Results 111 to 120 of about 167,383 (325)

Electronic structure of porphyrin-based metal– organic frameworks and their suitability for solar fuel production photocatalysis [PDF]

open access: yes, 2015
Metal–organic frameworks (MOFs) can be exceptionally good catalytic materials thanks to the presence of active metal centres and a porous structure that is advantageous for molecular adsorption and confinement.
Aziz, Alex   +5 more
core  

Engineering Framework Materials in Water Systems for Targeted Ion Extraction and Spontaneous Energy Harvesting

open access: yesAdvanced Materials, EarlyView.
Through comprehensive analysis of framework materials in ion extraction, osmotic energy conversion, and evaporative energy harvesting, this review establishes interdisciplinary connections centered on ion‐selective transport mechanisms across these applications and identifies critical challenges and knowledge gaps in existing studies.
Zhengyun Wang   +3 more
wiley   +1 more source

Harnessing Synergistic Cooperation of Neighboring Active Motifs in Heterogeneous Catalysts for Enhanced Catalytic Performance

open access: yesAdvanced Materials, EarlyView.
This review examines the critical role of neighboring active motifs in heterogeneous catalysts, emphasizing how their synergistic cooperativity can be rationally designed to modulate catalytic properties. The discussion centers on the modulation of electronic and geometric structures, categorizing the catalytic systems into metal‐acid (Brønsted/Lewis ...
Peng Yuan   +2 more
wiley   +1 more source

Electrochemical Generation of Porphyrin-Porphyrin and Porphyrin-C60 Polymeric Photoactive Organic Heterojunctions

open access: yesElectrochimica Acta, 2014
Abstract Photoactive organic-organic interfaces are formed by electrochemical synthesis. The generation of porphyrin/porphyrin and porphyrin/C60 heterojunctions over indium tin oxide electrodes by successive electropolymerization steps is described. Functionalized C60 buckminsterfullerene holding a carbazol residue and porphyrins containing carbazol ...
Suárez Ramanzin, Maria Belen   +7 more
openaire   +3 more sources

Designing Physical Unclonable Functions From Optically Active Materials

open access: yesAdvanced Materials, EarlyView.
Assigning unforgeable “fingerprints” to manufactured goods is a key strategy to fight global counterfeiting. Optical physical unclonable functions (PUFs) are chemically generated random patterns of optically active materials serving as unique authenticators.
Maxime Klausen   +2 more
wiley   +1 more source

Oxygen and Conformation Dependent Protein Oxidation and Aggregation by Porphyrins in Hepatocytes and Light-Exposed CellsSummary

open access: yesCellular and Molecular Gastroenterology and Hepatology, 2019
Background & Aims: Porphyrias are caused by porphyrin accumulation resulting from defects in the heme biosynthetic pathway that typically lead to photosensitivity and possible end-stage liver disease with an increased risk of hepatocellular carcinoma ...
Dhiman Maitra   +12 more
doaj  

Bioinspired Design of Heterogenous Single‐Atomic‐Site Catalysts for Electrocatalysis and Photocatalysis

open access: yesAdvanced Materials, EarlyView.
This review gives a summary on the representative bioinspired single‐atomic‐site catalysts (SACs) and their applications in heterogeneous electrocatalysis and photocatalysis. The fundamentals of bioinspired design strategies are systematically discussed in the context of the first shell coordination, the second/long‐range coordination, and the outer ...
Ying Wang   +4 more
wiley   +1 more source

A Sensitive A3B Porphyrin Nanomaterial for CO2 Detection

open access: yesMolecules, 2014
The present report deals with the tailoring, preparation and characterization of novel nanomaterials sensitive to CO2 for use in detection of this gas during space habitation missions. A new nanostructured material based on mixed substituted asymmetrical
Eugenia Fagadar-Cosma   +8 more
doaj   +1 more source

Electrochemistry and Spectroscopy of Sulfate and Thiosulfate Complexes of Iron Porphyrins [PDF]

open access: yes, 2002
The electrochemical and spectroscopic properties of the complex formed by the addition of thiosulfate to ferric porphyrins were examined. The NMR spectrum of the thiosulfate–ferric porphyrin complex was consistent with a high-spin ferric complex, while ...
Crawford, Philip Walter   +1 more
core   +1 more source

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