Results 81 to 90 of about 4,306 (216)

The Role of –OEt Substituents in Molybdenum-Assisted Pentathiepine Formation—Access to Diversely Functionalized Azines

Molecules
1,2,3,4,5-pentathiepines (PTEs) are naturally occurring polysulfides of increasing scientific interest based on their identified pharmacological activities.
Roberto Tallarita, Lukas M. Jacobsen, Siva S. M. Bandaru, Benedict J. Elvers, Carola Schulzke   +4 more
doaj   +1 more source

Enhancing the d–Electrocatalytic Activity of MXene Through Defect Engineering

Carbon Energy, EarlyView.
Applications of MXene. ABSTRACT Due to their versatile and tunable surface and bulk chemistry, MXenes have great potential as electrocatalysts for batteries and supercapacitors. When compared with other electrocatalytic processes, in electrocatalytic reactions, MXenes could improve ion diffusion and charge transfer by either providing functional groups
Chenxue Wang, Zixin Wang, Wen Lei, Haijun Zhang, Yuhua Wang   +4 more
wiley   +1 more source

Ultrafast Sodium‐Ion Storage in Self‐Doped 2D PVP‐VS4/Ti3C2Tx Hybrids for High‐Performance Sodium‐Ion Half/Full Batteries

Carbon Energy, EarlyView.
Self‐doped PVP‐VS4/Ti3C2Tx with sulfur vacancies enhances the structural stability and exhibits excellent electrochemical performance. ABSTRACT Transition metal sulfides demonstrate remarkable theoretical specific capacities, making them highly desirable anode materials for sodium‐ion batteries (SIBs).
Mingxuan Tang, Yali Cao, Xinxin Yin, Huan Ma, Xuntao Zhang, Dianzeng Jia   +5 more
wiley   +1 more source

Hydrogen Sulfide (H₂S)/Polysulfides (H₂S_n) Signalling and TRPA1 Channels Modification on Sulfur Metabolism

Biomolecules
Hydrogen sulfide (H2S) and polysulfides (H2Sn, n ≥ 2) produced by enzymes play a role as signalling molecules regulating neurotransmission, vascular tone, cytoprotection, inflammation, oxygen sensing, and energy formation.
Hideo Kimura
doaj   +1 more source

Enabling Wide‐Temperature Range Li‐S Batteries via Asymmetric‐Coordinated Titanium Sites‐Implanted Graphene Single‐Atom Electrocatalysts

Carbon Energy, EarlyView.
A Ti‐based single‐atom catalyst featuring isolated Ti atoms anchored on reduced graphene oxide (Ti‐rGO) has been successfully synthesized as a sulfur host material. This Ti‐rGO composite effectively integrates the robust adsorption capacity of Ti‐O5 coordination groups toward LiPSs with the rapid mass transport kinetics inherent to its porous ...
Shilin Chen, Kaijie Miao, Tao Ban, Jiangqi Zhou   +3 more
wiley   +1 more source

Engineering Spin State of Ni Single‐Atoms to Enhance Electrocatalytic Activity of Sulfur Conversion in Lithium–Sulfur Batteries

Carbon Energy, EarlyView.
Ni SACs with high‐spin state show strong catalytic activity toward lithium polysulfides (LPSs), whereas the Ni SACs with low‐spin state have strong adsorption capacity for LPSs. Therefore, the preparation of Ni SACs with an intermediate spin state by controlling pyridinic N and pyrrolic N enables an excellent balance between the adsorption and ...
Mengyang Li, Guiqiang Cao, Yiming Qi, Chenyang Hou, Xuexia Song, Ruixian Duan, Huijuan Yang, Yifan Li, Xiaorui Chen, Zongnan Lv, Qinchuan Chen, Yitong Yuan, Guohua Liu, Yuhui Xu, Jingjing Wang, Wenbin Li, Xifei Li   +16 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Polysulfide and persulfide-mediated activation of the PERK-eIF2α-ATF4 pathway increases Sestrin2 expression and reduces methylglyoxal toxicity

Redox Biology
Unfolded protein response (UPR) is activated in cells under endoplasmic reticulum (ER) stress. One sensor protein involved in this response is PERK, which is activated through its redox-dependent oligomerization.
Shin Koike, Hideo Kimura, Yuki Ogasawara
doaj   +1 more source

Going from Pt to PGM‐free Catalysts: Effects of Ink Compositions on PEM Water Electrolysis

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Optimisation of cathode ink formulations regarding the ratio between catalyst, carbon and binder results in a boost in PEM water electrolysis performance. The optimisation can be transferred from pentlandites to platinum and selenide catalysts, wherein the metal chalcogenides show a stronger performance enhancement.
Janna Wierper, Jannick Hiltrop, Kevinjeorjios Pellumbi, Julia Jökel, Sebastian Sanden, Miłosz Kożusznik, Andrzej Mikuła, Ulf‐Peter Apfel   +7 more
wiley   +1 more source

Nanolignin Functional Separators for Flexible Lithium–Sulfur Batteries With Enhanced Performance

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Nanolignin‐functionalized separators, incorporating lignin nanoparticles into a crosslinked PEGDA coating applied on commercial separators, reduce polysulfide shuttling, thereby enhancing cycling performance in flexible lithium–sulfur pouch cells, while also improving thermo‐oxidative stability and flame retardancy.
Emanuela Bellinetto, Vijay K. Tomer, Ritu Malik, Sourav Paul, Chandra Veer Singh, Stefano Turri, Mohini Sain, Gianmarco Griffini   +7 more
wiley   +1 more source