Results 1 to 10 of about 282 (111)

Mechanistic modeling of polysulfide shuttle and capacity loss in lithium–sulfur batteries [PDF]

Journal of Power Sources, 2014
Abstract Lithium–sulfur (Li/S) cells are promising candidates for a next generation of safe and cost-effective high energy density batteries for mobile and stationary applications. At present, most Li/S cells still suffer from relatively poor cyclability, capacity loss under moderate current densities and self-discharge.
Wolfgang G Bessler, Andreas Felix Hofmann, David N Fronczek   +2 more
exaly   +4 more sources

Advances in Strategic Inhibition of Polysulfide Shuttle in Room-Temperature Sodium-Sulfur Batteries via Electrode and Interface Engineering

Batteries, 2023
Room-temperature sodium-sulfur batteries (RT-NaSBs) with high theoretical energy density and low cost are ideal candidates for next-generation stationary and large-scale energy storage.
Chun Huang, Anupriya K Haridas, Huang Chun   +2 more
exaly   +3 more sources

Tunnel Structure Enhanced Polysulfide Conversion for Inhibiting “Shuttle Effect” in Lithium-Sulfur Battery

Nanomaterials, 2022
The Lithium sulfur (Li-S) battery has a great potential to replace lithium-ion batteries due to its high-energy density. However, the “shuttle effect” of polysulfide intermediates (Li2S8, Li2S6, Li2S4, etc.) from the cathode can lead to rapid capacity ...
Xiaotong Guo, Xu Bi, Junfeng Zhao, Xinxiang Yu, Han Dai   +4 more
doaj   +3 more sources

Approaches to Combat the Polysulfide Shuttle Phenomenon in Li–S Battery Technology

Batteries, 2022
Lithium–sulfur battery (LSB) technology has tremendous prospects to substitute lithium-ion battery (LIB) technology due to its high energy density. However, the escaping of polysulfide intermediates (produced during the redox reaction process) from the cathode structure is the primary reason for rapid capacity fading.
Braja Mandal, Cindy Mei
exaly   +3 more sources

Suppression strategies for the polysulfide shuttle effect in electrolyte systems

Communications Materials
Despite their theoretical high energy density, the commercialization of lithium-sulfur (Li-S) batteries has yet to be realized due to fundamental challenges in sulfur redox chemistry.
Junru Ke, Zhihua Wang, He Zhu, Mingxiao Chen, Ruoyu Song, Qingmin Ji, Dong Liu, Si Lan   +7 more
doaj   +2 more sources

Selective catalysis remedies polysulfide shuttling in lithium-sulfur batteries [PDF]

Advanced Materials, 2020
Abstract The shuttling of soluble lithium polysulfides between the electrodes leads to serious capacity fading and excess use of electrolyte, which severely bottlenecks practical use of Li-S batteries. Here selective catalysis is proposed as a fundamental remedy for the consecutive solid-liquid-solid sulfur redox reactions. The proof-of-concept
Wuxing Hua, Huan Li, Chun Pei, Jingyi Xia, Yafei Sun, Chen Zhang, Wei Lv, Ying Tao, Yan Jiao, Bingsen Zhang, Shizhang Qiao, Ying Wan, Quan-Hong Yang   +12 more
openaire   +2 more sources

A polysulfide radical anions scavenging binder achieves long‐life lithium–sulfur batteries

Battery Energy, 2022
Fast capacity decay caused by the polysulfide shuttle is the primary cause to impede the practical application of lithium–sulfur (Li–S) batteries. The polysulfide shuttle involves the evolution of polysulfide dianions (Li2Sx, x = 3–8) and radical anions (
Chengdong Wang, Yue Ma, Xiaofan Du, Huanrui Zhang, Gaojie Xu, Guanglei Cui   +5 more
doaj   +1 more source

Polysulfide Catalytic Materials for Fast‐Kinetic Metal–Sulfur Batteries: Principles and Active Centers

Advanced Science, 2022
Benefiting from the merits of low cost, ultrahigh‐energy densities, and environmentally friendliness, metal–sulfur batteries (M–S batteries) have drawn massive attention recently.
Menghao Cheng, Rui Yan, Zhao Yang, Xuefeng Tao, Tian Ma, Sujiao Cao, Fen Ran, Shuang Li, Wei Yang, Chong Cheng   +9 more
doaj   +1 more source

Electrolyte Measures to Prevent Polysulfide Shuttle in Lithium‐Sulfur Batteries

Batteries & Supercaps, 2022
Abstract Lithium‐sulfur (Li−S) batteries are recognized as one of the most promising technologies with the potential to become the next‐generation batteries. However, to ensure Li−S batteries reach commercialization, complex challenges remain, among which the tailoring of an appropriate electrolyte is the most important.
Di Donato G., Ates T., Adenusi H., Varzi A., Navarra M. A., Passerini S.   +5 more
openaire   +4 more sources

NiFe₂O₄/Ketjen Black Composites as Efficient Membrane Separators to Suppress the Shuttle Effect for Long-Life Lithium-Sulfur Batteries

Nanomaterials, 2022
Lithium-sulfur batteries exhibit great potential as one of the most promising energy storage devices due to their high theoretical energy density and specific capacity.
Wen Jiang, Lingling Dong, Shuanghui Liu, Shuangshuang Zhao, Kairu Han, Weimin Zhang, Kefeng Pan, Lipeng Zhang   +7 more
doaj   +1 more source