Results 61 to 70 of about 1,047,412 (314)

The (Glg)ABCs of cyanobacteria: modelling of glycogen synthesis and functional divergence of glycogen synthases in Synechocystis sp. PCC 6803

open access: yesFEBS Letters, EarlyView.
We reconstituted Synechocystis glycogen synthesis in vitro from purified enzymes and showed that two GlgA isoenzymes produce glycogen with different architectures: GlgA1 yields denser, highly branched glycogen, whereas GlgA2 synthesizes longer, less‐branched chains.
Kenric Lee   +3 more
wiley   +1 more source

Polymerization of Cycloolefines

open access: yesKobunshi Kagaku, 1969
1, 3-シクロオクタジエソ (1, 3-COD) と液体亜硫酸 (SO2) との共重合について検討した。1, 3-CODはAgNO3, H2O2などの添加によりSO2と共重合し, DMF, DMSOおよびSO2に可溶な1: 1組成のポリスルポソを与える。共役二重結合へのSO2の付加は主に1, 2-付加であろうと推定した。AgNO3を触媒とし, 過剰のSO2中で重合を行なった場合共重合初速度はAgNO3初濃度の1/2乗に比例し (0℃), 活性化エネルギーは約8.5kcal/mol (-10-+15℃) であった。重合初速度は約20℃に極大を有し, それ以上の温度では急激に低下し, 天井温度が35-40℃付近に存在することがわかった ([1, 3-COD] 0・[SO2] 0=10mol2/l2 ...
Tadashi Yamaguchi, Katsutoshi Nagai
openaire   +3 more sources

Structural insights into an engineered feruloyl esterase with improved MHET degrading properties

open access: yesFEBS Letters, EarlyView.
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa   +5 more
wiley   +1 more source

Polymerization-Induced Cooperative Assembly of Block Copolymer and Homopolymer via RAFT Dispersion Polymerization

open access: yes, 2017
Polymerization-induced cooperative assembly (PICA) is developed to promote morphological transitions at high solids via RAFT dispersion polymerization, using both a macromolecular chain transfer agent (macro-CTA) and a small molecule chain transfer agent
Xiaoqing Lv (1491601)   +4 more
core   +1 more source

Hyperosmotic stress induces PARP1‐mediated HPF1‐dependent mono(ADP‐ribosyl)ation

open access: yesFEBS Letters, EarlyView.
Sorbitol‐induced hyperosmotic stress rapidly induces reversible mono(ADP‐ribosyl)ation (MARylation) on PARP1 without the signs of genotoxic signaling. We show that PARP1 autoMARylation is HPF1 dependent and forms hydroxylamine‐resistant O‐glycosidic linkages.
Anna Georgina Kopasz   +11 more
wiley   +1 more source

Polymerization-Induced Self-Assembly Promoted by Liquid–Liquid Phase Separation

open access: yes, 2019
Polymerization-induced self-assembly (PISA) is a powerful method for the synthesis of polymeric kinetically frozen core nanoparticles. However, the PISA synthesis of biologically important polymeric fluidic materials is unexplored.
Yi Ding (172783)   +13 more
core   +3 more sources

Effects of Isocyanate-to-Polyols (NCO/OH) Ratio on Bio-based Polyurethane Film from Palm Kernel Oil based Monoester Polyols (PKO-p) for Polymer Electrolytes Application

open access: yesMedžiagotyra, 2022
This study investigated the synthesis of bio-based polyurethane (PU) film from palm kernel oil-based polyols (PKO-p) at four different isocyanate-to-polyols (NCO/OH) ratios comprising 100/100, 100/150, 100/200, and 100/250.
Mohd Sukor SU'AIT   +3 more
doaj   +1 more source

Kinetic Aspects of Polyester Solid State Polymerization

open access: yes, 2009
The chapter describe the solid state polymerization of polyesters, and in particular it deals with 3.1. Introduction 3.2. Phenomena involved in solid state polymerization of polyesters 3.2.1. Possible reactions in solid state polymerization of polyesters
PILATI, Francesco   +3 more
core   +1 more source

The ubiquitin‐proteasome system and autophagy as guardians of the cellular proteome

open access: yesFEBS Letters, EarlyView.
This Perspective covers the three principles governing the crosstalk between the ubiquitin‐proteasome system and autophagy in cellular proteostasis: (1) a shared ubiquitin code routing substrates via shuttle factors or autophagy receptors; (2) spatial compartmentalization into phase‐separated degradation hubs and organelle‐specific modules (exemplified
Ivan Dikic
wiley   +1 more source

New Insight into the Effect of Different Interactions of Polymers with Various Molecular Structures on the Surface Covering and Rheology of Cement Particle Suspension [PDF]

open access: yesعلوم و تکنولوژی پلیمر
Hypothesis: Water-soluble polymers with different structures are used as additives in cements. The types of functionalities are hydroxy, amine, sulfonate, and carboxylate ions. Polyethylene glycol branches in different sizes and numbers are placed inside
Mohammad Reza Rostami Daronkola   +4 more
doaj   +1 more source

Home - About - Disclaimer - Privacy