Active Site Determination of Heterogenized Molecular Electrocatalysts
Here, we develop a methodology to examine the active site availability of immobilized transition‐metal molecular complexes via cyclic voltammetry. By using varying loadings of the molecular complex FeTPP physically immobilized onto Vulcan Carbon, we show the influences of FeTPP/VC ratios on the total number of active sites.
Elena Antoniono +3 more
wiley +1 more source
ABSTRACT Wilson disease (WD) is an autosomal recessive disorder of copper metabolism caused by ATP7B mutations. Diagnosis is usually straightforward in symptomatic patients, but can be challenging in children and adolescents with mild liver disease, borderline urinary copper excretion, or inconclusive genetic findings.
Emanuele Nicastro +10 more
wiley +1 more source
Nanomaterial‐Mediated Near‐Infrared Photothermal Neuromodulation for Neurologic Disorders
This review summarizes how near‐infrared light activates photothermal nanomaterials to enable noninvasive neuromodulation with high spatiotemporal precision. It elucidates the underlying mechanisms, explores targeted therapeutic applications for neurological disorders, discusses integration with optogenetics and biosensors, and addresses future ...
Ting‐Ting Zeng +9 more
wiley +1 more source
Thermal alteration of organic matter in recent marine sediments. 1: Pigments [PDF]
Sediment from Tanner Basin, the outer continental shelf off Southern California, was analyzed for photosynthetic pigments and their derivatives, namely carotenes and chlorins. Samples of the sediment were also exposed to raised temperatures (65, 100, 150
Aizenshtat, Z. +3 more
core +1 more source
Dibenzazepin‐verbrückte Netzwerk‐Polymer‐Phthalocyanine als abbaubare heterogene Photokatalysatoren
Photodynamische Dibenzazepin‐Brücke wurde in Zink‐ und Kobalt‐Netzwerk‐Polymer‐Phthalocyanine (NP‐Pcs) eingeführt, um abbaubare heterogene Photokatalysatoren zu erhalten. Zum ersten Mal spielt die Bestrahlung mit Licht eine Schlüsselrolle beim „Design, der Verwendung und dem Abbau” von NP‐Pcs.
Erem Ahmetali +4 more
wiley +1 more source
Covalent organic framework–carbon nanotube (COF–CNT) core–shell nanohybrids are developed as an efficient platform to enhance the site utilization of molecular catalysts for electrochemical CO2 reduction. The well‐defined nanostructure promotes catalytic site accessibility, achieving CO turnover frequencies among the highest reported to date.
Liang Yao +8 more
wiley +1 more source
Exploiting porphyrin metabolism to inhibit angiogenesis. [PDF]
De Giorgio F +12 more
europepmc +1 more source
Dibenzazepine Bridged Network Polymeric Phthalocyanines as Degradable Heterogeneous Photocatalysts
Dibenzazepine photodynamic bridge has been introduced to zinc and cobalt networks phthalocyanines (NP‐Pcs) to obtain degradable heterogeneous photocatalysts. For the first time, light irradiation plays a key role in “design, use and degradation” of NP‐Pcs.
Erem Ahmetali +4 more
wiley +1 more source
Phthalocyanines and porphyrins linked to gold adatoms and their catalytic property towards hydroxide oxidation [PDF]
Adriaens, Mieke, De Wael, Karolien
core +1 more source
Probable Acute Hepatic Porphyria Diagnosed Using Urinary Porphyrin Spectrophotometry in a Resource-Limited Setting: A Case Report. [PDF]
Thanigasalan M.
europepmc +1 more source

