Illuminating Polysulfide Distribution in Lithium Sulfur Batteries; Tracking Polysulfide Shuttle Using Operando Optical Fluorescence Microscopy [PDF]
ACS Applied Materials & InterfacesHigh-energy-density lithium sulfur (Li-S) batteries suffer heavily from the polysulfide shuttle effect, a result of the dissolution and transport of intermediate polysulfides from the cathode, into the electrolyte, and onto the anode, leading to rapid cell degradation.
Coke, K +5 more
core +8 more sources
Electrostatic Polysulfides Confinement to Inhibit Redox Shuttle Process in the Lithium Sulfur Batteries [PDF]
ACS Applied Materials & Interfaces, 2017 Cationic polymer can capture polysulfide ions and inhibit polysulfide shuttle effect in lithium sulfur (Li-S) rechargeable batteries, enhancing the Li-S battery cycling performance. The cationic poly[bis(2-chloroethyl) ether-alt-1,3-bis[3-(dimethylamino) propyl]urea] quaternized (PQ) with a high density quaternary ammonium cations can trap the lithium ...
Min Ling +6 more
openaire +4 more sources
Recent advances in polysulfide mediation of lithium-sulfur batteries via facile cathode and electrolyte modification [PDF]
APL Materials, 2019 Lithium–sulfur (Li–S) batteries have garnered immense interest due to their potential to surpass the energy densities of state-of-the-art lithium-ion batteries.
Chen Fang +3 more
doaj +3 more sources
Multifunctional cation-vacancy-rich ZnCo2O4 polysulfide-blocking layer for ultrahigh-loading Li-S battery [PDF]
, 2021 The major hurdle in Li-S battery commercialization is the severe shuttle effect and sluggish reaction kinetics of polysulfide conversion during charge-discharge cycling.
Luke Hencz +15 more
core +3 more sources
Polysulfide shuttle suppression by electrolytes with low-density for high-energy lithium-sulfur batteries [PDF]
, 2022 Art. 1900625, 12 S.A low‐density electrolyte composition is introduced for lithium-sulfur (Li-S) batteries with intrinsic and effective polysulfide shuttle suppression.
Weller, Christine +4 more
core +1 more source
Aligned Bilayer of Single-Walled Carbon Nanotubes Suppresses the Polysulfide Shuttle in Li–S Batteries [PDF]
, 2022 Lithium–sulfur (Li–S) batteries have attracted much attention due to their high energy density and cost efficiency. However, the drawbacks such as the polysulfide shuttle effect and low electrical conductivity of active sulfur material result in poor ...
Peter Siffalovic (3797185) +10 more
core +1 more source
Crosslinked Ionomer Gel Separators for Polysulfide Shuttle Mitigation in Magnesium-Sulfur Batteries: Elucidation of Structure-Property Relationships [PDF]
, 2018 A series of crosslinked ionomer networks of varying poly(ethylene glycol) diacrylate crosslinker chain length, ionic co-monomer chemistry, and co-monomer ratio have been studied for their use as polysulfide shuttle inhibiting separators in magnesium ...
Laura C. Merrill (5614603) +9 more
core +3 more sources
Reduced polysulfide shuttle in lithium-sulfur batteries using Nafion-based separators [PDF]
, 2022 S.417-422Nafion-coated polypropylene separator (Celgard 2500) is used as cation-selective membrane for lithium sulfur batteries to suppress polysulfide diffusion enhancing the charge efficiency of the cells especially at low charge/discharge rates.
Kaskel, S. +4 more
core +1 more source
The Multi‐Functional Effects of CuS as Modifier to Fabricate Efficient Interlayer for Li‐S Batteries
Advanced Science, 2022 The shuttle effect of lithium polysulfides in lithium‐sulfur batteries (LSBs) has a detrimental impact on their electrochemical performance. To effectively mitigate the shuttle effect, in this study, the coral‐like CuS is introduced to modify the carbon ...
Mengzi Geng, Hangqi Yang, Chaoqun Shang
doaj +1 more source
Anchoring and boosting: Ferrocene-based separators used to eliminate the polysulfide shuttle effect for Li–S batteries [PDF]
, 2023 The commercialization of Li–S batteries has been seriously hampered by the infamous “shuttle effect” of soluble lithium polysulfide intermediates (LiPSs, Li2Sx, 4 ≤ x ≤ 8) and sluggish sulfur species conversion kinetics. In this work, vinyl ferrocene and
Cunpu Li +15 more
core +1 more source