependency of cavitation in semicrystalline polymers. [PDF]
Polybutene-1 (PB-1), a typical semicrystalline polymer, in its stable form I shows a peculiar temperature dependent strain-whitening behavior when being stretched at temperatures in between room temperature and melting temperature of the crystallites ...
Yaotao Wang+4 more
doaj +4 more sources
Novel aspects in the crystallization of polybutene-1 [PDF]
Semicrystalline polymers cover over two thirds of commercially produced polymeric materials, and have been widely applied to many areas of the modern society, including building and construction, electronics, packaging, etc. Understanding the behavior of polymer crystallization is of critical importance due to the significant impact of the ...
Wang, Wei
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Interlocking shish‐kebab morphology in polybutene‐1 [PDF]
AbstractThe aim of this research was to explore the effect of shear‐controlled orientation injection molding (SCORIM) on polybutene‐1 (PB‐1). This article describes the methods and processing conditions used for injection molding and discusses the properties of the moldings.
Kalay G., Kalay, C.R.
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An improved method for the high isotacticity measurement of polybutene-1
High isotactic polybutene-1 (HiPB) plays important roles in presenting outstanding resistance to creep and crack at high temperature. Therefore, rapid and accurate measurement of the HiPB is extremely important for both synthesis and application of ...
Weiping Zheng+4 more
doaj +3 more sources
Cross-Nucleation between Polymorphs: Quantitative Modeling of Kinetics and Morphology. [PDF]
Cross-nucleation is defined as the nucleation of one polymorph on the surface of another polymorph of the same substance. Although the description of this particular form of heterogeneous nucleation is mainly phenomenological, recently dedicated ...
Looijmans SFSP+3 more
europepmc +5 more sources
Synthesis of Isotactic Polybutene-1 with Ziegler-Natta Catalyst [PDF]
Hypothesis: Butene-1 is in excess in the polyolefin plants of Iran. Considering the properties of isotactic polybutene-1, including high creep and environmental stress cracking resistances, excellent elastic reversibility and good chemical abrasion ...
shokoufeh Hakim+2 more
doaj +1 more source
The Crystallization behaviour of isotactic polybutene-1 [PDF]
ABSTRACT THE CRYSTALLIZATION BEHAVIOUR OF ISOTACTIC POLYBUTENE-1 Haci Bayram Erdem M. S in Chemistry Supervisor: Assist. Prof. Dr. Gürhan Kalay August 2002 The crystallization behaviour of different commercial grades of isotactic polybutene-1 was investigated and an experimental set-up was designed for this research study.
Erdem, Hacı Bayram
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