Results 101 to 110 of about 103,245 (367)

Synthesis and properties amphiphilic meso-arylsubstituted porphyrins

open access: yesТонкие химические технологии, 2007
Synthesis of amphiphilic meso-arylsubstituted porphyrins with hydrophobic long chain groups and with terminal carboxylic and hydroxylic groups via dipyrrolylmethanes and with the use of monopyrrolic condensation is described.
I. N. Fedulova   +5 more
doaj  

Entropy analysis of nickel(II) porphyrins network via curve fitting techniques

open access: yesScientific Reports, 2023
Nickel(II) porphyrins typically adopt a square planar coordination geometry, with the nickel atom located at the center of the porphyrin ring and the coordinating atoms arranged in a square plane.
Muhammad Talha Farooq   +2 more
doaj   +1 more source

Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective

open access: yesAdvanced Materials, EarlyView.
This review explores how in situ and operando spectroscopic techniques reveal the real‐time behavior of reticular materials, including MOFs and COFs. These methods track material formation and functionalization, structural changes, defect formation, dynamic responses to external triggers, and catalytic processes.
Bettina Baumgartner   +4 more
wiley   +1 more source

Electrically addressing the spin of a magnetic porphyrin through covalently connected graphene electrodes [PDF]

open access: yes, 2019
We report on the fabrication and transport characterization of atomically-precise single molecule devices consisting of a magnetic porphyrin covalently wired by graphene nanoribbon electrodes. The tip of a scanning tunneling microscope was utilized to contact the end of a GNR-porphyrin-GNR hybrid system and create a molecular bridge between tip and ...
arxiv   +1 more source

Synthesis of Asymmetrical Porphyrins Substituted in the meso-Position from Dipyrrolomethanes

open access: yesMolecules, 2000
A convenient procedure for the synthesis of 5-(4-acetamidophenyl)-10,15,20-tris(4-substituted phenyl) porphyrins from dipyrrolomethane is reported. meso-(4-Substituted phenyl) dipyrrolomethanes were obtained in yields of 72-84%. The amide porphyrins were
E. N. Durantini   +3 more
doaj   +1 more source

Solvothermal Template‐Induced Hierarchical Porosity in Covalent Organic Frameworks: A Pathway to Enhanced Diffusivity

open access: yesAdvanced Materials, EarlyView.
Hierarchically porous covalent organic frameworks (hCOFs) are constructed using a solvothermal template‐induced synthetic strategy. Commercially available zinc oxide nanoparticles are employed as hard template enabling an increase in total pore volume in a series of COFs.
Fabian Heck   +6 more
wiley   +1 more source

When do tripdoublet states fluoresce? A theoretical study of copper(II) porphyrin [PDF]

open access: yesarXiv, 2023
Open-shell molecules rarely fluoresce, due to their typically faster non-radiative relaxation rates compared to closed-shell ones. Even rarer is the fluorescence from states that have two more unpaired electrons than the open-shell ground state, for example tripdoublet states (a triplet excitation antiferromagnetically coupled to a doublet state).
arxiv  

Porphyrias associated with malignant tumors: Results of treatment with ionizing irradiation [PDF]

open access: yes, 2001
Background: Porphyrin metabolism disorders, known as porphyria, represent inherited or acquired diseases. The development of porphyria due to light sensibility occurs especially with exposure to wavelengths in the range of 300-700 nm.
Dühmke, Eckhart   +4 more
core   +1 more source

Porphyrins as Theranostic Agents from Prehistoric to Modern Times

open access: yesTheranostics, 2012
Long before humans roamed the planet, porphyrins in blood were serving not only as indispensable oxygen carriers, but also as the bright red contrast agent that unmistakably indicates injury sites.
Yumiao Zhang, Jonathan F. Lovell
doaj  

Responsive Molecules for Organic Neuromorphic Devices: Harnessing Memory Diversification

open access: yesAdvanced Materials, EarlyView.
Responsive molecules are essential for organic in‐sensor computing devices. This Review highlights recent advances in thedesign, synthesis, and incorporation of electrically, optically, and magnetically responsive molecules in multifunctional synaptic perception devices endowedwith both nonvolatile and volatile memory diversification. By exploiting the
Yusheng Chen   +4 more
wiley   +1 more source

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